M.Sc. (Geology) / Please refer to full text to view abstract

The 2.9 Ga old Usushwana Complex in the Piet Retief-Amsterdam area (south-eastern Transvaal) represents an exposed segment of a layered intrusion. It has the form of a dyke-like body elongated in a northwesterly direction, and extends to an estimated depth of 3000 -5500 m. Lithologically, the Complex consists of a cumulate succession of mafic rocks capped by granitoids and has intruded along the contact between the basement and the supracrustal sequences of the Kaapvaal Craton. Differentiation of an already contaminated gabbroic magma resulted in an ordered stratigraphic sequence comprising progressively more evolved lithotypes, with at least two imperfect cyclic units developed over a stratigraphic thickness of about 700 metres (Hlelo River Section). Meso- to orthocumulate textured gabbros and quartz gabbros grade upwards into magnetite- and apatite-bearing quartz gabbros, interlayered with discontinuous magnetitite horizons. The gabbros in turn grade into hornblende-rich, granophyric granodiorites. The differentiation process is regarded as having been considerably enhanced by the assimilation of acidic material, derived by partial melting of the felsic country rocks at the roof of the magma chamber. Recrystallisation of these rocks gave rise to the microgranites that locally overlie the granodiorites. Mineralogical, textural and geochemical features indicate a relatively advanced fractionation stage, suggesting that the exposed sequence of the Usushwana Complex in the study area represents the upper portion of the intrusion. No significant mineralised occurrences were identified. However, on the basis of similarities between the Usushwana Complex and other mafic layered intrusions which host significant ore deposits, it is suggested that economic concentrations of base metal(Cu-Ni) sulphides, PGE and chromitites are likely to be developed at lower stratigraphic levels.

Bibliography: pages 100-109. / The Kaap Valley Tonalite (KVT) was a homogenous hornblende+ biotite tonalite that had been subjected to overail propylitic and potassic alteration. Petrographic studies reveal that carbonate alteration and increased proportions of hydrous minerals occur along the KVT and Barberton greenstone belt contact zone, and along major shear zones within the KVT.

This study lias initiated with the aim of identifying the existence of any geochemical criteria which may be used to distinguish between the various volcanic formations within the Witwatersrand triad. The Witwatersrand triad comprises three sequences: the Dominion Group at the base, the Witwatersrand Supergroup in the middle, and the Ventersdorp Supergroup at the top. It is underlain by Archaean basement rocks, and covered by rocks of the Transvaal sequence. The Dominion Group consists of the sedimentary Rhenosterspruit quartzite Formation at the base, overlain by a bimodal component of the Syferfontein Porphyry succession of lavas. Basaltic lavas are the major component of the Rhenosterhoek Formation, while the overlying Formation consists primarily of dacitic porphyries. Intercalations of one lava type within the other are common, however, so each formation is not the exclusive domain of only one lava type. The Witwatersrand Supergroup, a predominantly argillaceous and arenaceous sequence, contains two narrow volcanic horizons, one of wbich, the Jeppestown Amygdaloid (now Crown Formation), consisting of tholeiitic andesites, occurs in the study area. The overlying Ventersdorp Supergroup has, at its base, the basaltic Klipriviersberg Group, of which four out of six formations are present in the study area, namely, the Alberton, Orkney, Loraine and Edenville Formations. This group is succeeded unconformably by the PIatberg Group, consisting of the sedimentary Kameel doorns Formation, followed by the (informal) Goedgenoeg, Makwassie Quartz Porphyry and Rietgat Formations. The Goedgenoeg and Rietgat Formations are basaltic, whil e the Mawassie rocks range from basaltic to dacitic, the majority being tholeiitic andesites and andesites . The Pniel sequence at the top of the Ventersdorp Supergroup consists of the sedimentary Bothaville Formation, and the Allarridge Formation, the lavas of which are basaltic with some andesitic tendencies. A well-defined geochemical stratigraphy was found to exist. From the eleven volcanic formations examined, nine distinct geochemical units emerged, as the Loraine and Edenville Formations were found to have the same geochemical characteristics, as did the Goedgenoeg and Rietgat Formations. Despite having undergone law-grade greenschist facies metamorphism, very clear variation patterns with height are displayed by the immobile elements Ti, P, Kb, Zr and Y, and the light rare earth elements La, Ce and Nd. In contrast, much scatter was observed in the variation patterns of Na, K, Mn, Ba and Rb. Three techniques were employed to effect discrimination between formations - orthosonal discrimination, interelement and ratio vs ratio plots, and discriminant analysis. Confidence limits placed on normal probability plots served to isolate outlier samples for further examination by the various discrimination techniques. A successful test of the efficacy of the discrimination techniques was afforded when fourteen samples from an unknown succession were positively identified as representative of the Klipriviersberg Group

The study area is located between Loskop Dam and the town of Groblersdal, on the southeastern flank of the Dennilton dome, and is underlain by lithologies of the Pretoria Group, Bushveld Complex mafics and ultramafics and acid lavas that resort under the Rooiberg felsites. Field work comprised of geological mapping, soil-, hard-rock- and stream sediment geochemistry, various geophysical techniques and diamond drilling. The rocktypes that resembles the Rustenburg Layered Suite on the farm Rietfontein 70JS is subdivided into a Mixed Zone, Critical Zone and Main Zone, on grounds of geochemical and certain geophysical attributes. The Mixed Zone that overlies the Bushveld Complex floor-rocks, is furthermore separated into an i) Lower-, ii) Middle- and, iii) Upper Unit. The Lower Unit of the Mixed Zone consists primarily of magnetite-gabbros, iron-rich pegmatites, harzburgites and feldspathic pyroxenites. The Fe-rich constituents of this stratigraphic horizon generates a pronounced magnetic anomaly within the study area. On the basis of; amongst other parameters, Zr/Rb and Sr/Al₂0₃ ratios, the magnetite-gabbros are postulated to conform to lithotypes in the vicinity of magnetite layers 8 to 14 of Upper Zone Subzone B in a normal Bushveld Complex stratigraphical scenario. Similarly, it is argued that the feldspathic pyroxenites and norites that display elevated chromium values are analogues to normal Critical Zone rocktypes of the Rustenburg Layered Snite. A more elaborate and precise stratigraphic correlation for the Critical zone was, however, not possible. It is advocated that a volume imbalance was created by the hot, ascending mafic magmas of the intruding Bushveld Complex, resulting in the updoming of certain prevailing basement features such as the Dennilton Dome. In addition to this ideology, it is proposed that the Mineral Range Fragment is in fact a large xenolith underlain by mafics, after being detached from the Dennilton Dome during the intrusion event. Evidence generated by this study unequivocally indicate that the potential for viable PGE's, Ni, Cu and Au within a Merensky Reef- type configuration or a Plat Reef-type scenario under a relatively thin veneer of acid Bushveld Complex roof-rocks on the eastern flank of the Dennilton Dome, appears feasible.

The subject of BIF genesis, particularly their environmental conditions and ocean chemistry at the time of deposition and their evolution through time, has been a subject of much contentiousness, generating a wealth of proposed genetic models and constant refinements thereof over the years. The prevailing paradigm within the various schools of thought, is the widespread and generally agreed upon depositional and diagenetic model(s) which advocate for BIF deposition under anoxic marine conditions. According to the prevailing models, the primary depositional environment would have involved a seawater column whereby soluble Fe²⁺ expelled by hydrothermal activity mixed with free O₂ from the shallow photic zone produced by eukaryotes, forming a high valence iron oxy-hydroxide precursor such as FeOOH or Fe(OH)₃. An alternative biological mechanism producing similar ferric precursors would have been in the form of photo-ferrotrophy, whereby oxidation of ferrous iron to the ferric form took place in the absence of biological O₂ production. Irrespective of the exact mode of primary iron precipitation (which remains contentious to date), the precipitated ferric oxy-hydroxide precursor would have reacted with co-precipitated organic matter, thus acting as a suitable electron acceptor for organic carbon remineralisation through Dissimilatory Iron Reduction (DIR), as also observed in many modern anoxic diagenetic environments. DIR-dominated diagenetic models imply a predominantly diagenetic influence in BIF mineralogy and genesis, and use as key evidence the low δ¹³C values relative to the seawater bicarbonate value of ~0 ‰, which is also thought to have been the dissolved bicarbonate isotope composition in the early Precambrian oceans. The carbon for diagenetic carbonate formation would thus have been sourced through a combination of two end-member sources: pore-fluid bicarbonate at ~0 ‰ and particulate organic carbon at circa -28 ‰, resulting in the intermediate δ¹³C values observed in BIFs today. This study targets 65 drillcore samples of the upper Kuruman and Griquatown BIF from the lower Transvaal Supergroup in the Hotazel area, Northern Cape, South Africa, and sets out to explore key aspects in BIF carbonate petrography and geochemistry that are pertinent to current debates surrounding their interpretation with regard to primary versus diagenetic processes. The focus here rests on applications of carbonate (mainly siderite and ankerite) petrography, mineral chemistry, bulk and mineral-specific carbon isotopes and speciation analyses, with a view to obtaining valuable new insights into BIF carbonates as potential records of ocean chemistry for their bulk carbonate-carbon isotope signature. Evaluation of the present results is done in light of pre-existing, widely accepted diagenetic models against a proposed water-column model for the origin of the carbonate species in BIF. The latter utilises a combination of geochemical attributes of the studied carbonates, including the conspicuous Mn enrichment and stratigraphic variability in Mn/Fe ratio of the Griquatown BIF recorded solely in the carbonate fraction of the rocks. Additionally, the carbon isotope signatures of the Griquatown BIF samples are brought into the discussion and provide insights into the potential causes and mechanisms that may have controlled these signatures in a diagenetic versus primary sedimentary environment. Ultimately, implications of the combined observations, findings and arguments presented in this thesis are presented and discussed with particular respect to the redox evolution and carbon cycle of the ocean system prior to the Great Oxidation Event (GOE). A crucial conclusion reached is that, by contrast to previously-proposed models, diagenesis cannot singularly be the major contributing factor in BIF genesis at least with respect to the carbonate fraction in BIF, as it does not readily explain the carbon isotope and mineral-chemical signatures of carbonates in the Griquatown and uppermost Kuruman BIFs. It is proposed instead that these signatures may well record water-column processes of carbon, manganese and iron cycling, and that carbonate formation in the water column and its subsequent transfer to the precursor BIF sediment constitutes a faithful record of such processes. Corollary to that interpretation is the suggestion that the evidently increasing Mn abundance in the carbonate fraction of the Griquatown BIF up-section would point to a chemically evolving depositional basin with time, from being mainly ferruginous as expressed by Mn-poor BIFs in the lower stratigraphic sections (i.e. Kuruman BF) to more manganiferous as recorded in the upper Griquatown BIF, culminating in the deposition of the abnormally enriched in Mn Hotazel BIF at the stratigraphic top of the Transvaal Supergroup. The Paleoproterozoic ocean must therefore have been characterised by long-term active cycling of organic carbon in the water column in the form of an ancient biological pump, albeit with Fe(III) and subsequently Mn(III,IV) oxy-hydroxides being the key electron acceptors within the water column. The highly reproducible stratigraphic isotope profiles for bulk δ¹³C from similar sections further afield over distances up to 20 km, further corroborate unabatedly that bulk carbonate carbon isotope signatures record water column carbon cycling processes rather than widely-proposed anaerobic diagenetic processes.