Internal Combustion Engine (ICE) exhaust components are exposed to extreme operating temperatures. Thus, it is necessary that they are designed with materials that can sustain thermal and vibrational stresses. This study investigates the wear mechanisms and tribological performance of the exhaust manifold joint in Scania CV diesel trucks, focusing on the lip seal ring between the exhaust and turbo manifolds. The joint is prone to wear due to thermal and vibrational stresses, impacting its service life and raising environmental concerns. The manifold material, ductile cast iron SiMo51, offers good thermal resistance, while the lip seal ring, made of Inconel 718c, provides excellent thermal fatigue and corrosion resistance, coated with AlTiN for wear and oxidation resistance. However, the tribological performance of this joint and material combination remains unknown, necessitating further research.  This work aims to understand wear initiation mechanisms and their relationship with temperature. Test setups were established using an oscillating cylinder on disc configuration in the SRV 3 tribometer. SiMo51 uncoated/coated with Tribaloy 400 and Inconel 718c uncoated/coated with AlTiN were tested against each other to identify the best material pair. Analysis involved coefficient of friction, visual inspection, wear volume measurements, SEM micrographs, and EDS for surface chemical composition. Results indicated that friction behaviour is temperature-dependent, with oxide layer formation reducing the coefficient of friction when the manifold is uncoated, while the opposite occurs when coated with Tribaloy 400. Wear behaviour varied based on material combinations and temperature. Uncoated manifold exhibited dominant adhesion (galling) accompanied by tribo-oxidation at higher temperatures, with maximum wear volumes at room temperature. Introduction of T-400 on the manifold initiated galling on the lip seal, leading to abrasion on the manifold surface, accompanied by tribo-oxidation at elevated temperatures. Wear increased until 500°C, followed by a decrease at 700°C. Further explanations of T-400 wear behaviour are lacking in the literature.