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N-Heterocyclic carbene containing element organic frameworks as heterogeneous organocatalystsRose, Marcus, Notzon, Andreas, Heitbaum, Maja, Nickerl, Georg, Paasch, Silvia, Brunner, Eike, Glorius, Frank, Kaskel, Stefan January 2011 (has links)
A bifunctional imidazolium linker was used for the production of highly crosslinked element organic frameworks by Suzuki-coupling with tetrafunctional boronic acids. The resulting porous materials are good heterogeneous organocatalysts in the N-heterocyclic carbene-catalyzed conjugated umpolung of α,β-unsaturated cinnamaldehyde. / Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich.
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