No description available.

Thesis (M.Eng.)--University of Wollongong, 2007. / Typescript. Includes bibliographical references: leaf 94-98.

No description available.

The increase in environmental levels of platinum can in part be attributed to the introduction of motor vehicle catalytic converters. Quadrupole inductively coupled plasma mass spectrometry (Q-ICP-MS) has been evaluated as a analytical tool for the determination of platinum in environmental samples, such as vegetation, roadside dust, soil and sediment. Instrumental parameters were studied and a forward power of 1.4 kW and nebuliser flow rate of 0.95 1 min-1 were shown to give the optimum signal response for the 195Pt+ isotope. A detection limit of 0.12 ng ml-1 was achieved. Iridium was shown to be the most suitable choice for use as an internal standard with the 191Ir+ isotope being monitored. Various digestion methods were studied with aqua regia / hydrofluoric acid open vessel digestion being found to give good recovery for 2 certified reference materials, NIST 2556 (Used Autocatalyst, Pellets) and 2557 Used Autocatalyst, Monolith) with concentrations of 681 (38) mug g-1 and 1085 (32) mug g-1 respectively [certified values 697.4 (2.3) mug g-1 and 1131 (11) mug g-1]. Attention has been given to the problem of spectroscopic interference on 195Pt+ from hafnium oxide. Various correction methods were evaluated with a modification proposed to a previous method of mathematical correction being found to provide the best correction for the 179Hf16O+. An 'in-house' reference sample was prepared from a used catalytic converter and its platinum content of 3563 (176) ng g-1 established through inter-laboratory and inter-method procedures. Common rye grass (Lolium perenne) was shown to uptake platinum from both solid and liquid platinum-containing matrices. The methods developed were applied to a study of roadside dust samples taken from a busy section of the London M25 orbital motorway. The measured platinum levels of up to 194 ng g-1 agree with published literature from other European countries and represent a useful contribution to the knowledge concerning roadside platinum in the UK.

Welding is a common metal fabrication process within industry. Epidemiology suggests that welders as an occupational group demonstrate slight, but significant, increased risks of respiratory ill-health. This might be expected as welding processes often present high levels of occupational exposure to oxidising gasses and weld fumes which are often inadequately controlled through local exhaust ventilation or personal respiratory protection because of high costs and the burden of worker participation. Fundamental control strategies of occupational hygiene encourage development and use of engineering controls as the best means to optimally control occupational exposure. However, engineering controls have not yet been successfully developed to control occupational exposure to welding fume and gases. This thesis investigates the interrelationships between ultra-violet radiation (UV). ozone (0:;). and hexavalent chromium (CrVI) in metal inert gas (MIG) welding in order to investigate possible methods to control occupational exposure to welding fume and gases by engineering contro!' Past studies of occupational ill-health in welders are reviewed as is the currently understanding of the physico-chemical principles by which the various components of welding fume evolves. Experiments were designed to investigate the mechanisms of formation of UV, 0 3 and CrVI formation from which a number of possible control strategies were developed further. Among these results emerge two process modifications with exciting potential to reduce two toxic components. 0, and CrVI , in stainless steel welding fume and gas. The addition of trace amounts of Zinc to chromium containing steel wires virtually eliminates all 0, and significantly reduces hexavalent chromium within the weld plume. As Zn is a volatile metal, it does not contaminate weld quality but increases the zinc oxide le\els in the fume slightly. A second method developed in this thesis involves the addition of a dual shield gas shroud containing reducing gases such as C2H .. to remove 0, and consequently. reduce Cr(VI) levels. Preliminary results suggest that these methods can be used separately. or in combination, to provide a practical means of controlling occupational exposure to two of the more toxic components of welding fume and gases. This thesis describes in details the experiments and results culminating in successful preliminary development of engineering controls for 0 3 and CrVI through process modification of the stainless steel MIG welding process. Further work for further development of these methods is outlined and funding to extend this area of applied research is being actively pursued with the support of major UK industry.

No description available.

Aims and objectives: The general aim of this study was to determine the personal respiratory exposure and biological monitoring of manganese (Mn) present in welding fumes as well as its neurological influence on welders. The objectives of this study were: (i) to assess the respiratory exposure of welders to Mn present in welding fumes; (ii) to assess the biological Mn load of welders via the use of nail clippings; (iii) to establish possible correlations between respiratory exposure to Mn and its presence in nail clippings, and (iv) to determine the possible difference in finger dexterity and coordination between Mn exposed welders and a control group. Methods: A gravimetrical method was used to determine the respiratory exposure of welders. A cassette containing a 0.8-μm, cellulose ester membrane filter, attached to the side of a welding helmet provided, was connected via a stainless steel fitting to the inside (respiratory zone) of the helmet. Chemical analysis (metal content) of the welding fumes was done according to the NIOSH 7300 method, using Inductively Coupled Argon Plasma, Atomic Emission Spectroscopy (ICP-AES). Nail clippings were collected at the beginning and end of the study to determine the Mn level in the nails in both welders as well as paired controls. The nails were deposited into small, plastic vials and also analysed according to the NIOSH 7300 method. A Perdue pegboard and mirror drawing test was also conducted to determine the influence of Mn exposure on finger dexterity and hand-eye coordination of welders. Results: Mn exposure in the welding fumes did not exceed the occupational exposure limit – recommended limit (OEL-RL) (1 mg/m3) of the Regulations for Hazardous Chemical Substances (RHCS), although two of these exposures exceeded the action level (0.5 mg/m3). No statistical significant correlations were found between the Mn respiratory exposure and the Mn found in the nails of the welders. Mn in the nails of exposed welders was statistical significantly higher (p = 0.003) than that of controls. The only statistical significant differences found in the motor function tests between the controls and welders were the test which was done by using their non-dominant hand in the beginning of the study (p = 0.016) and when the non-dominant hand values were pooled (p = 0.012). The usage of both hands simultaneously showed results that leaned toward statistical significant decrease of the welders compared to the control subjects (p = 0.090). In all these cases the controls inserted more pins than the welders. Only one moderately positive correlation (r = 0.612; p = 0.02) was found between Mn in the welding fumes and the number of errors made in the mirror drawing coordination test done by the welders. Discussion and Conclusions: The Mn in the nails of the control group was significantly lower than the Mn in the nails of the welders. This indicates that Mn respiratory exposure may influence Mn body burden although no correlation between Mn in welding fumes and Mn in nails were found. Nail Mn may serve as a biomarker to determine Mn body burden. Only the use of the non-dominant hand of the control subjects compared to the welders showed a significant decrease in finger dexterity of the welders. The moderately positive association between the Mn in the welding fumes and the number of errors made in the mirror drawing coordination test done by the welders indicates that with an increase in Mn in welding fumes, a decrease in hand-eye coordination will occur. It can be concluded that welders’ finger dexterity and hand-eye coordination may be influenced by the exposure to Mn in the welding fumes. / Thesis (MSc (Occupational Hygiene))--North-West University, Potchefstroom Campus, 2013

Aims and objectives: The general aim of this study was to determine the personal respiratory exposure and biological monitoring of manganese (Mn) present in welding fumes as well as its neurological influence on welders. The objectives of this study were: (i) to assess the respiratory exposure of welders to Mn present in welding fumes; (ii) to assess the biological Mn load of welders via the use of nail clippings; (iii) to establish possible correlations between respiratory exposure to Mn and its presence in nail clippings, and (iv) to determine the possible difference in finger dexterity and coordination between Mn exposed welders and a control group. Methods: A gravimetrical method was used to determine the respiratory exposure of welders. A cassette containing a 0.8-μm, cellulose ester membrane filter, attached to the side of a welding helmet provided, was connected via a stainless steel fitting to the inside (respiratory zone) of the helmet. Chemical analysis (metal content) of the welding fumes was done according to the NIOSH 7300 method, using Inductively Coupled Argon Plasma, Atomic Emission Spectroscopy (ICP-AES). Nail clippings were collected at the beginning and end of the study to determine the Mn level in the nails in both welders as well as paired controls. The nails were deposited into small, plastic vials and also analysed according to the NIOSH 7300 method. A Perdue pegboard and mirror drawing test was also conducted to determine the influence of Mn exposure on finger dexterity and hand-eye coordination of welders. Results: Mn exposure in the welding fumes did not exceed the occupational exposure limit – recommended limit (OEL-RL) (1 mg/m3) of the Regulations for Hazardous Chemical Substances (RHCS), although two of these exposures exceeded the action level (0.5 mg/m3). No statistical significant correlations were found between the Mn respiratory exposure and the Mn found in the nails of the welders. Mn in the nails of exposed welders was statistical significantly higher (p = 0.003) than that of controls. The only statistical significant differences found in the motor function tests between the controls and welders were the test which was done by using their non-dominant hand in the beginning of the study (p = 0.016) and when the non-dominant hand values were pooled (p = 0.012). The usage of both hands simultaneously showed results that leaned toward statistical significant decrease of the welders compared to the control subjects (p = 0.090). In all these cases the controls inserted more pins than the welders. Only one moderately positive correlation (r = 0.612; p = 0.02) was found between Mn in the welding fumes and the number of errors made in the mirror drawing coordination test done by the welders. Discussion and Conclusions: The Mn in the nails of the control group was significantly lower than the Mn in the nails of the welders. This indicates that Mn respiratory exposure may influence Mn body burden although no correlation between Mn in welding fumes and Mn in nails were found. Nail Mn may serve as a biomarker to determine Mn body burden. Only the use of the non-dominant hand of the control subjects compared to the welders showed a significant decrease in finger dexterity of the welders. The moderately positive association between the Mn in the welding fumes and the number of errors made in the mirror drawing coordination test done by the welders indicates that with an increase in Mn in welding fumes, a decrease in hand-eye coordination will occur. It can be concluded that welders’ finger dexterity and hand-eye coordination may be influenced by the exposure to Mn in the welding fumes. / Thesis (MSc (Occupational Hygiene))--North-West University, Potchefstroom Campus, 2013

Thesis (Ph.D.)--University of Wollongong, 2004. / Typescript. Includes bibliographical references: leaf 227-237.

Welding is today seen as one of the most dangerous professions on earth, mostly because of the toxic fumes. These fumes can lead to a variety of diseases and in worst case death. Now imagine this problem when you are working at different places every day and you can not always bring the equipment needed to protect your health since they are either too big or does not have enough capacity. This is a problem which welders that work at temporary workplaces have to face every day. With this project I have looked into this problem and come up with a product that makes the temporary workplaces safer and at the same time keeps an efficient workflow.