The thermodynamic behaviours in a PFBC combustor were simulated for the ash from all of the six coals with sand and limestone as bed material. Ash components determined the ash thermodynamic behaviour at high temperature, and each component had different effects. For assessment of the potential for bed material agglomeration, the temperature at which 15% of the ash would become liquid (T15) was calculated with the coal ash, the cyclone ash and the cyclone ash mixed with varying amounts of limestone. Both the bed ash and fly ash, collected from an industrial PFBC plant, consisted of limestone/lime particles with different extent of sulphation, and coal ash particles. The calcium aluminosilicate material formed on the coal ash particles but not on the limestone particles. The aluminosilicate materials appeared to be formed from fine ash and lime particles at some local hot zones in the boiler. The melted materials may glue ash and bed material particle into large particles leading to bed agglomeration and defluidization. Four mechanisms were proposed for the formation of bed material agglomeration in PFBC, which may occur under different conditions. One mechanism explains the bed material agglomeration with the high localized high temperature zone due to the improper design or operation, while the bed agglomeration through the other three mechanisms results from the unsuitable coals burnt in the PFBC combustor. The maximum char temperature and the minimum T15 were used simultaneously to predict the tendency towards bed material agglomeration in PFBC burning different coals. Both char properties and ash properties should be considered during coal selection process for PFBC, to ameliorate the potential problem of bed agglomeration.

The salt attack of Fired Clay Bricks (FCBs) causes surface damage that is aesthetically displeasing and eventually leads to structural damage. Methods for determining the resistances of FCBs to salt weathering have mainly tried to simulate the process by using accelerating aging tests. Most research in this area has concentrated on the types of salt that can cause damage and the damage that occurs during accelerated aging tests. This approach has lead to the use of accelerated aging tests as standard methods for determining resistance. Recently, it has been acknowledged that are not the most reliable way to determine salt attack resistance for all FCBs in all environments. Few researchers have examined FCBs with the aim of determining which material and mechanical properties make a FCB resistant to salt attack. The aim of this study was to identify the properties that were significant to the resistance of FCBs to salt attack. In doing so, this study aids in the development of a better test method to assess the resistance of FCBs to salt attack. The current Australian Standard accelerated aging test was used to measure the resistance of eight FCBs to salt attack using sodium sulfate and sodium chloride. The results of these tests were compared to the water absorption properties and the total porosity of FCBs. An empirical relationship was developed between the twenty-four-hour water absorption value and the number of cycles to failure from sodium sulfate tests. The volume of sodium chloride solution was found to be proportional to the total porosity of FCBs in this study. A phenomenological discussion of results led to a new mechanism being presented to explain the derivation of stress during salt crystallisation of anhydrous and hydratable salts. The mechanical properties of FCBs were measured using compression tests. FCBs were analysed as cellular materials to find that the elastic modules of FCBs was equivalent for extruded FCBs that had been fired a similar temperatures and time. Two samples were found to have significantly different elastic moduli of the solid microstructure. One of these samples was a pressed brick that was stiffer due to the extra bond that is obtained during sintering a closely packed structure. The other sample was an extruded brick that had more firing temperature and time compared with the other samples in this study. A non-destructive method was used to measure the indentation hardness and indentation stress-strain properties of FCBs. The indentation hardness of FCBs was found to be proportional to the uniaxial compression strength. In addition, the indentation hardness had a better linear correlation to the total porosity of FCBs except for those samples that had different elastic moduli of the solid microstructure. Fractography of exfoliated particles during salt cycle tests and compression tests showed there was a similar pattern of fracture during each failure. The results indicate there were inherent properties of a FCB that determines the size and shape of fractured particles during salt attack. The microstructural variables that determined the fracture properties of FCBs were shown to be important variables to include in future models that attempt to estimate the resistance of FCBs to salt attack.

Large scale power generation commences with the combustion of coal or other fuel, which in turn converts high pressure water into steam which then drives a turbine thus generating electricity. Burning high moisture coal, such as lignite, for power generation implies that a significant amount of energy is wasted in vaporising the moisture, which could otherwise be used in the steam raising process. This implies that more moist coal would be required to drive the same process than if the coal was drier, thus increasing the amount of combustion products such as greenhouses gases. Introducing a dried coal in an existing boiler will significantly change the heat flux profiles, which could result in boiler damage or excessive fouling. Flame temperature is influenced by the supply of reactants; in most cases the limiting reactant will be oxygen. The supply of oxygen (through air) to a pneumatically transported coal stream and subsequent reaction is controlled by the localised fluid mechanics or ‘mixing’. This research aims to provide an understanding of the mixing process between the pneumatically transported coal and air in brown coal fired boilers by modelling the individual jets. The effects of the change in velocity ratio for the air (secondary) jets and fuel (primary) jets of rectangular burners typical of those found in brown coal fired boilers has been studied experimentally and is reported in this thesis. In particular, scientific analysis was used to investigate the physical mechanisms which control fuel-air mixing, and to quantify the concentration of primary and secondary fluid. The concentration data was used in a regression model in conjunction with a reactive combustion model, developed from a 1:30 scale cold model of the Yallourn W’ stage 2 boiler, in order that overall boiler performance can be assessed. This overall study is fundamental as a result of the questions raised concerning the future of brown coal in modern society. A qualitative flow visualisation study of the unconfined 1:30 scaled primary, and two adjacent rectangular jets, was conducted using single colour planar laser induced fluorescence. The characteristics of the jet flow were examined by imaging individually seeded primary and secondary jets and were visualised through four different planes longitudinally, on the axes of each jet. In addition, a transverse qualitative and quantitative study on the rectangular jets was also conducted for the individually seeded jets, and was visualised through planes of flow perpendicular to the direction flow, specifically at axial stations of x/D =0.1, 0.2, 0.5, 1, 2, 4, 6 and 8. The flow characteristics were also examined under different co-flow conditions, particularly secondary to primary jet velocity ratios (λ) of 0, 0.55, 1.4, 2.8, 3.6 and ∞. This quantitative data yields the basis for a 3D regression model to predict fuel-air mixing in actual boilers. A semi-quantitative investigation into some geometrical modifications on the rectangular jets was also conducted at velocity ratios of λ=0, 0.55 and 1.4. The rectangular nozzles were fitted with base plates orientated at 90 degrees and 60 degrees to the direction of flow. The longitudinal flow visualisation study highlighted the effect of velocity ratio on the flow field of the primary and secondary jets. In particular it showed that the main structures of the primary and secondary jets are sensitive to the co-flowing conditions. The primary jet also experienced the formation of coherent structures close to the bluff body re-circulation region for λ>2.8. The quantitative transverse analysis of the rectangular jets showed that the primary jet and secondary jets close to the nozzle exit plane distorted with a change in co-flowing conditions. The primary jet experienced distortion for λ>1.4, and the secondary jets experienced distortion for λ <1.4. A plausible mechanism for this “distortion” can be explained by different co-flowing conditions altering the velocity gradients of the jet, thus changing the denomination of the counter rotating vortices present in the corners of rectangular jets, allowing them to alter jet shape. The transverse quantitative analysis of the rectangular jets allowed for graphical representation of the normalised concentration of the primary and secondary jets in the radial direction and the centreline mixture fraction decay. The analysis of the latter showed that the primary jet, under all co-flow conditions, reached self-similarity at approximately x/D =4, whereas the secondary jets did so at x/D =2. The primary jets observed greater rates of centreline dilution at high velocity ratios, whereas the secondary jets did so at λ=0.55. The quantification of the centreline concentration decay obeyed the inverse rate law for all co-flowing conditions. The first order decay constant K₁, was found to be heavily dependant on velocity ratio. The planar transverse quantitative data of the primary and secondary jets was used with the method of weighted squares to develop a regression model that would three-dimensionally reproduce the scalar mixing field as a function of velocity ratio. The regression model reproduces scalar quantities for λ=0 and λ=0.55 to 3.6 for the primary jet and λ=0.55 to 3.6 and ∞ for the secondary jet, and is capable of predicting primary and secondary bulk fluid concentrations within 30 to 40 % of the measured values. A sensitivity analysis on the regression model revealed that it is highly responsive to the momentum-controlling region between the jets with a change in velocity ratio. / http://proxy.library.adelaide.edu.au/login?url= http://library.adelaide.edu.au/cgi-bin/Pwebrecon.cgi?BBID=1297627 / Thesis (Ph.D.) -- University of Adelaide, School of Chemical Engineering, 2007

Large scale power generation commences with the combustion of coal or other fuel, which in turn converts high pressure water into steam which then drives a turbine thus generating electricity. Burning high moisture coal, such as lignite, for power generation implies that a significant amount of energy is wasted in vaporising the moisture, which could otherwise be used in the steam raising process. This implies that more moist coal would be required to drive the same process than if the coal was drier, thus increasing the amount of combustion products such as greenhouses gases. Introducing a dried coal in an existing boiler will significantly change the heat flux profiles, which could result in boiler damage or excessive fouling. Flame temperature is influenced by the supply of reactants; in most cases the limiting reactant will be oxygen. The supply of oxygen (through air) to a pneumatically transported coal stream and subsequent reaction is controlled by the localised fluid mechanics or ‘mixing’. This research aims to provide an understanding of the mixing process between the pneumatically transported coal and air in brown coal fired boilers by modelling the individual jets. The effects of the change in velocity ratio for the air (secondary) jets and fuel (primary) jets of rectangular burners typical of those found in brown coal fired boilers has been studied experimentally and is reported in this thesis. In particular, scientific analysis was used to investigate the physical mechanisms which control fuel-air mixing, and to quantify the concentration of primary and secondary fluid. The concentration data was used in a regression model in conjunction with a reactive combustion model, developed from a 1:30 scale cold model of the Yallourn W’ stage 2 boiler, in order that overall boiler performance can be assessed. This overall study is fundamental as a result of the questions raised concerning the future of brown coal in modern society. A qualitative flow visualisation study of the unconfined 1:30 scaled primary, and two adjacent rectangular jets, was conducted using single colour planar laser induced fluorescence. The characteristics of the jet flow were examined by imaging individually seeded primary and secondary jets and were visualised through four different planes longitudinally, on the axes of each jet. In addition, a transverse qualitative and quantitative study on the rectangular jets was also conducted for the individually seeded jets, and was visualised through planes of flow perpendicular to the direction flow, specifically at axial stations of x/D =0.1, 0.2, 0.5, 1, 2, 4, 6 and 8. The flow characteristics were also examined under different co-flow conditions, particularly secondary to primary jet velocity ratios (λ) of 0, 0.55, 1.4, 2.8, 3.6 and ∞. This quantitative data yields the basis for a 3D regression model to predict fuel-air mixing in actual boilers. A semi-quantitative investigation into some geometrical modifications on the rectangular jets was also conducted at velocity ratios of λ=0, 0.55 and 1.4. The rectangular nozzles were fitted with base plates orientated at 90 degrees and 60 degrees to the direction of flow. The longitudinal flow visualisation study highlighted the effect of velocity ratio on the flow field of the primary and secondary jets. In particular it showed that the main structures of the primary and secondary jets are sensitive to the co-flowing conditions. The primary jet also experienced the formation of coherent structures close to the bluff body re-circulation region for λ>2.8. The quantitative transverse analysis of the rectangular jets showed that the primary jet and secondary jets close to the nozzle exit plane distorted with a change in co-flowing conditions. The primary jet experienced distortion for λ>1.4, and the secondary jets experienced distortion for λ <1.4. A plausible mechanism for this “distortion” can be explained by different co-flowing conditions altering the velocity gradients of the jet, thus changing the denomination of the counter rotating vortices present in the corners of rectangular jets, allowing them to alter jet shape. The transverse quantitative analysis of the rectangular jets allowed for graphical representation of the normalised concentration of the primary and secondary jets in the radial direction and the centreline mixture fraction decay. The analysis of the latter showed that the primary jet, under all co-flow conditions, reached self-similarity at approximately x/D =4, whereas the secondary jets did so at x/D =2. The primary jets observed greater rates of centreline dilution at high velocity ratios, whereas the secondary jets did so at λ=0.55. The quantification of the centreline concentration decay obeyed the inverse rate law for all co-flowing conditions. The first order decay constant K₁, was found to be heavily dependant on velocity ratio. The planar transverse quantitative data of the primary and secondary jets was used with the method of weighted squares to develop a regression model that would three-dimensionally reproduce the scalar mixing field as a function of velocity ratio. The regression model reproduces scalar quantities for λ=0 and λ=0.55 to 3.6 for the primary jet and λ=0.55 to 3.6 and ∞ for the secondary jet, and is capable of predicting primary and secondary bulk fluid concentrations within 30 to 40 % of the measured values. A sensitivity analysis on the regression model revealed that it is highly responsive to the momentum-controlling region between the jets with a change in velocity ratio. / http://proxy.library.adelaide.edu.au/login?url= http://library.adelaide.edu.au/cgi-bin/Pwebrecon.cgi?BBID=1297627 / Thesis (Ph.D.) -- University of Adelaide, School of Chemical Engineering, 2007

Thesis (Ph. D.)--West Virginia University, 2006. / Title from document title page. Document formatted into pages; contains viii, 170 p. : ill. Includes abstract. Includes bibliographical references (p. 119-137).

Thesis (Ph. D.)--University of Washington, 2001. / Vita. Includes bibliographical references (leaves 98-109).

This thesis presents a laser diagnostic investigation into the combustion, NOx formation and mixing processes occurring within the optically assessed combustion chamber of a methane-fired (10kW), fully premixed, self-aspirating, Helmholtz pulse combustor. The inlet geometry of the combustion chamber consisted of a step expansion and a bluff body obstacle formed by a stagnation plate. The focus of the investigation was the effects of the stream-wise position of the stagnation plate on the pulse combustion processes. A comprehensive parametric study of the performance of the pulse combustor is presented with stagnation plate position, air/fuel ratio and tailpipe length as the variables. The operating frequency and peak pressure amplitude trends were found to vary in accordance with the Rayleigh criterion. The operation of the combustor was more stable with the effective heat-release point preceding the resonant acoustic peak. Operation outside of this regime produce increased levels of CO. Time-resolved, laser-sheet flow visualisation images are presented of the flow structures within the combustion chamber. The inlet mixing - between the reactants and residual gases - was dominated by the formation of two counter-rotating toroidal vortices. In general, the inlet mixing was found to decrease as the stagnation plate was moved further into the combustion chamber. However, other mechanisms that tended to counter this trend were observed. Under certain conditions, significant flow reversals were imaged with gases penetrating the combustion chamber from the tailpipe. The combustion event was investigated using cycle-resolved chemiluminescence and laser induced fluorescence imaging of OH* radicals. Ignition of the fresh reactants by residual combustion/radical activity was found to occur along the interface between reactants and residual gases. The increase in reaction zone area generated by the action of the toroidal vortices provided the necessary mechanism for the rapid combustion of the reactants. The reduced mixing associated with moving the stagnation plate further into the combustion chamber produced a more compact combustion zone with less interaction between combusting reactants and cooler residual gases. This modification to the combustion zone was consistent with the measured trends of rising NOx tailpipe emissions and decreasing N02/NOx ratio. Under certain conditions, a reversal in the NOx and N02/NO, ratio trends was observed. This was explained by an augmentation of heat transfer rate out of the combustion chamber, characterised by increased flow reversal strength, which lead to cooler residual gases. Additional mechanisms, which modified the inlet mixing process, were also identified as contributing to the reversal of the NOx trends.

A large-scale pilot plant (0.43 m ID) was extensively modified and converted into an absorber/stripper system to demonstrate CO₂ capture technology using aqueous piperazine promoted potassium carbonate for coalfired power plants. Four pilot plant campaigns were completed. Three campaigns were conducted using 5 m K⁺/2.5 m PZ and 6.4 m K⁺/1.6 m PZ. Flexipac 1Y and Flexipac AQ Style 20 structured packing were used in the absorber. The stripper was tested with 14 sieve trays, IMTP #40 random packing, and Flexipac AQ Style 20 packing. Monoethanolamine (7 m) was tested in the third campaign to establish a base case. An approximate rate analysis showed that 5 m K⁺/2.5 m PZ is two times faster than 7 m MEA and three times faster than 6.4 m K⁺/1.6 m PZ. The location of the temperature bulge moves from the top of the column to bottom as the liquid to gas flow rate ratio is increased. Foaming occurred in the absorber in the first two campaigns and occurred in the stripper in the fourth campaign. Data from the pilot plant was used to develop a K⁺/PZ absorber model in Aspen Plus® RateSep[trademark]. The Hilliard (2005) Aspen Plus® VLE model and the kinetics developed by Cullinane (2005) were incorporated in the model. Data-Fit was simultaneously used to reconcile pilot plant data and perform a regression of the interfacial area and heat loss parameters for the RateSep[trademark] absorber model. The lean loading for the pilot plant data was shifted down by 10% to account for a discrepancy with the Cullinane vapor-liquid equilibrium data. The Data-Fit results showed that the average interfacial area for Flexipac 1Y was 80% of the value measure by the air-water column. The average interfacial area for Flexipac AQ Style 20 for 5 m K⁺/2.5 m PZ was 56% of the air-water measurement. The CO₂ heat of absorption may not have been adequately predicted by the RateSep[trademark] absorber model because the regressed values of heat loss were consistent with forced convection.

Thesis (Ph. D. - Hydrology and Water Resources)--University of Arizona. / Includes bibliographical references.

Thesis (Ph. D.)--University of Texas at Austin, 2007. / Vita. Includes bibliographical references.