This thesis work is a continuation of a project aimed at the consolidation of insulation material (IM) to produce porous ceramics with sufficient porosity and compression strength for post-insulation of buildings. The porous structure and contact points are tailored to produce IM with ultra-low thermal conductivity.  One of the main goals is to introduce expandable microspheres, that are perfect lightweight fillers and blowing agents into production. They are relatively new materials in the market which are used to manufacture products with low weight and controlled foam structure. Therefore, it is of interest to be integrated into the construction field as a component for insulating materials.  The project is built on the advanced structuring of porous materials with tailored porosity to offer 5-10 times lower thermal conductivity value providing adequate insulation with an insulation cover of 2-10 mm in thickness. Enhancing the insulating capacity allows to limit the use of energy to improve energy efficiency. Thus, less energy is required to heat or cool the indoor climate. The success in achieving such thin effective IM will eliminate the need for any modification of existing window frames, electrical and heating installations. In the first stage, it is necessary to confirm the entire concept of creating a thermal IM with a controlled porous structure using various compositions of materials and an assessment of the structure, porosity, and functional properties. This project focuses on developing a composition of ceramic panels. The various components of the ceramic panels including the type of ceramic are adjusted and their effects on the composition are described. Pure alumina, activated alumina and silica have been investigated to find the optimized quality and price. In addition, various methods and conditions have been implemented for panel fabrication.  Prototypes of ceramic panels are prepared for demonstration, followed by upscaling at the facilities of industrial partners. The project has been performed in collaboration with companies i.e., Nouryon, HIPOR Materials AB, and LindePac AB as the industrial partner.

Alumina based transparent ceramic bodies were prepared within this diploma thesis by the gel casting process followed by presintering to closed porosity stage with subsequent hot isostatic pressing. The problematic drying of large bodies was solved by means of careful temperature and relative humidity control and by osmotic drying. Almost perfectly dense ceramics were achieved thanks to colloidal processing of TM-DAR and TM-UF ceramic powders providing a final structure with grain size of 381 nm, resp. 302 nm. High real in-line transmission of 72,3 % was achieved at wavelength of 632,8 nm and thickness of 0,8 mm. Among mechanical properties high values of hardness HV10 = 22,5 GPa, fracture toughness KIC = 3,99 MPam0,5, Young’s modulus E = 400 GPa a bending strength o = 494 MPa were achieved.

Diploma thesis is focused on development of method for preparation individualized bioscaffolds prepared by milling of HA foam prepared by gel casting method and consolidated via epoxy curing reaction. Diploma thesis continues in bachelor thesis Modern processing methods of porous bioceramics. Literature search is filled in the newest knowledge from the field of bioactivity enhancement of scaffolds. Experimental part of diploma thesis described development of system for individualized scaffold manufacturing from HA suspension preparation, preparation of ceramic blocks used as material for machining to final blocks machining. Pressure strength of foam were evaluated, too. Chosen samples were coated with calcium polyphosphate coating for biological response enhancement. Coated samples were given for in-vivo test to partner university in Beijing under the terms of project FP7-NMP-2013-EU-China: "Bioscaffolds"

Macroporous ceramic materials have found widespread technological application ranging from particulate filters in diesel engines, tissue engineering scaffolds, and as support materials in carbon capture processes. This thesis demonstrates how the pore space of macroporous alumina can be manipulated, analysed in three-dimensions (3D) using visualisation techniques, and functionalised with a CO2-adsorbing material. A novel method was developed to produce macroporous alumina materials: by combining sacrificial templating with thermally expandable polymeric microspheres and gel-casting of an alumina suspension. This method offers a versatile production of macroporous ceramics in which the level of porosity and the pore size distribution can easily be altered by varying the amount and type of spheres. The permeability to fluid flow could be regulated by controlling the connectivity of the pore space and the size of the smallest constrictions between the pores. Sacrificial templating with particle-coated expandable spheres significantly increased the fraction of isolated pore clusters and reduced both the sizes and the numbers of connections between neighbouring pores, compared to templating with un-coated spheres. The macroporous alumina materials were characterised with X-ray micro-computed tomography (μ-CT). The 3D data-sets obtained by X-ray μ-CT were used to calculate the spatial variation in porosity, the throat and pore size distributions and to calculate the permeability to fluid flow. The throat and pore size distributions were also able to be accurately quantified in only one extrusion and intrusion cycle with water-based porosimetry; a relatively novel and simple characterisation technique. The pore walls of the macroporous alumina materials were also coated with zeolite films by a colloidal processing technique. The CO2-uptake of the coated alumina materials and of hierarchically porous monoliths of zeolites was evaluated and compared. / As the time of the doctoral defense, the following papers were unpublished and had a status as follows: Paper 2: Submitted. Paper 4: Accepted. Paper 5: Manuscript. Paper 6: Submitted.