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Rhizosphere microbial diversity in PAH's contaminated and uncontaminated soilRandima, Livhuwani Priscilla. January 2009 (has links)
Thesis (M.Sc.)(Microbiology))--University of Pretoria, 2009. / Summary in English. Includes bibliographical references.
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Biodegradation of aromatic hydrocarbons : microbial and isotopic studies /Diegor, Elizabeth Justa M., January 2000 (has links)
Thesis (M.Sc.)--Memorial University of Newfoundland, 2000. / Bibliography: leaves 105-119.
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Solid peroxide stimulated phenanthrene removal from contaminated river sedimentSchaffnit, Katherine Stuart. January 2009 (has links) (PDF)
Thesis (M.S. in environmental engineering)--Washington State University, December 2009. / Title from PDF title page (viewed on Jan. 14, 2010). "Department of Civil and Environmental Engineering." Includes bibliographical references (p. 41-42).
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Preparation of benzoenyne-allenes, enyne-isocyanates and enyne-carbodiimides and their applications in the synthesis of polycyclic aromatic hydrocarbons and heterocyclesLi, Hongbin, January 1900 (has links)
Thesis (Ph. D.)--West Virginia University, 2002. / Title from document title page. Document formatted into pages; contains xvi, 377 p. : ill. Includes abstract. Includes bibliographical references (p. 120-128).
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Thermal activation and intermediates of six-membered cyclic hydrocarbons and alkyl nitrites on Pt(111) and Cu(100) /Ihm, Hyeran, January 2000 (has links)
Thesis (Ph. D.)--University of Texas at Austin, 2000. / Vita. Includes bibliographical references (leaves 158-168). Available also in a digital version from Dissertation Abstracts.
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Polycyclic aromatic hydrocarbon degradaton by novel bacteria isolated from burrow sediments of marine benthic macrofauna /Chung, Wai Ki, King, Gary Boettcher, Katherine. Distel, Daniel L. MacRae, Jean D. Singer, John. January 2001 (has links)
Thesis (Ph. D.) in Microbiology--University of Maine, 2001. / Includes vita. Advisory Committee: Gary King, Clare S. Darling Prof. of Oceanography and Prof. of Microbiology and Marine Studies, Advisor; Katherine Boettcher, Asst. Prof. of Microbiology; Daniel Distel, Assoc. Prof. of Biochemistry, Microbiology & Molecular Biology; Jean MacRae, Asst. Prof. of Civil & Environmental Engineering; John Singer, Prof. of Microbiology and Chair of Dept. of Biochemistry, Microbiology & Molecular Biology. Includes bibliographical references (leaves 77-91).
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Genetic, metabolic, and histopathological studies of particle-associated respiratory alterationsGhanem, Mohamed Mohamedy. January 2003 (has links)
Thesis (Ph. D.)--West Virginia University, 2003. / Title from document title page. Document formatted into pages; contains xiv, 235 p. : ill. (some col.). Includes abstract. Includes bibliographical references (p. 201-235).
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Biodegradation of polycyclic aromatic hydrocarbons in marine sediment under anoxic conditionsLü, Xiaoying, 吕晓莹 January 2011 (has links)
published_or_final_version / Civil Engineering / Doctoral / Doctor of Philosophy
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Non-heme iron(III) complexes catalyzed oxidation of saturated hydrocarbons and cis-dihydroxylation of alkenesChow, Wai-shan., 周慧珊. January 2010 (has links)
published_or_final_version / Chemistry / Doctoral / Doctor of Philosophy
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Ruthenium porphyrin catalyzed nitrene insertion into C-H bonds of aromatic heterocycles, aldehydes and alkanesXiao, Wenbo., 萧文博. January 2012 (has links)
Transition metal catalyzed selective nitrene insertion into C-H bonds, which allows direct incorporation of nitrogen functionality into hydrocarbons, represents an appealing methodology for C-N bond formation, a type of bond formation of great importance in organic synthesis due to the prevalence of amino groups in biologically active natural products and pharmaceuticals. Organic azides are atom-economic and an environment-benign nitrene source. This dissertation reports the use of organic azides as a nitrene source to develop a series of protocols for C-H bond functionalization by metal-catalyzed nitrene insertion, including the diimination of indoles, the phosphoramidation of aldehydes and the amination of hydrocarbons catalyzed by ruthenium porphyrins.
Carbonylruthenium(II) porphyrin complex Ru(TTP)(CO) (TTP = meso-tetrakis(p-tolyl)porphyrinato dianion) is an effective catalyst for nitrene transfer to sp2 C-H bonds of indoles using aryl azides (ArN3) as a nitrene source. This “Ru(TTP)(CO) + ArN3” protocol selectively results in the diimination of indoles without the corresponding monoimination products being detected. In the presence of a catalyst Ru(TTP)(CO), the reactions of N-methylindole with ArN3 (Ar = 4-nitrophenyl; 3,5-bis(trifluoromethyl)phenyl), and reactions of a variety of N-substituted indoles with 4-nitrophenylazide, afford 2,3-diiminoindoles in good to excellent yields (up to 90%). This unique type of 2,3-diimination products was characterized by NMR spectroscopy, mass spectrometry and single crystal X-ray crystallography. The catalytic diimination product from N-methylindole and ArN3 (Ar = 3,5-bis(trifluoromethyl)phenyl) can also be obtained through stoichiometric reaction of N-methylindole with the corresponding bis(arylimido)ruthenium(VI) porphyrin, suggesting the possible involvement of RuVI(TTP)(NAr)2 intermediates in the Ru(TTP)(CO)-catalyzed diimination reactions.
Dichlororuthenium(IV) porphyrin complex Ru(TTP)Cl2 efficiently catalyzes the phosphoramidation of aldehydes with phosphoryl azides (RO)2P(O)N3 via a nitrene insertion into sp2 C-H bonds of aldehydes. This represents the first study on the catalytic activity of a ruthenium(IV) porphyrin towards nitrene insertion into C-H bonds. The “Ru(TTP)Cl2 + (RO)2P(O)N3” protocol exhibits high chemoselectivity and functional group tolerability. Good to excellent product yields (up to 99%) have been obtained for the Ru(TTP)Cl2-catalyzed phosphoramidation of a wide variety of aldehydes with commercially available (PhO)2P(O)N3 (DPPA) and phosphoramidation of p-tolualdehyde with various (RO)2P(O)N3 (R = Me, Et, CCl3CH2, 4-nitrophenyl). The reaction can be scaled up by adding phosphoryl azide dropwise. The use of commercially available DPPA in this protocol offers a convenient and practical method for the synthesis of N-acylphosphoramidates.
“Ru(TDCPP)Cl2 + (CCl3CH2O)2P(O)N3” (TDCPP = meso-tetrakis(2,6-dichlorophenyl)porphyrinato dianion) serves as an effective protocol for intermolecular nitrene insertion into sp3 C-H bonds of hydrocarbons. Using this protocol, a variety of hydrocarbons including cycloalkanes (such as cyclohexane) and ethylbenzenes undergo sp3 C-H amination in moderate to high yields (up to 86%). Compared with ruthenium(II) porphyrins such as Ru(TDCPP)(CO) and dirhodium carboxylates such as Rh2(OAc)4, Ru(TDCPP)Cl2 displays a markedly higher catalytic activity towards the nitrene sp3 C-H insertion with (CCl3CH2O)2P(O)N3. In addition, intramolecular nitrene insertion into sp3 C-H bond can also take place in good yields with Ru(TDCPP)Cl2 as the catalyst. / published_or_final_version / Chemistry / Doctoral / Doctor of Philosophy
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