No description available.

M.Sc. / Please refer to full text to view abstract

No description available.

A thesis submitted to the Faculty of Science, University of the Witwatersrand, Johannesburg, in fulfilment of the requirements for the degree of Doctor of Philosophy. Johannesburg, 2015. / The Palaeoproterozoic Baoulé-Mossi domain of the West African Craton in northeastern Burkina Faso hosts numerous gold deposits such as Essakane and Tarpako. Integrated strato-tectonic, geophysical, geochemical, geochronological, regional stratigraphic framework and metallogenic studies of the Oudalan-Gorouol volcano-sedimentary Belt and the Gorom-Gorom Granitoid Terrane have provided new insight into the geotectonic evolution of the northeastern part of Burkina Faso. This work outlines the structural context and architecture necessary for forming these deposits. In this work, a new strato-tectonic model is proposed for the area by integrating field data and geophysical, geochemical, and geochronological data. The integrated data highlights and characterizes the setting of the Essakane gold mine and gold camp relative to the location of other regional gold deposits, metamorphosed Birimian Supergroup, intrusive rocks and shear zones. Structural, geochemical and geochronological analyses have helped to clarify the geological evolution of the Oudalan-Gorouol volcano-sedimentary Belt and the Gorom-Gorom Granitoid Terrane during the Tangaean (D1) and Eburnean (D2) orogenies through to the Wabo Tampelse Event (D3). Further to these, zircon U-Pb geochronology data have demonstrated that the Oudalan-Gorouol volcano-sedimentary Belt and the Gorom-Gorom Granitoid Terrane represent some of the oldest outcropping geology in the Palaeoproterozoic Baoulé-Mossi domain recognised to date. The geochronology and geology suggest that the basement or a pre- Birimian crust to the Birimian Supergroup may be found in the northeast of Burkina Faso. The Eburnean Orogeny in northeastern Burkina Faso is preceded by two phases of deformation (D1-x and D1), and two phases of magmatism. The first, D1-x, is associated with the emplacement of the Dori Batholith at the onset of D1 (2164 – 2141 Ma). D1 ductile-brittle deformation formed F1 folds and discrete high-strain mylonite zones that deformed the Oudalan- Gorouol volcano-sedimentary Belt and the Gorom-Gorom Granitoid Terrane during a southwestdirected palaeo-principal compressive stress. The pre-Birimian to Birimian supracrustal rocks and intrusions were regionally metamorphosed during D1 to greenschist to amphibolite facies with development of mineral assemblage of quartz-chlorite-muscovite ± chloritoid to biotite-potash feldspar ± hornblende. D1 is also associated with volcanic arc type calc-alkaline magmatism, producing TTGs enriched in heavy rare earth elements. The Eburnean Orogeny (2130 – 1980 Ma) is characterised by northwest-southeast shortening; it was followed by north-northwest - south-southeast shortening with development of northeast trending sinistral strike-slip faults and shears. D2 brittle-(ductile) deformation is manifested by refolding of F1 by northeast-trending F2, and development of a pervasive northeast-trending S2 to S2-C foliation. Metamorphic grade attained greenschist facies during D2, with development of mineral assemblage of quartz-chlorite-muscovite ± actinolite. The Wabo Tampelse (D3) deformation event is brittle in character and does not significantly affect the regional geological architecture in the study area.

No description available.

A dissertation submitted to the Faculty of Science, University of the Witwatersrand, Johannesburg, in fulfilment of the requirements for the degree of Master of Science. Johannesburg, 2016 / The Mesoproterozoic Pilanesberg Complex, South Africa, is the world’s largest alkaline intrusive complex. Mapped geological field relationships suggest the Complex has circular inward dipping layers. However, it is unclear how the dipping layers extend at depth. As a result, the 3D geometry of the Pilanesberg Complex is unknown. Modelling of the Pilanesberg Complex uses 2D forward models as well as 3D forward and inversion, gravity and magnetic data models, to set limits on the 3D geometry of the Pilanesberg Complex. The 2D Bouguer gravity models and geology maps indicate that some of the Bushveld Complex Main Zone shifted to the west of the Pilanesberg Complex during emplacement. This, and a highly faulted country rock, accounts for a portion of how the host rock was able to accommodate the Pilanesberg Complex intrusion. The geometry of the Complex is explored with test gravity models where the model of outward dipping and vertically dipping cylinders are unable to match the Bouguer gravity signal over the Complex, but the inward dipping model matched the data to provide a possible solution for the geometry of the Complex. The Pilanesberg Complex geometry is modelled with 3D magnetic inversion, 3D forward gravity models and 2.5D gravity test profiles that were all constrained by the surface geology. The different models correlate so that best data fit for the Complex is represented by an overall inward dipping structure. Surface geological measurements indicate that the northern edge of the Complex dip out to the north. The 3D forward modelling was able to produce a positive solution that matched the gravity data with a northward dipping northern edge. The dipping northern edge is also observed on the University of British Columbia, UBC, 3D gravity inversion and the Euler deconvolution gravity profile solutions. The depth of the Pilanesberg Complex from 3D forward gravity modelling is estimated to be between 5 and 6 km. The Complex is suggested to have undergone block movement where the northern block and southern block are separated by the 30 km long Vlakfontein fault, which bisects the Complex from the north-east to the south-west. The image processing contact depth, Euler deconvolution solutions and the 3D Voxi inversion model suggest that the fresh bedrock is closer to surface in the north, while the southern block appears to be approximately 1km deeper than the northern block. The northern dip and block movement are explained by complicated structural events that include trap door graben settling which hinged on the northern edge as well as faulting and external block movement during a regional lateral extensional event. The Pilanesberg Complex intruded during a larger system of alkaline intrusions, known as the Pilanesberg Alkaline Province. The intrusions are associated with the Province due to their ages and chemical affinity. This Province includes two dyke swarms that radiate to the north-west and south of the Pilanesberg Complex, as well as smaller circular clinopyroxenite intrusions throughout the Bushveld Complex. The Pilanesberg dyke system and the circular clinopyroxenite intrusions are reversely magnetised with IGRF corrected values ranging between -150 to -320 nT compared to the normally magnetised 166 to 330 nT values of the Pilanesberg Complex. This suggests that a magnetic reversal occurred between the emplacement of the Pilanesberg Complex and the dyke System. The age data of the Complex and dyke Swarm suggest a magnetic reversal could have occurred between the emplacement of the Pilanesberg Complex and the Pilanesberg dyke System. The Complex is dated at 1602 ± 38 Ma and 1583 ± 10 Ma, from two white foyaite samples from the southern edge (using 40Ar/39Ar amphibole spectrum analysis). These ages are vastly different from previously reported ages, which ranged between 1200 Ma and 1450 Ma (Harmer R., 1992; Hansen et al., 2006). The error analysis has improved considerably from the published dates making the proposed dates plausible for the intrusion of the Pilanesberg Complex as the first and main intrusion of the Pilanesberg Alkaline Province. The Pilanesberg dyke System intruded much later between 1219 ± 6 Ma to 1268 ± 10 Ma for the red syenite dyke samples (using 40Ar/39Ar on feldspars spectrum analysis) and 1139 ± 18 Ma obtained for the grey syenite dyke (using 40Ar/39Ar on amphiboles inverse isochronal analysis). The dyke Swarm dates are significantly younger than the previously published ages for the dykes, which were between 1290 Ma and 1330 Ma (Van Niekerk, 1962; Emerman, 1991). / LG2017

The age of the Bridgerian/Uintan boundary has been regarded as one of the most important outstanding problems in North American Land Mammal “Age” (NALMA) biochronology. The Bridger Basin in southwestern Wyoming preserves one of the best stratigraphic records of the faunal boundary as well as the preceding Bridgerian NALMA. In this dissertation, I first developed a chronological framework for the Eocene Bridger Formation including the age of the boundary, based on a combination of magnetostratigraphy and U-Pb ID-TIMS geochronology. Within the temporal framework, I attempted at making a regional correlation of the boundary-bearing strata within the western U.S., and also assessed the body size evolution of three representative taxa from the Bridger Basin within the context of Early Eocene Climatic Optimum. Integrating radioisotopic, magnetostratigraphic and astronomical data from the early to middle Eocene, I reviewed various calibration models for the Geological Time Scale and intercalibration of 40Ar/39Ar data among laboratories and against U-Pb data, toward the community goal of achieving a high precision and well integrated Geological Time Scale. In Chapter 2, I present a magnetostratigraphy and U-Pb zircon geochronology of the Bridger Formation from the Bridger Basin in southwestern Wyoming. The ~560 meter composite section spans from the lower Bridger B to the Bridger E, including the Bridgerian/Uintan NALMA boundary in the uppermost part of the section. Analysis of samples from 90 sites indicates two paleomagnetic reversals that are correlated to an interval spanning Chrons C22n, C21r, and C21n by comparison to the Geomagnetic Polarity Time Scale (GPTS). This correlation places the Bridgerian/Uintan faunal boundary within Chron C21n, during the initial cooling phase following the peak of the Early Eocene Climatic Optimum. Based on the bio- and magnetostratigraphic correlation, I provide correlation of other Bridgerian/Uintan boundary-bearing sections to the GPTS, demonstrating that in the western North America, the Bridgerian/Uintan boundary occurs everywhere in Chron C21n. In addition, U-Pb zircon geochronological analyses were performed on three ash beds from the Bridger Formation. High-precision U-Pb dates were combined with the paleomagnetic polarity data of the same ash beds as well as the integrative chronostratigraphy of the basin to assess prior calibration models for the Eocene part of the GPTS. The data from the Bridger Formation indicate that the Option 3 age model of Westerhold et al. (2008) best reconciles the geochronological data from all of the ash beds except for one. Thus I favor this Option 3 model, which indicates the ages of 56.33 Ma and 66.08 Ma for the Paleocene-Eocene Thermal Maximum and Cretaceous/Paleogene boundary, respectively. In Chapter 3, the body size evolution of three mammalian taxa from the Bridgerian NALMA was analyzed within the context of Bergmann’s Rule, which poses a correlation between the size of endotherms and climate (latitude). The Bridgerian NALMA is from a time of global cooling following the peak of the Early Eocene Climatic Optimum, thus according to Bergmann’s Rule, the Bridgerian mammals are expected to increase in size. This hypothesis is tested among Notharctus, Hyopsodus, and Orohippus, using the size of molar dentition as a proxy for their body size. These taxa represent three different ecomorphs, and I investigated if these taxa showed a pattern of body size change consistent with the prediction made by Bergmann’s Rule, and how their ecological adaptation may have affected their response to the climate change. Prior to analyzing the body size evolution, specimens of Notharctus and Hyopsodus were identified to species based on dental characters. This practice differs from previous studies in which species identification relied on relative size of the individuals and stratigraphic levels of origin. Within the new framework of morphologically determined species identification, five species of Notharctus were recognized, among which, N. pugnax, N. robustior and N. sp. indet. exhibited statistically significant body size increase in the time span of interest. Based on morphological analyses of Hyopsodus dentition, I recognized five species. Dentition-based body size analysis showed that H. lepidus and H. despiciens exhibited a statistically significant change towards larger size within the sampled interval. When analyzed at the generic level, a statistically significant increase was observed for both Notharctus and Hyopsodus. Finally, a genus-level analysis of Orohippus showed a lack of statistically significant size increase over the study interval. Thus, among the three taxa from the Bridgerian, Bergmann’s Rule is supported by Notharctus and Hyopsodus, at least at the genus level, but not by Orohippus, although the patterns are more variable at the intraspecific level. In Chapter 4, 40Ar/39Ar dates were obtained from sanidines from the middle Eocene Henrys Fork tuff and Upper Carboniferous Fire Clay tonstein, with the goal of making highly precise measurements of these two samples, keyed to the Fish Canyon monitor standard. Analytically, both samples were well characterized, as had been shown previously. The irradiation disk was arranged such that there would have been control from the Fish Canyon surrounding each of the unknown pits. However, due to several complications in the lab during the course of the experiment, only the analyses from one run disk (Disk 677) were of the quality needed for the goals of the study. As a result, the Fish Canyon sanidine standards that were irradiated near the center of the irradiation disk had to be discarded, and thus, the neutron fluence could not be mapped out precisely across the entire disk. The 40Ar/39Ar age relative to Fish Canyon sanidines is 47.828 ± 0.205 Ma and 311.937 ± 1.282 Ma for the Henrys Fork tuff and Fire Clay tonstein, respectively (1σ, including error on the age of the monitor). Because the ages were both offset about the same amount, I explored the option of using the U-Pb ID-TIMS ages of the Henrys Fork tuff and Fire Clay tonstein to test the agreement in the chronometers. The Henrys Fork tuff was dated at 48.260 ± 0.107 Ma (1σ, including error on the age of the monitor) using the Fire Clay sanidines and assuming its age is the U-Pb zircon age. The Fire Clay tonstein was dated at 314.593 ± 0.699 Ma (1σ, including error on the age of the monitor), using the Henrys Fork sanidines and assuming its age is the U/Pb zircon age. Although the complications encountered render these data unpublishable, they show great promise as the ages of each sanidine sample, tied to the other ash using the other ash’s U-Pb age, give results that are in close agreement between the two chronometers on the same sample (e.g., 314.593 ± 0.699 Ma vs. 314.554 ± 0.020 Ma at 1σ for sanidine and zircon respectively from the Fire Clay tonstein, and 48.260 ± 0.107 Ma vs. 48.265 ± 0.008 Ma 1σ for sanidine and zircon respectively from the Henrys Fork tuff).

The development of gently inclined faults with large stratigraphic separation has long been enigmatic in the corridor of southeastern Idaho. Recent interpretations have culled examples from across the Basin and Range to suggest that these faults originated at a low dip and represent a regional scale low-angle normal fault system. In contrast, others cite extensive studies from fault mechanics and seismological data that cast doubt on whether these extensional structures could have formed at low inclination in the upper crust. This dissertation reviews the evidence and timing of the proposed Bannock detachment system in the Bannock Range of southeastern Idaho and puts forth a re-evaluation of the styles of extension in the region and a regional framework in which to place them. Chapter 1 re-evaluates gently dipping normal faults in the southern Bannock Range of southeastern Idaho that have previously been interpreted as evidence for a regional detachment system originating and slipping at a low inclination. Previous work was based on geometrical relations between faults and bedding in lacustrine sediments of the upper Miocene to lower Pliocene Salt Lake Formation. The detachment argument was underpinned by three locations on the Oxford Mountain at which Salt Lake Formation was inferred to have been cut by low-angle normal faults. These locations have been re-evaluated. Two of the locations were found to preserve bedding-to-fault geometries that are well explained by offset from a fault of moderately dipping inclination. The third example is re-interpreted as an unconformable contact, not a fault, an observation that by itself precludes the existence of a detachment at that location. Chapter 2 presents a test of tephronchronology by the 40Ar/39Ar isotopic method. This study compares ages obtained by the geochronologic method of tephrochronology to ages obtained by 40Ar/39Ar single grain laser fusion of feldspars. The results of this study suggest certain considerations must be made when employing the method of tephrochronology for chronological work. Chapter 3 presents a regional synthesis for the tectonics of southeastern Idaho expanding on the new data presented in chapters 1 and 2. 40Ar/39Ar ages obtained from the Salt Lake Formation show evidence that extension in this region was underway > 15 Ma. Bedding-to-fault cutoff angles for the low-angle faults with the largest stratigraphic separations in the region suggest that the now gently inclined normal faults developed with moderate to steep dips, then tilted to lower inclination during continued extension. A splay of the Paris thrust is interpreted to account for both geometric relations between Paleozoic age rocks and the Neoproterozoic Pocatello Formation, as well as an unconformable contact between Pocatello Formation and late Miocene to Pliocene lake deposits of the Salt Lake Formation. This dissertation focuses on one example of a detachment system. However, it has implications for low-angle faults in general – particularly in regions like the Basin and Range that have had a protracted deformation history. The examples we have studied are important because they involve strata as young as Pliocene and they provide strong support for the role of tilting in accounting for the present-day attitude of large-offset normal faults, eliminating the need for the well-known mechanical paradox of low-angle normal fault formation.

Anthropogenic climate change risks significant changes in the global distribution of precipitation. Across the western United States, modelling studies show significant reductions in wetness that imply weighty societal and ecological impacts. But the validity of the model projections need to be ground-truthed. Paleo-hydroclimate data are useful reference points to assess a model’s ability to hindcast past hydroclimate. If the hindcast matches the paleodata, it brings confidence to a model’s ability to predict future hydroclimatic change. The foremost metric of hydroclimate in the geologic record is the surface area of lakes in hydrologically closed basins. In such basins, a lake’s surface area is determined by the balance between precipitation and evaporation. The lake will expand when the balance is positive, and it will contract when the balance is negative. In this dissertation, I develop a 25-9 ka record of lake fluctuation from the Mono Basin, a hydrologically closed basin in east-central California. I deduced the fluctuations using three pieces of evidence: stratigraphy; geomorphology; and geochronology. These pieces of evidence were determined from a study of the Mono Basin’s Late Pleistocene lithostratigraphic unit: the Wilson Creek Formation. There are 19 tephra intercalated in the Wilson Creek tephra. They are named by their reverse depositional order (Ash 19 is the oldest and Ash 1 is the youngest). Uncertainty on their ages cause confusion as to the paleo-hydroclimate record of the Mono Basin. The age of Ash 19, for example, is important because its deposition marks the onset of relatively high lake levels that occurred during the last glaciation. There are two principal interpretations of Ash 19’s age: 40 ka, which is based on lacustrine macrofossil 14C data; and 66 ka, which is underpinned by paleomagnetic intensity data. In chapter 2, I tested these end-member interpretations. I used the U/Th method to date carbonate deposits that underlie and cut across Ash 19. The U/Th data show that Ash 19 must have been deposited between these two dates: 66.8 ± 2.8 ka; and 65.4 ± 0.3 ka. These dates are, therefore, more consistent with the 66 ka interpretation of Ash 19’s age. Thus the onset of relatively high lake levels in the Mono Basin corresponds with the rapid drawdown of atmospheric CO2 during Marine Isotope Stage 4. The coincidence between the drop in atmospheric CO2 and lake level rise is suggestive of a causal link. In chapter 3, I determined Mono Lake's fluctuations 25-9 ka. This time encompasses three climatic intervals: the coolest time of the last glaciation, termed the Last Glacial Maximum (LGM); the period corresponding to the rapid termination of the last glaciation, termed the deglaciation; and the early Holocene, a period of inordinate warmth that immediately followed the last glaciation’s termination. In this study, I used stratigraphic and geomorphic evidence in conjunction with 14C and U/Th dates. I measured the 14C dates on bird bones and charcoal. And I measured the U/Th dates on carbonates. Together the data showed that the lake's rises and falls concurred with North Atlantic climate. Periods of aberrant warmth in the North Atlantic concurred with low stands of Mono Lake. On the other hand, extreme cooling in the North Atlantic correlated with Mono Lake high stands. The timing of these lake fluctuations also corresponds with variations in other tropical and mid-latitude hydroclimatic records. The global harmony in the hydroclimatic records suggests a unifying conductor. I hypothesize that the conductor is tropical atmospheric circulation. In chapter 4, I present evidence on the peculiar case of an extreme low stand of Mono Lake. The low stand is dubbed the “Big Low”. The principal evidence underpinning the Big Low derives from a sedimentary sequence exposed along the canyon walls of Mill Creek. The strata show that the lake fell below 1,982 m between the deposition of Ashes 5 and 4—making this low stand the lowest recognized level of Mono Lake during the Wilson Creek Formation. Observations from dispersed sequences corroborate this interpretation. And three data constrain the age of the Big Low to be between ~24.4-20.5 ka: a carbonate U/Th date on a littoral conglomerate associated with the Big Low; a carbonate U/Th date that underlies Ash 4; and a carbonate U/Th date that cuts across Ash 5. Thus the interval that the Big Low must occur within encompasses the LGM. The timing of this low stand, therefore, corresponds with summer temperature minima, suggesting that the fall was due not to an increase in evaporation but due to a decrease in precipitation. This finding is counter to conventional wisdom: that the LGM was a relatively wet interval. In addition, both the documentation of a low stand during glacial maximum conditions and the inference that precipitation must have been reduced are contrary to previous published interpretations from model and paleoclimatic data. These discrepancies raise significant questions about our understanding of the regional expression and forcing of hydroclimate across the western United States during the LGM. Because of this period’s importance to ground-truthing climatic models, additional evidence on the geographic extent of this unexpected result is essential.

Mt. Morning is a 2,732 m high, Cenozoic, alkaline eruptive centre situated in the south-west corner of McMurdo Sound in the Ross Sea, Antarctica. Mt. Morning is approximately 100 km south-west of Mt. Erebus, the world's southernmost active volcano. Several Cenozoic, alkali eruptive centres in this region make up the Erebus Volcanic Province. The region is currently undergoing continental extension. Regional-scale, north-striking faulting on the northern flank of Mt. Morning has offset vertical dykes, as young as 3.9 Ma, by up to 6 m dextrally. This is consistent with the trans-extensional regime in the region. The faults also have a dip-slip component, downthrown to the east. These faults define part of the western boundary of the West Antarctic Rift System. Mt. Morning straddles the boundary between the continental rift shoulder of the Transantarctic Mountains in Southern Victoria Land, and the perceived oceanic crust of the Ross Sea. Age determination of the youngest offset dyke constrains movement in the last 3.88 � 0.05 m.y., to an average rate of 0.0015 mm per year. Volcanism on Mt. Morning is divided into two phases. Phase I was erupted between 18.7 � 0.3 and 114 � 0.2 Ma and Phase II between 6.13 � 0.20 and 0.15 � 0.01 Ma. The two phases are separated by a 5.3 m.y. period of quiescence. The geochemistry of Phase I is mildly alkaline; it is composed of volcaniclastic deposits, dykes, sills, and volcanic plugs of nepheline-basanite, nepheline-trachyte, quartz-mugearite, quartz-trachyte, and rhyolite. Phase I rocks evolved along at least two trends: a quartz normative trend, and a nepheline normative trend. Chemical variation in Phase I can be explained in part by crystal fractionation, which has been modelled using major element multiple linear regression. Phase I quartz-mugearite can fractionate to quartz-trachyte after 44% crystallisation. Quartz-trachyte can fractionate to rhyolite after a further 6% erystallisation. The models indicate that clinopyroxene + plagioclase + opaque oxides � alkali feldspar � apatite are the dominant fractionated phases. Many of the Phase I quartz normative volcanic rocks have relatively high ⁸⁷Sr/⁸⁶Sr ratios (0.70501), suggesting that assimilation, most likely of crustal material, has modified them. Phase I nepheline-basanite can fractionate to nepheline-trachyte after 68% crystallisation. Modelling indicates clinopyroxene + nepheline + olivine + opaque oxides are the dominant fractionated phases. Phase II volcanic rocks are strongly alkaline and are mapped as flows, volcaniclastic deposits, dykes, and sills. They have been erupted mainly from parasitic scoria vents and rarely from fissure vents. Rock types include picrobasalt, basalt, basanite, tephrite, hawaiite, mugearite, phonotephrite, tephriphonolite, benmoreite, and phonolite. Chemical variations in the Phase II volcanic rocks can be explained by simple fractionation. Phase II picrobasalt can fractionate to phonotephrite after 78% crystallisation. Phonotephrite can fractionate to phonolite after at least 35% crystallisation, depending on which of several multiple linear regression models are selected. Fractionation is dominated by the removal of clinopyroxene + plagioclase + nepheline + olivine + opaque oxides � apatite � kaersutite. Volcanic rocks in the Erebus Volcanic Province are strongly alkaline on a silica versus total alkalis plot, similar to the Phase II volcanic rocks from Mt. Morning. Mildly alkaline rocks of Phase I are, to date, unique within the Erebus Volcanic Province. Bulk rock isotope ratios of ⁸⁶Sr/⁸⁷Sr (0.70307 - 0.70371 and 0.70498 - 0.70501), �⁴�Nd/�⁴⁴Nd (0.512650 - 0.512902), and �⁰⁶Pb/�⁰⁴Pb (18.593 -20.039) show that the majority of Mt. Morning volcanic rocks lie on a mixing line between HIMU (high-[mu]; enriched in �⁰⁶Pb and �⁰⁸Pb and relatively depleted in ⁸⁶Sr/⁸⁷Sr values) and DM (depleted mantle; high �⁴�Nd/�⁴⁴Nd, low ⁸⁶Sr/⁸⁷Sr, and low �⁰⁶Pb/�⁰⁴Pb). This is similar to the majority of volcanic rocks from the SW Pacific, including Antarctica and New Zealand. Mt. Morning volcanic rocks have tapped this broadly common mantle reservoir. There are variations in radiogenic isotope ratios between Mt. Morning and Mt. Erebus. There are also differences between the incompatible element ratios in volcanic rocks from Mt. Morning, Mt. Erebus, and White Island (a third eruptive centre in the Erebus Volcanic Province), suggesting heterogeneity in the mantle beneath the Erebus Volcanic Province. Significant chemical differences are also noted between ultramafic xenoliths collected from Mt. Morning and from Foster Crater only 15 km away. This suggests a deca-kilometre, possibly even kilometre-scale, heterogeneity in the mantle. Such small-scale chemical differences appear difficult to reconcile with large-scale plume hypotheses for the initiation of volcanism in the Erebus Volcanic Province. Instead, volcanism is much more likely to be related to numerous small plumes, or the preferred hypothesis, metasomatism and amagmatic rifting, followed by decompression melting of upwelling mantle and volcanism during transtensional lithospheric rifting. This latter model is supported by a lack of regional updoming expected with a plume(s), and fits models of localised extension proposed in this thesis. Calc-alkaline and alkaline igneous xenoliths, of felsic to mafic crustal material, have been collected from Mt. Morning. U-Pb geochronology (545.4 � 3.7 Ma and 518.6 � 4.4 Ma) on crustal xenoliths from Mt. Morning illustrate that the basement is Cambrian. Bulk rock chemistry of crustal xenoliths has similarities to compositions reported for Ross Orogen rocks, suggesting the Mt. Morning volcanic edifice is built on a basement that is composed of Cambrian Ross Orogen rock types. Quartz-bearing felsic granulite xenoliths with greater than 70 weight percent silica, collected from Mt. Morning, suggest that part of the basement is felsic. This is the only occurrence of felsic xenoliths reported to date east of the present day coastline of Victoria Land. Mt. Morning crops out less than 25 km from the known northern end of the Koettlitz Glacier Alkaline Province in the Transantarctic Mountains. The partially alkaline basement beneath Mt. Morning suggests the province may continue beneath part of Mt. Morning. The mantle beneath Mt. Morning can be characterised as anhydrous and otherwise largely unmetasomatised, which is atypical of xenoliths collected from the western Ross Sea. Only a handful of Mt. Morning xenoliths show petrographic evidence of metasomatism, these include modal phlogopite, apatite, Fe-Ni sulphide, and plagioclase (in pyroxenite xenoliths), suggesting metasomatising fluids occur discretely in this region. Where present, the metasomatic fluid(s) beneath Mt. Morning are enriched in Ba, LREEs, Th, U, P, Fe, Ni, S, and K, and depleted in Ti relative to the metasomatic fluid composition described at nearby Foster Crater. Oxygen fugacity (fO₂) of the Antarctic shallow mantle has been measured from xenoliths collected from Mt. Morning, where fO₂ was demonstrated to be strongly dependant upon spinel Fe�⁺ content that was measured using Mössbauer spectroscopy, and calculated from the olivine-orthopyroxene-spinel oxybarometer. fO₂ in the rifted Antarctic mantle varies between 0.1 and -1 log units relative to the fayalite-magnetite-quartz buffer and is coupled to melt depletion, with increasing degrees of melt extraction resulting in a more oxidised mantle. This range of upper mantle fO₂ is commonly observed in continental rift settings worldwide. The mantle beneath Mt. Morning is composed of, in increasing degree of fertility, dunite, harzburgite, and lherzolite. Xenoliths representing discrete samples of this mantle have mostly crystallised in the spinel stability field of the mantle at pressures of approximately 15 kb and temperatures between 950 - 970 �C. Symplectites of spinel and pyroxene have been interpreted as petrographic evidence that some of the spinel peridotite originated in the garnet stability field of the mantle. Rare plagioclase-bearing spinel lherzolite (plagioclase lherzolite) is also present in the mantle beneath Mt. Morning, which crystallised at temperatures of between 885 and 935 �C at 5 kb. The Mt. Morning peridotite xenoliths plot along the pre-defined geotherm for the Erebus Volcanic Province, strongly supporting it as the appropriate choice of geothermal gradient for south-west McMurdo Sound. Mineral and bulk rock compositions are nearly identical between the plagioclase lherzolite xenoliths and spinel lherzolite xenoliths. Mineral and bulk rock chemistry suggest it is unlikely that the plagioclase is due to metasomatism. Petrographic evidence and mass balance calculations suggest that the plagioclase lherzolite has crystallised via a sub-solidus (metamorphic) transition from spinel lherzolite upon decompression and upwelling of the mantle. The occurrence of plagioclase lherzolite beneath Mt. Morning could be explained by lithospheric scale uplift along faults that define the western margin of the West Antarctic Rift System. Plagioclase lherzolite has also been collected and described from White Island. White Island is also interpreted to straddle lithospheric scale faults. Rifting and buoyant uplift is sufficient to explain the presence of plagioclase lherzolite in the Erebus Volcanic Province. Plagioclase lherzolite has also been described from Mt Melbourne, an eruptive centre in Northern Victoria Land. Known occurrences of plagioclase lherzolite from the western shoulder of the Ross Sea now cover an area 430 km long and 80 km wide. This is one of the largest provinces of plagioclase peridotite worldwide so far reported.