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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Monolithic Heterovalent Integration of Compound Semiconductors and Their Applications

January 2019 (has links)
abstract: Compound semiconductors tend to be more ionic if the cations and anions are further apart in atomic columns, such as II-VI compared to III-V compounds, due in part to the greater electronegativity difference between group-II and group-VI atoms. As the electronegativity between the atoms increases, the materials tend to have more insulator-like properties, including higher energy band gaps and lower indices of refraction. This enables significant differences in the optical and electronic properties between III-V, II-VI, and IV-VI semiconductors. Many of these binary compounds have similar lattice constants and therefore can be grown epitaxially on top of each other to create monolithic heterovalent and heterocrystalline heterostructures with optical and electronic properties unachievable in conventional isovalent heterostructures. Due to the difference in vapor pressures and ideal growth temperatures between the different materials, precise growth methods are required to optimize the structural and optical properties of the heterovalent heterostructures. The high growth temperatures of the III-V materials can damage the II-VI barrier layers, and therefore a compromise must be found for the growth of high-quality III-V and II-VI layers in the same heterostructure. In addition, precise control of the interface termination has been shown to play a significant role in the crystal quality of the different layers in the structure. For non-polar orientations, elemental fluxes of group-II and group-V atoms consistently help to lower the stacking fault and dislocation density in the II-VI/III-V heterovalent heterostructures. This dissertation examines the epitaxial growth of heterovalent and heterocrystalline heterostructures lattice-matched to GaAs, GaSb, and InSb substrates in a single-chamber growth system. The optimal growth conditions to achieve alternating layers of III-V, II-VI, and IV-VI semiconductors have been investigated using temperature ramps, migration-enhanced epitaxy, and elemental fluxes at the interface. GaSb/ZnTe distributed Bragg reflectors grown in this study significantly outperform similar isovalent GaSb-based reflectors and show great promise for mid-infrared applications. Also, carrier confinement in GaAs/ZnSe quantum wells was achieved with a low-temperature growth technique for GaAs on ZnSe. Additionally, nearly lattice-matched heterocrystalline PbTe/CdTe/InSb heterostructures with strong infrared photoluminescence were demonstrated, along with virtual (211) CdZnTe/InSb substrates with extremely low defect densities for long-wavelength optoelectronic applications. / Dissertation/Thesis / Doctoral Dissertation Electrical Engineering 2019
2

Heterovalent Semiconductors: First-Principles Calculations of the Band Structure of ZnGeGa<sub>2</sub>N<sub>4</sub>, and Metalorganic Chemical Vapor Deposition of ZnGeN<sub>2</sub> - GaN Alloys and ZnSnN<sub>2</sub>

Jayatunga, Benthara Hewage Dinushi 21 June 2021 (has links)
No description available.
3

Development of Zn-IV-N2 and III-N/Zn-IV-N2 Heterostructures for High Efficiency Light Emitting Diodes Emitting Beyond Blue and Green

Karim, Md Rezaul 13 October 2021 (has links)
No description available.
4

Materials Integration and Metamorphic Substrate Engineering from Si to GaAs to InP for Advanced III-V/Si Photovoltaics

Carlin, Andrew Michael 19 December 2012 (has links)
No description available.

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