Increased knowledge into the physics and chemistrycontrolling emissions from flame-surface interactions shouldhelp in the design of combustion engines featuring improvedfuel economy and reduced emissions. The overall aim of this work has been to obtain afundamental understanding of wall-related, premixed combustionusing numerical modeling with detailed chemical kinetics. Thiswork has utilized CHEMKIN®, one of the leading softwarepackages for modeling combustion kinetics. The simple fuels hydrogen and methane as well as the morecomplex fuels propane and gasified biomass have been used inthe model. The main emphasis has been on lean combustion, andthe principal flow field studied is a laminar boundary layerflow in two-dimensional channels. The assumption has been madethat the wall effects may at least in principle be the same forlaminar and turbulent flames. Different flame geometries have been investigated, includingfor example autoignition flames (Papers I and II) and premixedflame fronts propagating toward a wall (Papers III and IV).Analysis of the results has shown that the wall effects arisingdue to the surface chemistry are strongly affected by changesin flame geometry. When a wall material promoting catalyticcombustion (Pt) is used, the homogeneous reactions in theboundary layer are inhibited (Papers I, II and IV). This isexplained by a process whereby water produced by catalyticcombustion increases the rate of the third-body recombinationreaction: H+O2+M ⇔ HO2+M. In addition, the water produced at higherpressures increases the rate of the 2CH3(+M) ⇔ C2H6(+M) reaction, giving rise to increased unburnedhydrocarbon emissions (Paper IV). The thermal coupling between the flame and the wall (theheat transfer and development of the boundary layers) issignificant in lean combustion. This leads to a sloweroxidation rate of the fuel than of the intermediatehydrocarbons (Paper III). Finally in Paper V, a well-known problem in the combustionof gasified biomass has been addressed, being the formation offuel-NOx due to the presence of NH3 in the biogas. A hybridcatalytic gas-turbine combustor has been designed, which cansignificantly reduce fuel-NOx formation. Keywords:wall effects, premixed flames, flamequenching, numerical modeling, CHEMKIN, boundarylayerapproximation, gasified biomass, fuel-NOx, hybrid catalytic combustor. / QC 20100504