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Kinetics of the deprotonation and N-alkylation of acetanilide via phase-transfer catalysisWright, James T., Jr. 12 1900 (has links)
No description available.
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Modifying the Three-Phase Synchronous Reference Frame Phase-Locked Loop to Remove Unbalance and Harmonic ErrorsEren, Suzan 17 December 2008 (has links)
As an increasing number of distributed power generation systems (DPGS) are being connected to the utility grid, there is a growing requirement for the DPGS to be able to ride through short grid disturbances. This requires improvements to be made to the grid-side control scheme of the DPGS. An important part of the grid-side control scheme is the grid synchronization method, which is responsible for tracking the phase angle of the grid voltage vector. The state-of-the-art grid synchronization methods being used today are phase-locked loops.
This thesis presents a modified phase-locked loop which is more robust towards grid disturbances. It consists of a multi-block adaptive notch filter (ANF) integrated into a conventional three-phase synchronous reference frame phase-locked loop (SRF-PLL). The addition of the multi-block ANF to the system allows it to become frequency adaptive. Also, since the multi-block ANF consists of multiple ANF blocks in parallel with one another, the system is able to remove multiple input signal distortions. Thus, the proposed system is able to eliminate the double frequency ripple that is caused in the conventional three-phase SRF-PLL by input unbalance, as well as harmonic errors, despite the presence of frequency variations in the input signal.
Simulation results found using Matlab/Simulink, and experimental results found using the dSPACE DS1103 DSP board, demonstrate the feasibility of the modified SRF-PLL. Also, the modified SRF-PLL is compared to a conventional three-phase SRF-PLL, as well as to a conventional three-phase SRF-PLL with a simple notch filter, and the advantages of the modified SRF-PLL are discussed. / Thesis (Master, Electrical & Computer Engineering) -- Queen's University, 2008-12-17 12:38:02.589
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Use of Dynamic Phase Angle and Complex Modulus for The Low Temperature Performance Grading of Asphalt CementsSOLEIMANI, ABDOLRASOUL 01 September 2009 (has links)
This thesis discusses and documents the validation efforts related to Ontario’s LS-299 and LS-308 test methods which are two new test methods developed for the performance-based specification grading of asphalt cement. In addition, this report presents the field validation of a simple performance indicator, loss tangent, for specification grading of asphalt cement for thermal cracking. Furthermore, another objective of this study is to investigate and compare the low temperature fracture and rheological behavior of engineered asphalt materials from field and laboratory-aged test sections on Highway 655 in northern Ontario.
Extracted asphalt cements from 20 contract sites in eastern and northeastern Ontario were tested according to Ontario’s LS-299 and LS-308 test methods. It was found that all good performing contracts that showed little or no distress showed low grade losses in LS-308 and retained high strain tolerances as measured in LS-299 compared to the poor performing contracts.
Asphalt cements recovered from these 20 contract sites in eastern and northeastern Ontario were also tested in torsion bar geometry to determine their viscoelastic properties. It was decided to focus on the phase angle, as a more direct measure for low temperature performance. Phase angle is a very sensitive parameter to small changes in rheology as the phase angle is approximately equal to the derivative of the logarithm of the stiffness with respect to frequency.
It was found that tan() was able to distinguish good from poor performers with 95% accuracy after only a short period of conditioning prior to testing. This is a considerable improvement over the current low temperature bending beam rheometer protocol.
Black space diagrams, frequency sweeps, Cole-Cole plots, and master curves were generated for comparison of field and laboratory aged materials from the Highway 655 trial in northern Ontario. The findings show that chemical hardening occurs much faster in the field than through laboratory ageing methods. Also, reversible ageing of binders may occur at low temperatures and could be linked to field performance. Furthermore, a high low temperature phase angle appears to be a reasonable indicator for thermal cracking resistance. / Thesis (Master, Chemistry) -- Queen's University, 2009-08-28 15:12:29.845
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Analysis of Anterior Dentofacial Aesthetic Characteristics and their Association to Post-Phase I Orthodontic Treatment DecisionsWitt, Matthew M Unknown Date
No description available.
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Experimental PVT Study of the Phase Behavior of CO2 + Heavy Oil MixturesKhaleghi, Keivan Unknown Date
No description available.
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Dynamics of a single flexible cylinder in external axial compressible fluid flowOstoja-Starzewski, Martin January 1980 (has links)
No description available.
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Phase-transfer catalysis in supercritical fluid solventsWheeler, Theresa Christy 05 1900 (has links)
No description available.
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Mass transfer in two-phase annular flowWu, Der Chang 05 1900 (has links)
No description available.
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Measurement and correlation of critical statesSmith, Richard Lee, Jr. 12 1900 (has links)
No description available.
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Two phase swirling flow in a cylindrical reactorNygaard, Thor Isak. 05 1900 (has links)
No description available.
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