Biodiesel is a renewable, biodegradable, environmentally benign fuel for use in the diesel engines. It can be produced from renewable sources such as vegetable oils or animal fats. Although this fuel has gained worldwide recognition for many years, it is not being widely commercialized mainly because it is more expensive than petroleum diesel. A cheaper feedstock, such as fryer grease, may be used to improve the economics of biodiesel. <p>Methanol is the most common alcohol used in the transesterification process due to its low cost. However, recently, ethanol has been promoted as an alcohol for use in transesterification since it can be produced from renewable resources such as switchgrass, corn and wood, thereby reducing the dependency on petroleum sources (Pimentel and Patzek, 2005). A mixture of methanol and ethanol is hypothesized to take the advantages of both methanol and ethanol. The present work is focused on the production of biodiesel from fryer grease via transesterification with various mixtures of methanol and ethanol. Also, the kinetics of transesterification from fryer grease was studied. <p> Since fryer grease contains a high concentration of free fatty acids (FFA) (5.6 wt. %) and water (7.3 wt. %), a two-step acid/alkaline transesterification process was used to produce the esters. Sulfuric acid and potassium hydroxide were used as acid and alkaline catalysts, respectively. The methanol to ethanol molar ratio was varied from 3:3 to 5:1, whereas alcohol to oil molar ratio was maintained at 6:1. After the fryer grease was transesterified, all esters met ASTM standard D-6751. The viscosity of these esters ranged from 4.7 to 5.9 mm2/s. The heating value of the esters was approximately 10% less than that of petroleum diesel. The cloud point and pour point were in the range of 1 to -1 oC and -3 to -6 oC, respectively. When the mixed alcohol was used ethyl esters were also formed at a lower concentration along with methyl esters. The dominant fatty acid in fryer grease esters was found to be oleic acid. The lubricity of kerosene fuel was improved by as much as 33 % through the addition of these esters at rates as low as 1 %. <p>For the kinetic study of alkali-catalyzed transesterification of fryer grease, the alcohol to oil molar ratio, the reaction temperature, and the catalyst loading were varied as 6:1, 9:1, 12:1; 30, 40, 50 oC; and 0.5, 1.0, 1.5 %, respectively. The ester concentration was found to rise with an increase in the catalyst loading or the reaction temperature and with a decrease in the alcohol to oil molar ratio. The overall forward and backward reaction orders were assumed to follow first and second order kinetics, respectively. The kinetic parameters were calculated using MATLAB. The conversion of triglyceride to diglyceride was found to be the rate determining step (RDS) of the overall reaction, with an activation energy of 36.9 kJ/mol.

Biodiesel is a renewable, biodegradable, environmentally benign fuel for use in the diesel engines. It can be produced from renewable sources such as vegetable oils or animal fats. Although this fuel has gained worldwide recognition for many years, it is not being widely commercialized mainly because it is more expensive than petroleum diesel. A cheaper feedstock, such as fryer grease, may be used to improve the economics of biodiesel. <p>Methanol is the most common alcohol used in the transesterification process due to its low cost. However, recently, ethanol has been promoted as an alcohol for use in transesterification since it can be produced from renewable resources such as switchgrass, corn and wood, thereby reducing the dependency on petroleum sources (Pimentel and Patzek, 2005). A mixture of methanol and ethanol is hypothesized to take the advantages of both methanol and ethanol. The present work is focused on the production of biodiesel from fryer grease via transesterification with various mixtures of methanol and ethanol. Also, the kinetics of transesterification from fryer grease was studied. <p> Since fryer grease contains a high concentration of free fatty acids (FFA) (5.6 wt. %) and water (7.3 wt. %), a two-step acid/alkaline transesterification process was used to produce the esters. Sulfuric acid and potassium hydroxide were used as acid and alkaline catalysts, respectively. The methanol to ethanol molar ratio was varied from 3:3 to 5:1, whereas alcohol to oil molar ratio was maintained at 6:1. After the fryer grease was transesterified, all esters met ASTM standard D-6751. The viscosity of these esters ranged from 4.7 to 5.9 mm2/s. The heating value of the esters was approximately 10% less than that of petroleum diesel. The cloud point and pour point were in the range of 1 to -1 oC and -3 to -6 oC, respectively. When the mixed alcohol was used ethyl esters were also formed at a lower concentration along with methyl esters. The dominant fatty acid in fryer grease esters was found to be oleic acid. The lubricity of kerosene fuel was improved by as much as 33 % through the addition of these esters at rates as low as 1 %. <p>For the kinetic study of alkali-catalyzed transesterification of fryer grease, the alcohol to oil molar ratio, the reaction temperature, and the catalyst loading were varied as 6:1, 9:1, 12:1; 30, 40, 50 oC; and 0.5, 1.0, 1.5 %, respectively. The ester concentration was found to rise with an increase in the catalyst loading or the reaction temperature and with a decrease in the alcohol to oil molar ratio. The overall forward and backward reaction orders were assumed to follow first and second order kinetics, respectively. The kinetic parameters were calculated using MATLAB. The conversion of triglyceride to diglyceride was found to be the rate determining step (RDS) of the overall reaction, with an activation energy of 36.9 kJ/mol.

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Yes / The torque-tension relationship of threaded fasteners affects almost all engineering disciplines. Tribological processes at fastener interfaces manifest as the system's friction coefficient. Lubrication-related influences are usually described empirically using K or μ. The drive towards lightweight fastener materials in engineering systems and lubricants with reduced environmental impact is challenging existing knowledge and industrial practice in a range of applications, many safety critical. More comprehensive understanding is needed to achieve repeatable friction during assembly and re-assembly, resistance to loosening and fretting during operation, and effective anti-seize for disassembly with a growing range of materials and lubricants. The lubricants considered showed three predominant lubrication mechanisms: plastic deformation of metal powders; burnishing/alignment of molybdenum disulphide, MoS2; and adhering/embedding of non-metal particles. Multivariate analysis identified key sensitivities for these mechanisms. Assembly generated changes at fastener surfaces and in the lubricating materials. Re-assembly exhibited significant reductions in friction. / The full-text of this article will be released for public view at the end of the publisher embargo on 07 Dec 2024.

Recent commercial developments have created a need for alternative materials and methods for imparting oil/grease resistance to paper and/or paperboard used in packaging. The performance of a novel grease resistant functional coating comprised of polyvinyl alcohol (PVA), sodium tetraborate pentahydrate (borate) and acetonedicarboxylic acid (ACDA) and the application of said coating by means of flexographic press is presented herein. Application criteria is developed, testing procedures described, and performance assessment of the developed coating materials are made. SEM images along with contact angle data suggest that coating performance is probably attributable to decreased mean pore size in conjunction with a slightly increased surface contact angle facilitated by crosslinking of PVA molecules by both borate ions and ACDA.

Fat, oil, and grease residues, food particles, solids and some kitchen wastewaters are collected in grease traps which are separate from the municipal wastewater stream. Grease traps are emptied periodically and grease trap waste (GTW) is hauled for treatment. This dissertation focuses on anaerobic co-digestion of un-dewatered (raw) GTW with municipal wastewater treatment sludge (MWS) at wastewater treatment plants. In particular, this research focuses on the biochemical methane potential of un-dewatered GTW as well as the stability and performance of anaerobic co-digestion of MWS and un-dewatered GTW. A set of modified biochemical methane potential tests was performed to determine the methane potential of un-dewatered GTW under mesophilic conditions (35 °C). Methane potential of un-dewatered GTW in this study was 606 mL CH₄/g VS [subscript added] which is less than previously reported methane potentials of 845 - 1050 mL CH₄/g VS [subscript added] for concentrated/dewatered GTW. However, the methane potential of un-dewatered GTW (606 mL CH₄/g VS [subscript added]) was more than two times greater than the 223 mL CH₄/g VS [subscript added] reported for MWS digestion alone. A comprehensive study was performed to determine the stability and performance of anaerobic co-digestion of MWS with un-dewatered GTW as a function of increasing GTW feed ratios. The performance of two semi-continuously fed anaerobic digesters at 35 °C was evaluated as a function of increasing GTW feed ratios. Anaerobic co-digestion of MWS with un-dewatered GTW at a 46% GTW feed ratio (on a volatile solids basis) resulted in a 67% increase in methane production and a 26% increase in volatile solids reduction compared to anaerobic digestion of MWS alone. On the other hand, anaerobic co-digestion of un-dewatered GTW resulted in a higher inhibition threshold (46% on VS basis) than that of dewatered GTW. These results indicate that using un-dewatered GTW instead of dewatered GTW can reduce the inhibition risk of anaerobic co-digestion of MWS and GTW. Recovery of the anaerobic digesters following upset conditions was also evaluated and semi-continuous feed of digester effluent into upset digesters yielded of the biogas production level of the undisrupted digestion. Finally, a mathematical model was used to describe the relationship between methane potential and GTW feed ratio on a VS basis. The results of this research can be used to predict methane production and identify suitable GTW feeding ratios for successful co-digestion of un-dewatered GTW and MWS. / text

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The inclusion of electric vehicles in the automotive industry represents an opportunity for lubricating grease producers. Different speed, loads, and electric conditions are present in the bearings of the electric vehicles when compared with the conditions in a traditional internal combustion engine vehicle. Therefore, the development of new grease formulations is desired to overcome these, and other challenges introduced by this new technology. This project aims to compare two grease-thickener technologies through the installation, development, and validation of a novel high-speed bearing-grease test HSBT machine. This rig allows emulating the conditions present in the bearings of an electric vehicle. In this thesis, 6208 deep groove ball bearings were used to compare the mechanical performance of the greases. The comparative study of lithium complex and polypropylene greases was performed through the analysis of the frictional moment and self-induced temperature of the tested grease-bearing combinations. The results present the energy-saving potential of both greases and show the feasibility of using the HSBT machine as a grease testing machine. This project is the first step in an ambitious plan of enhancing e-mobility through grease research. It gives the input for future development of the machine and the creation of new standards for testing electric vehicle greases. / Införandet av elfordon i bilindustrin utgör en möjlighet för smörjfettproducenter. Olika hastigheter, belastningar och elektriska förhållanden är närvarande i de elektriska fordonens kullager i jämförelse med förhållandena i ett traditionellt förbränningsmotorfordon. Detta kräver utveckling av nya fetter som kan hantera de utmaningar som uppkommer med denna nya teknik. Detta projekt ämnar jämföra två fettförtjockningstekniker genom att installera, utveckla och validera en ny höghastighetslagermaskin (HSBT-maskin) för smörjfettstestning. Denna maskin möjliggör att förhållanden som finns i lagren hos ett elektriskt fordon kan efterliknas. I denna masteruppsats användes spårkullager med beteckningen 6208 för att jämföra smörjfettens mekaniska prestanda. I denna studie jämfördes litiumkomplex- och polypropenfetter genom att analysera friktionsmomentet och den självinducerade temperaturen för de testade kullagersmörjfettskombinationerna. Resultatet av studien visar energibesparingspotentialen för båda smörjfetterna och visar möjligheten att använda HSBT-maskinen för att testa smörjfetter. Detta projekt är det första steget i en ambitiös plan att förbättra e-mobilitet genom smörjfettsforskning. Studien ger indata för framtida utveckling av elektriska maskiner och bidrar till skapandet av nya standarder för testning av fetter för elektriska fordon.

The Upper Paleolithic site of Vale Boi in coastal, southwestern Portugal currently represents the earliest known case of grease-rendering in Eurasia, with initial occupation occurring during the early Gravettian at ~ 27,000 BP. Long-term exploitation of marine resources is indicated by marine shellfish remains, mainly in the form of limpets (<italic>Patella</italic>), recovered from all three cultural periods (Gravettian, Solutrean and Magdalenian). High-level exploitation of rabbits (<italic>Oryctolagus</italic>) began with initial use of the site and continued throughout the occupations, with a possible increase in intensity at the onset of the Solutrean. Grease-rendering of red deer (<italic>Cervus elaphus</italic>), horse (<italic>Equus caballus</italic>), European ass (<italic>Equus hydruntinus</italic>) and aurochs (<italic>Bos primigenius</italic>) bones was identified through multi-dimensional taphonomic and zooarchaeological analyses. Ungulate remains demonstrated extensive fragmentation and abundant evidence of impact features such as cone fractures, crushing, denting and cracking. The intensity of fragmentation and impact damage to red deer remains is significantly correlated with quantities of marrow and bone grease within these portions. Lack of density-mediated attrition of either the leporid remains or the cranial bone of red deer and horse, demonstrates that the loss of low-density, grease-rich post-cranial skeletal portions is due to human subsistence activities. Balanced body-part representation of ungulates indicates that density-mediated attrition of post-cranial elements is not related to differential transport of carcass portions. Comparison of element portion frequencies to food utility indices further demonstrates that humans were systematically harvesting marrow and bone grease throughout the Gravettian, Solutrean and Magdalenian culture periods. The co-occurrence of fire-cracked rock, stone anvils and hammerstones corroborates this suggestion. Although grease rendering at Vale Boi pre-dates other known sites in Eurasia by several thousand years, faunal assemblages in southeastern Spain indicate that resource diversification and intensification appeared there coevally with Vale Boi. The persistence and continued intensification of subsistence practices throughout the Upper Paleolithic suggests a sustained depression of large game in relation to human populations. This was likely due to patchy, spatially-restricted resources, resulting in territorial circumscription. Only through technological innovation and novel approaches to resource harvesting, were foragers able to maintain and ultimately expand their populations in southern Iberia.