The aim of this diploma thesis is to conduct optical and photovoltaic characterization of derivatives of diketopyrrolopyrrole (DPP) as materials suitable for fabrication of bulk heterojunction organic solar cells. The charge transfer from donor material (DPP) to acceptor material (PCBM) is studied by a quenching of fluorescence. The photovoltaic response is studied by current – voltage characteristic which can tell us crucial parameters such as shor circuit current density Jsc, open circuit voltage Voc, fill factor FF and power conversion efficiency PCE. Optical characterization was carried out for symmetrical DPP derivatives (U69 and U97) which both contained diphenylaminstilbene moiety and differed in N-alkyl group. On the other hand photovoltaic characterization was conducted for analogous but asymmetrical materials (U70 and U99). Material U29 was characterized as well but its properties proved to be very poor. Both these characterizations tell us that materials with shorter solubilization groups (U69 and U99) are more suitable candidates. Achieved PCE for U70 was 0,74 % and for U99 up to 1,39 %. From these values one can say that small molecule organic materials can be used for fabrication of solar cells.

The subject of this diploma thesis is to analyse solar cells, demonstrate linearized model of PN junction and show basic techniques of measurement of this model. Solar cells measurement and acquired results are also presented.

Objective of master’s thesis theoretical part is especially to illustrate influence of operation conditions, such as solar radiation, temperature or pollution of photovoltaic generator active area, on load and power characteristics of photovoltaic generator, or more precisely on photovoltaic conversion efficiency. Possible variants of increasing effectivity of using photovoltaic generator are explored, such as solar radiation concentration, photovoltaic generator active area cooling or aplication of optimalization circuit. Pivotal part of master‘s thesis is focused on experimental device practical realisation, concretely type MSQ36-10 photovoltaic generator with oriented concentrators of solar radiation. Practical realisation includes design of master‘s thesis experimental part construction with subsequent design of photovoltaic generator motion cycle necessary for adequate simulation of configuration variants solved using single testing photovoltaic generator. Description of own experimental device construction with list of measuring places used in task takes up. It is used automatic monitoring system working as independent measurement task for required values measuring and consecutive data collecting. It is done in two phases. First phase is measurement of all required values, in second phase measurement with attached optimalization circuit is made. Optimalization circuit sets best working point of photovoltaic generator according to actual working conditions. Master‘s thesis intention is experimental verification of solar radiation concentrators application convenience, orientation of photovoltaic generator or its mutual combination, namely using type MSQ36-10 photovoltaic generator. Objective is evaluation of reached energetic gain for all experimental device layouts in variable operating conditions.

In mentioned theses there are described the basic tenets of the photovoltaic panels operation. There is described the progress of the photovoltaic panels. Theses is focused on the theoretical knowledges about the equivalent circuits and their aplication in the proposed simulation system. The goal of theses is to create the surroundings in the program Agilent VEE Pro 8.0 and to create the program for the simulation of the serial and paralel conjunction of the photovoltaic panels. The resultant program enables the simulation of the I – V and P – V characteristics of the real photovoltaic panels.

In the opening part of this master´s thesis there is given concept, description, usage and advantages of micro hybrid grids in comparison to micro grids and there are evolution steps towards hybrid grid. There is also a mention about economics of operation of these grids. In the second part of this thesis there are descriptions of devices that are suitable for usage in micro hybrid grids with emphasis on generators and accumulation possibilities. In the next part of this thesis there is given an approach and description for modeling of various components of hybrid grids in PSCAD environment. In the next part of this thesis there are given simulation results that were conducted on created model. Especially power balance in 24 hour operation of the grid with method for determining suitable size of accumulation and installed capacity of photovoltaics. And next there are showed responses from change of power from photovoltaics, next there is a transition to islanded mode and last there is showed the behavior of converter when the limits of accumulation are reached. In the final part of this thesis there are conclusions, fulfillment of goals of this thesis and possibilities of further study.

The work deals with the measurement of CV characteristics of photovoltaic cells and the consequent derivation of the free / bound charge in the volume. It also discusses factors that influence these measurements.

This thesis describes the design of the active load for adjusting the maximum power point of PV module and the module loaded with the defined parameters for measuring the effectiveness and identifying the characteristics of the PV module.

This master’s thesis deals with the problem of thin film solar cells, their parameters and measuring. The introductory chapter describes the properties of individual thin-film technology, summarizes their advantages against the crystalline silicon cell. Another chapter is exclusively focused on thin-film cells based on amorphous silicon. There is described the manufacturing processes of amorphous cells and modifications performed during the manufacturing. One part of master’s thesis is dedicated to the description of basic electrical quantities and PV cell degradation mechanisms that negatively affect these electrical properties. It is explained in detail the most important degradation phenomenon called Steabler - Wronski effect. The master’s thesis describes standards regarding testing amorphous cells as well as method, how to achieve their performance stability. The practical part is focused on the testing of several single-layer amorphous cells that were exposed to degradation and regeneration effects. One part of the thesis is studying of a new method of testing of amorphous cell, where is necessary to determine whether it is the degradation or regeneration process. Measured values obtained from several types of measurements were compared, evaluated and displayed in the graphs. The recommendation for future testing of amorphous article is stated in the final chapter.

This diploma thesis deals with the issues of photovoltaic cells. The main aim of this thesis is to introduce the principles of operation of solar cells and methods of detection of defects affecting their quality. The first part is about the functional properties of silicon cells and it also examines the possibilities of detecting the defects of these structures. It also describes the most commonly used modern diagnostic methods. In the next part, practical tests of photovoltaic cells using the methods electroluminescence and photoluminescence are performed. These methods are based on the excitation of luminescence radiation of the silicon material by the external light source.

The master’s thesis deals with the principle of the photoelectric effect, the composition of the photovoltaic cell and different types of solar panels. Here is described the principle of converting wind energy into electricity. This master’s thesis describes reasons for using of the hybrid system. The next section describes the measurement system which is used to measure real operating statuses. The last section is an analysis of measured values and there are listed factors influencing the design of hybrid power system.