<p>The pore-size dependence of liquid diffusivity in mesopores has been a controversial topic. It is especially meaningful in dye-sensitized solar cells (DSSCs) because the triiodide ion diffusivity is closely related to the cell performance. By applying electrochemical measurements, the pore-size dependence of ion diffusivity in DSSCs was investigated based on TiO₂ thin films of variable pore diameters. The alternation of pore-size was achieved by the epitaxial growth of TiO₂ after TiCl₄ post-treatments. From the trend of normalized diffusivities, the respective valid regimes of pore-size dependent and independent diffusion were determined, which were separated by the transition point located at 5-7 nm. In addition, my results have showed that the DSSC fabrication processes, e.g., dye loading, TiCl₄ post-treatment will not lead to the transition of diffusion behaviors. Furthermore, the unexpected drop of diffusivity after one TiCl₄ treatment is attributed to the involvement of surface diffusion in untreated TiO₂ matrix.</p> / Master of Applied Science (MASc)