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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
131

PROMOTING CONSERVATION AGRICULTURE IN THE EASTERN FREE STATE OF SOUTH AFRICA

Knot, Jakob 04 August 2014 (has links)
Agriculture contributes to greenhouse gas emissions (GHG) through practices that reduce the amount of soil organic carbon. Examples of this are fallow and intensive tillage. Conventional ways of farming are not sustainable as soils are degraded, imbalanced, over-utilized, low in organic matter and without heavy inorganic fertilizer good yields are not possible. Sustainable crop production however is essential for South Africaâs food security, employment and contribution to the national economy. The sustainability of agriculture needs therefore to address environmental, economical and sociological aspects. Conservation Agriculture (CA) is world-wide found as an antipode against soil degradation, erosion and ineffective water conservation as a result of conventional tillage. The problem, however is that CA is a much developed product of No-till, which requires a gradual and timely process. No-tillage in itself is not the desired outcome, but a first step to CA. Ample technical research has been conducted on no-tillage and CA reflecting improved soil quality, yields and profits (see paper 1). This thesis will elaborate more on local technical issues e.g. soil quality (paper 4) and profitability (paper 3), as to contribute to the increased adoption of sustainable farming. This thesis emphasized the urgency for transdisciplinary research and the role of sociology in innovation studies. The role of sociology is often overlooked, but this thesis advocates that sociology is an integral part of transdisciplinary research. Narratives are useful methods of explaining what NT and CA is (see paper 2). The Actor Network Theory is useful in that farmers possess âagencyâ as a result of networking, which enables the uptake of an innovation of NT and in addition to develop into context related or ecotype specific CA production system (see paper 5). This thesis addressed conventional farmers barriers to adopting NT e.g. livestock integration, doubt concerning profitability and lack of knowhow. This thesis contributes to environmental awareness and promotes that CA can mitigate GHG emissions through sequestration of organic carbon in the soil (paper 4) and reflecting direct and indirect environmental costs in terms of GHG through the use of diesel, fertilizer, pesticides and other chemicals (see paper 3).
132

APPLICATION OF THE MIXING CELL MODEL TO THE QUANTIFICATION OF GROUNDWATER â SURFACE WATER INTERACTION

Matthews, Amy Jane 07 August 2014 (has links)
The significance of a reliable groundwater resource assessment is of growing importance as water resources are stretched to accommodate the growing population. An essential component of a groundwater resource assessment is the quantification of surface water â groundwater interaction. The insufficient amount of data in South Africa and the apparent lack of accuracy of current estimates of the groundwater component of baseflow lead to the investigation of a new methodology. The applicability of the Mixing Cell Model (MCM) to quantify the groundwater contribution to baseflow is examined to determine whether the method would be of use in groundwater resource assessments. The MCM simultaneously solves water and solute mass balances to determine unknown inflows to a system, in this application the groundwater component of baseflow. The incorporation of water quality data into the estimation of the surface water â groundwater interaction increases the use of available data, and thus has the ability to decrease the uncertainty of the estimation process. The balance equations are equated to an error term which is used in the quadratic programming solution of minimizing the square error sums in order to determine the unknown inflows. The mixing cell model is applied to datasets from the surface water â groundwater interaction test site developed by the University of the Free State, in addition to data collected along the middle Modder River during a fieldwork survey. The MCM is subsequently applied to a set of quaternary catchments in the Limpopo Province for which there are available calibrated estimates of the groundwater component of baseflow for the Sami and Hughes models. The MCM is further applied to the quaternary catchment D73F, located in the semi-arid Northern Cape, to assess the applicability of the mathematically based MCM in terms of a flow system located within a regionally-defined zero groundwater baseflow zone. The MCM results for each study area are assessed in comparison to groundwater baseflow volumes determined by the Pitman, Sami and Hughes models. A chemical hydrograph separation method which also incorporates water quality data is additionally reported for the study areas to further validate the MCM. The results indicate that the mixing cell model can reliably estimate the groundwater component of baseflow to a river. This application of the mixing cell model could contribute to increase and evaluate the accuracy of current groundwater baseflow estimates in South Africa, which will in turn ensure the responsible and sustainable use of the countries water resources.
133

LAND REFORM AND POVERTY ALLEVIATION IN MASHONALAND EAST, ZIMBABWE

Makunike, Blessing 07 August 2014 (has links)
The study is an investigation into the linkage between, landownership and poverty alleviation in Mashonaland East Province of Zimbabwe. The focus is directed by the fact that in Zimbabwe, the poorest live in rural areas. The problem of rural poverty has been attributed, in part, to lack of access to land due to historical imbalances arising from colonialism. The objective of this study is to find out how the livelihoods of those who were resettled have been transformed. Despite heated debate among scholars on Zimbabweâs controversial land reform, a systematic investigation of the relationship between access to land and poverty alleviation in Zimbabwe is generally weak; consequently, there are gaps in the analysis of land occupation processes and what is required for sustainable agrarian livelihoods. Indeed, the programme of land reform is crucial to the resolution of rural poverty. It is, therefore, important that such a programme be implemented in a fair, just and sustainable manner in the interest of all the stakeholders within the ambits of the law and constitution of Zimbabwe. The approach followed in the discussion can be described as moving from the macro to the micro in that the thesis covers broad but very important contextual issues about the political history of the land question in Zimbabwe and then narrows down to a discussion of land reform and poverty in Mashonaland East. The theoretical position of the study is that the land question in Zimbabwe is by and large, a political issue. The key argument is that distribution of societyâs scarce resources in Zimbabwe is primarily informed by political calculations rather than non-partisan concerns for alleviation of poverty at the grassroots of society. Land is finite and therefore a scarce resource and its redistribution has largely been informed by political calculations rather than consistent criteria to deal with the plight of the rural poor based on measured levels of need and poverty. The politicization of land reform in Zimbabwe has a lot to do with the reproduction of power of the ruling ZANU-PF political elites. Poverty in Zimbabwe emanates from lack of access by the poor majority to resources and other material means of life. The theoretical perspective is that governmentâs decisions on who gets land leads to poverty as the vulnerable groups and less politically connected are not always prioritized for access to land. The research paradigm used is the sustainable livelihoods approach, which is influenced by qualitative methodology. It emphasizes the complexity of rural class structures and the contingency of individual agency. This approach has, at its center, the individual or individual households, and tries to understand how each household derives its livelihood. The theory of justice is also partially used to inform the assessment of the social character of land reform beneficiaries, in relation to grievances, the procedure of the reform, the social organization of beneficiaries, and the intended impact of the reform. Because of the economic and political environment in which the study was done, simple random sampling was used to select respondents for discussions and interviews. This approach was justified because it gave each unit an equal chance of being chosen. But the study is based, on the overall; on a case study method hence the findings may have limited generalization to contexts outside Mashonaland East. The narrative of the Zimbabwean state is that the land reform programme met its targets. Resettlement benefited a broad set of people. However empirical evidence examined during the research shows that there was no significant reduction in rural poverty levels, beneficiary selection was not done in a just, fair and transparent manner and productivity was generally low. The thesis argues that the land reform programme in Zimbabwe is in a crisis characterized by a lack of transparency and presided over by a state that is itself unclear about the redistribution strategy that it wants to pursue. There is an ambiguous implementation plan as well as inadequate capacity enhancing policy parameters that are vital to enable a fair and objective evaluation of the whole programme.
134

DESIGNING A DEWATERING PLAN FOR THE RUASHI MINE IN THE DEMOCRATIC REPUBLIC OF CONGO

Chironga, Lordrif 08 August 2014 (has links)
This dissertation describes the results of field based investigations on groundwater flow at Ruashi Mine located in Katanga Province of Democratic Republic of Congo (DRC). The core objectives of the study were to simulate groundwater flow, estimate flow into the pits and ultimately design a dewatering strategy for the mine. In order to understand how groundwater flows into and through the mine, a detailed conceptual hydrogeological model was constructed as framework for numerical groundwater flow modelling. The numerical model was used simulate groundwater flow and predict pit inflow volumes. At the time of this research, mining at Ruashi was being carried out in three pits that are expected to reach terminal depth of 180 metres below ground level (mbgl) in 16 years of continued mining. The mine is located along a faulted overturned syncline composed of composed of Siltstones, Argillites, Sandstones and Shales and covered by Laterite. Based on aquifer hydraulic testing results, the transmissivity of the shallow aquifer was estimated to be 10 m2/d. The specific yield for the deep aquifer was estimated to be 1 x 10-5. The Chloride Mass Balance Method was used to estimate recharge to the groundwater system as 280 mm per annum (14% of Mean Annual Precipitation). Water levels vary from 1.02 to 62.5 mbgl. The general groundwater type was analysed to be calcium-magnesium-bicarbonate (Ca-Mg- HCO3), typical of young groundwater. The numerical groundwater flow model area is 15.7 km2 and comprises 5 layers, 17 240 elements and 10 614 nodes. The model results indicated that groundwater flow to the pits is unlikely to exceed 42 000 m3/d. Using the pumping capacity (15 000 m3/d) for year 2012, a maximum water level drawdown of 55 m was estimated. However, the numerical model demonstrated that the existing pumping boreholes can be augmented by an additional set of 16 boreholes pumping 2 000 m3/d per borehole. This pumping rate can lower the groundwater level to about 1 188 mamsl which is about two meters below pit terminal elevation. This study made significant contribution to understanding the hydrogeological properties of aquifers at the mine. The aquifer hydraulic testing data was used to estimate aquifer hydraulic parameters. However based on the field evidence, it is suggested that Packer testing could improve the estimates of aquifer hydraulic parameters for each aquifer. The numerical model demonstrated the typical aquifer response to different pumping scenarios. The different pumping scenarios were run in order to determine the optimum pumping rates to dewater the mine.
135

A QUANTITATIVE APPROACH IN MINE WATER BALANCES AND STRATEGIC MANAGEMENT

Mostert, Joseph Ferdinand Willem 08 August 2014 (has links)
The vital role of water within the mining industry, both as an asset which generates value as well as a shared natural resource requiring responsible stewardship, have long been recognised. Due to extreme climate changes, an increasing population density and poor water management, securing of water has become a global challenge and water scarcity will continue to be one of the greatest challenges facing mine water management. There is no simple recipe for mine water management and regulations by environmental authorities, along with past polluting practices, are forcing mining operations to improve and prioritise their water consumption. Accordingly, this sector is expected to be increasingly required to demonstrate leadership through innovative water use management. A mine water balance is considered to be one of the most important and fundamental tools available for mining operations as management begins with a basic understanding of where water is sourced from, and where it is utilised. With this kept in mind, a mine water balance should be based on a holistic systems model approach with an appropriate relationship between the required level of complexity in the model structure and purpose. Excessive detail can cause the model to become clumsy and tend not to focus on strategic water management principles. Emphasis should be put on a system approach, taking into consideration the main interactions, feedbacks and functional relationships between the various parts of the whole system. An overall mine water balance that superimposes different water systems can be divided into a process water system and a natural water system. The natural water system is associated with the intrinsic hydrological cycle and is often disregarded due to uncertainties. It can however significantly impact on mine water usage and losses as indicated in this case study. Consequently, decision making and management options should be based on the evaluation of the system as a whole and inclusion of the natural system as a component of the mine water balance is imperative for accurate quantification. The natural system includes a surface water environmental circuit as well as a groundwater environmental circuit. Surface and groundwater resources have historically been managed separately, but more than ever before, interaction between these two systems are required to facilitate effective resource management. Mining activities have a major effect on the modification of the hydrological regime and the influence of increased hydraulic conductivity along with mining induced recharge, should be evaluated as part of the adapted mine water balance. Furthermore, mine dewatering predictions and climatic scenarios must be incorporated to reflect site conditions more accurately. As poor water management poses an operational risk to mining operations, this sector has developed novel ways to respond to water issues in differing circumstances and has illustrated the ability to turn risk into opportunity. Now, more than ever, special measures are needed to identify options for life-of-mine strategies and initiatives for water conservation and management. Future focus should be to continue investigation and implementation of the water use strategies in order to improve performance across operations and encourage engagement with other water users. Moreover, to share experiences, learn from others and contribute to water discussions and debate at local, national and international levels.
136

THE USE OF ECOSYSTEM PARAMETERS IN PREDICTING THE RISK OF AIRCRAFT-WILDLIFE COLLISIONS AT NAMIBIAN AIRPORTS

Hauptfleisch, Morgan Lindo 19 August 2014 (has links)
Human-wildlife conflict is affecting a number of aspects of society as a result of increased competition for resources such as food and space. To address the complexity, management of human wildlife conflict needs to be innovative to achieve a difficult but possible win-win solution for both humans and wildlife. As an important form of human-wildlife conflict, aircraft-wildlife collisions (AWCs), more commonly known as bird strikes, require even greater imagination and innovation to solve. AWCs have the potential to cause loss of life to humans, and annual losses in damages as a result of such collisions runs in excess of US$ 3 billion per year to the aviation industry. Due to lack of accurate reporting of AWCs in Namibia (and Africa as a whole) losses have been impossible to quantify locally. In addition to direct damage, airlines, airports and individuals have been litigated in Europe and the USA for indirect damages resulting from AWCs. A number of studies have identified an increasing trend in AWCs globally as a result of higher flight volumes and increases in risk bird populations. Flight safety in Africa is of concern internationally, and AWCs are an important safety aspect which need to be understood better. Very little empirical research on the extent or causes of AWCs in Africa have been published. At Namibiaâs two major airports, Hosea Kutako International and Eros (domestic), 128 AWC incidents were recorded between 2006 and 2010. Although none led to human injury or death, two major incidents lead to costs in excess of N$ 20 million and N$ 1million respectively. Publications on AWC minimisation strategies and techniques on the continent are limited to South Africa and Uganda. This is problematic, as mitigation measures for AWCs in Africa are therefore mostly based on research in foreign ecosystems; while we know that local knowledge of AWC factors, such as bird and mammal population dynamics and climatic seasonality are critical to the success of AWC management. This study is the first scientific investigation into any aspect of AWCs in Namibia. It aims to understand the relationship between ecosystem components and their effect on the risk of aircraft-wildlife collisions occurring at Hosea Kutako and Eros airports. Monitoring of ecosystem components such as insects and small mammals are useful to airport wildlife management as they are relatively quick and inexpensive tools for determining ecosystem health and functioning and can indicate varying environmental contexts and responses. These ecosystem components and others such as vegetation and avian communities were explored. The study found that modelling the abovementioned ecosystem factors to predict the risk of AWCs would be marginally accurate, but still useful in understanding the system, as well as the effects of various management actions on that system. Systems modelling was found to have the potential to map the complexity of influences on AWCs and make them understandable to airport management in order to allow more informed decision making and resourcing regarding the management of AWC risk. The international obligation placed on airport staff to control wildlife hazards in the vicinity of airports is often difficult to fulfil, especially at smaller airports or in countries with inadequate resources and capacity. In addition to this, research into wildlife habitat, species and their habits at airports has predominantly originated in Europe and North America, and hence mitigation measures are most effective in these conditions, and less effective elsewhere. Based on the context of its literature and empirical research, this study proposes a toolkit which was designed to guide airports in Southern Africa to minimise risk of aircraftwildlife collisions. It is based on the understanding of ecosystems in the vicinity of the two airports on which this study was based, but also on the broader understanding of capacity and resources available to many Southern African countries. It also considers the recommended practices of ICAO, global best practice and promotes a multi-stakeholder management approach.
137

ESTIMATION OF REPRESENTATIVE TRANSMISSIVITIES OF HETEROGENEOUS AQUIFERS

Steyl, Gideon 19 August 2014 (has links)
The study describes the effect of calculating a generalised mean transmissivity or hydraulic conductivity value for a region or aquifer system as it pertains to South Africa. Resource determination of an area is usually driven by the determination of the bulk flow parameters, such as hydraulic conductivity and storativity values. At this stage a decision is usually made on the basis of either maintaining the area under natural conditions (no pumping), or an abstraction (pumping) scenario is envisaged. In both instances water levels, hydraulic testing and distribution of the water resources (aquifer) are required. Since it is not possible to evaluate the total area for these parameters certain assumptions have to be made such as that an average bulk flow parameter for an area can be determined. In wide-ranging situations a simple average of observation points is assumed to be sufficient. A systematic research approach was followed in which a three-step process was used to evaluate methods of calculating these mean values. In the first instance a conceptual model approach was used, and all bulk flow parameters were generated by means of matrices to represent the natural system. Three typically employed mean values (arithmetic, geometric and harmonic) were calculated for two different dimensional matrices, i.e., N x N (N = 100 and 1000) with different hydraulic conductivity zones. In addition the relative difference between these hydraulic conductivity zones were steadily increased to mimic observed parameters in the field, i.e. typical hydraulic conductivity of shale (K = 0.01 m/d) versus a fracture zone (K = 100 m/d). In all instances the harmonic mean performed the best and as the number of sample sets were increased, a reduction in mean values were observed. As part of the conceptual model approach, two typically encountered scenarios were investigated, i.e. natural flow and forced gradient conditions. Under these two scenario conditions the harmonic mean performed the best to estimate the actual observed hydraulic conductivity value. Secondly, case studies were presented which highlighted the influence of sample size on observed parameters. Additionally, the effect of the differences between the low and high hydraulic conductivity zones on the calculated mean value as a function of sample size, was also reported. In all of these case studies the harmonic mean was the closest in approximating the observed hydraulic conductivity. It is evident from this section that the number of host rock (formation) hydraulic conductivity values plays a critical part in the mean value calculation since it is general practice in South Africa not to report low yielding borehole hydraulic test values. In the third step, the results were discussed in the context of a more general approach to the problem of calculating a regional mean hydraulic conductivity of transmissivity value. The estimation of representa-tive transmissivity values were discussed as seen from a stochastic modelling perspective as well as from the deterministic point of view. A comparison between main stream groundwater and oil industry specialists were noted in which both groups share the fundamental training but differ on the methodology of determining the observed transmissivity values. The impact of horizontal heterogeneities and different fracture networks was discussed and the influence these features have on the actual transmissivity value obtained, i.e. the influence of internal boundaries on hydraulic test data. Scale effects were also addressed from a regional perspective, with a focus on apparent scaling and the actual regional transmissivity value which should be obtained. The findings of this study are that in essence using geostatistical methods are not advised if regional transmissivity values are required from a South African perspective. The reason behind this statement is that the distribution of transmissivity values in an area does not follow the basic precepts that are required for these methods to work. In general the values are discontinuous in distribution and statistically skewed. Furthermore, the presence of transmissivity areas or points that differ significantly in magnitude, i.e. transmissivity values which differ by more than two orders, can be located within one meter from each other. The explanation of this phenomenon is the presence of dolerite dykes, which create baked-fractured zones with exceptionally large transmissivity values compared to the extremely low transmissivity ranges of the surrounding country rock (shales, mudstone and siltstone). In addition, the lack of data concerning low-yielding or âdryâ boreholes is a major source of concern since it influences the calculated mean value to a high degree.
138

EVALUATION OF ACID ROCK DRAINAGE POTENTIAL IN THE WATERBERG COALFIELD

Aphane, Velapi Venessa 21 August 2014 (has links)
Acid Rock Drainage (ARD) is expected to take place as soon as rock or coal that consists of sulphide minerals is exposed to the surface and comes into contact with oxygen and water. Water not only acts as catalyst, but also as a transportation medium of the yellow boy precipitates which in turn deteriorates the condition of the environment as well as water resources. Due to the long-term irreversible impact that ARD has, minimisation of this condition is an important factor to be looked at by mining companies. Worst cases have been reported by the Department of Water Affairs in and around coal and gold mines in the Witwatersrand and Witbank areas. This has brought about a necessity to explore pre-mining investigations into different lithologies to be aware of possible changes that might occur in the environment once mining commences. An evaluation of ARD was also done on the coal and rock samples to have better knowledge of what will be released in the environment and water resources as more mines are introduced in the Waterberg Coalfield.. Controlling ARD means to control the acid generating reactions of which mineralogy stands at the core of the whole reaction process. Coal deposits in South Africa largely consist of shales; mudstones, siltstones and sandstones which contain clay minerals, quartz, carbonates and sulphides. Problems that are associated with ARD (results) include decreased pH values and increased values of metals, acidity, sulphate and dissolved and suspended solids. The sulphate concentration is caused by sulphide minerals that are in the mining environment and undergo oxidation, thus bringing out the presence of sulphate. The investigation took place in four areas, namely Resgen, Grootegeluk (Exxaro), Sasol and Sekoko. A total of 214 samples were selected from the borehole core to conduct an Acid Base Accounting (ABA) (from the interburden, overburden and coal samples), 29 samples were selected for whole rock and mineralogical analysis, and 8 selected for kinetic tests. Results from the ABA and the kinetic tests leachate were further analysed for major and trace elements using the ICP-OES (Inductively Coupled Plasma- Optical Emission Spectrometer). ABA results show that the interburden and coal samples have a higher risk of producing acid upon oxidation when comparing it to overburden samples. They have a higher concentration of neutralising minerals that can neutralise the acid produced through sulphide minerals as oxidation takes place. In the Sasol samples, which were collected from the full succession that includes the Volksrust and the Vryheid formation, the closed Net Neutralising Potential (NNP) varied from -306.19 to 121.05 kg/tonne CaCO3. The results indicate that there is higher potential of acid production than neutralisation. Grootegeluk samples taken from the overburden showed a closed NNP that varied between -0.33 to 310.80 kg/tonne CaCO3 which classifies the samples as having more potential of neutralisation than acidification; the same case applies for Resgen with closed NNP that is between -68.96 and 57.74 kg/tonne CaCO3. Sekoko consists of the lowest number of samples that have a low risk of acid generation with more samples having a sulphide âS that is more than 0.3%. Mineralogical analysis indicates that there is a presence of pyrite, calcite and dolomite present in accessory to minor concentration. Minerals quartz and kaolinite are found in all the samples constituted in major to dominant concentrations. Results from the whole rock analysis which correlate with mineralogical analysis were SiO2 and Al2O3 which have the highest weight percentage and is similar to the presence of quartz and kaolinite. The average Fe2O3 that is 6.73 wt.% for Sasol and 3.28 wt.% for Resgen, is higher than the average CaO and MgO which is the result of the calcite and dolomite mineral. Leachate analysis from the ABA shows that metals become more soluble as acidity increases. An increase was noted in metals such as iron, magnesium and cadmium, which is a greater threat than the acidity that results from the drainage. Further tests were carried out after the completion of the ABA analysis; kinetic tests were performed on samples that gave inconclusive NNP results. The analysis showed the long-term behaviour of different samples with the EC and pH changing over time. Samples with a lower pH continue to produce more sulphate, while calcium continues to increase until it is depleted from the samples. The Waterberg Coalfield has not yet experienced major environmental deteriorations due to ARD; this is likely to change as more mines will be added to the area.
139

Creation and implementation of a pilot prenatal fitness program / Prenatal fitness program.

Rains, Daniel P. January 1979 (has links)
Using information available in the medical and sports medicine literature, a pilot program of exercise for pregnant women was designed for implementation at the local YMCA. The exercises consisted of 1) calisthenics and stretching exercises performed for 20 to 30 minutes and 2) a similar time period of aerobic exercise at no more than 70 percent predicted maximum pulse. Each of these was conducted formally three times weekly with participants urged to perform the exercises on their own at additional times. A group of nine women was followed from 14-16 weeks gestation through delivery and for 6 weeks postpartum and was matched with a group of four nonexercising controls. Both groups were tested by predicted maximum oxygen uptake during bicycle ergometer testing. To date, 37 women have participated and delivered with no untoward side effects in either mothers or offspring. In addition, considerable subjective benefits were stated by participants. Objective quantification of these benefits requires greater numbers of participants and controls, a longer period of time (estimate 3 years) to complete data collection, and more vigorous data collection in terms of reproducibility and meeting the schedule desired.
140

COMPOSITION AND PERFORMANCE OF MULTIâLAYER LINER SYSTEMS TO INHIBIT CONTAMINANT TRANSPORT IN A FLYâASH DUMP

Mokhahlane, Lehlohonolo 13 May 2014 (has links)
The engineering properties of a South African class F fly ash were studied as a potential base liner for a dry coal ash dump. In order to increase the unconfined compression strength, lime and gypsum were added to the fly ash while also aiding in reducing the hydraulic conductivity. Lime was added in the range of 1 to 10% while the gypsum amounts were varied at 1% and 3% per specimen. The constant head method was used to determine the hydraulic conductivity of compacted specimens in the laboratory. Gypsum was observed to have more influence in reducing the hydraulic conductivity as specimens with 3% gypsum had a more reduced hydraulic conductivity that those with 1%. The variations in lime percentages did not appear to reduce the hydraulic conductivity but rather displayed higher values than fly ash specimens without additives when higher percentages of lime were used. A fly ash admixture of 3% lime and 3% gypsum was found to have the lowest hydraulic conductivity of 2.27 x10-9 m/s after 60 days of percolating with brine water. The unconfined compression strength also appeared to be more influenced by gypsum than lime percentages as specimens with 3% gypsum obtained higher strength values than those with 1% gypsum added. Unreacted lime was observed in specimens with higher percentages of lime added and these specimens also presented lower strength values. The addition of lime and gypsum was observed to have limited the release of some trace elements from fly ash. The secondary mineral ettringite was detected and could have possibly precipitated and captured out these toxic elements. An attempt was also made to increase the plasticity index of fly ash using lignosulphonate and values recommended by the South African legislative guidelines for liner materials were obtained. The plasticity was however not retained with subsequent leaching. Two multi-layer liner systems were loaded under different compaction rates in permeameter cells with fitted inflow and outflow points. The primary liners of both systems were able to contain over 95% of leachate that percolated through a waste layer. Compaction rate was found to affect the liners performance as primary liners with a higher compaction rate had less seepage than primary liner compacted at a lower rate. An addition of lime and gypsum improved the overall engineering properties of fly ash to levels accepted by the South African legislative guidelines for a liner material that is able to line hazardous waste. Even though concentrations of some trace elements in fly ash were reduced by addition of lime and gypsum the level of some of these trace elements remain above the threshold set by South African legislative guidelines and therefore remains a health and environmental concern.

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