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Biodiesel purification processes generate wastewater streams that require a large amount of energy when distillation is used as a treatment technology. Process simulation software was used to show that an alternative water treatment process involving ion exchange would require only 31% of the energy used by distillation. Experiments showed that multiple washing stages were required to meet the standard specification for sodium, an impurity present in crude biodiesel, when washing biodiesel made from used frying oil. A comparison was made between washing biodiesel in a cross-current washing configuration and a counter-current configuration. Both configurations met the specification for sodium within three washing stages; however, the counter-current configuration required less water, making it the more efficient process. Lastly, the removal of sodium from wastewater samples using an ion exchange resin was experimentally investigated. The results validated the use of ion exchange to reduce energy consumption in biodiesel purification.

In order to increase the current efficiency in copper electrowinning tankhouses, iron can be removed from the electrolyte using ion exchange. While this is a proven technology, very little data is available for the application of this technology to copper electrowinning electrolytes containing antimony and bismuth. The feasibility of utilizing iron ion exchange for the removal of iron from copper electrowinning electrolytes containing antimony and bismuth was studied in the laboratory. Apicolylamine, a sulphonated diphosphonic, an aminophosphonic and three sulphonated monophosphonic resins were tested. The picolylamine resin was found to be completely impractical as it loaded high levels of copper. All the phosphonic resins tested loaded an appreciable amount of antimony, however, only the aminophosponic resin loaded an appreciable amount of bismuth. Tests to determine whether or not the sulphonated monophosphonic Purolite S957 resin would continue to load antimony with time and, hence, reduce the resin's ability to remove iron gave inconclusive results. In the event that the resin's ability to remove iron is hampered due to antimony loading, testing has shown that the resin performance may be restored via a regeneration with a solution containing sulphuric acid and sodium chloride. A case study for the application of this technology to the CVRD Inco CRED plant has shown that, while iron removal by ion exchange is technically feasible, it will upset the plant's acid balance in electrolyte. Therefore, an acid removal process would need to be implemented in tandem with an iron ion exchange system. Additionally, preliminary calculations suggest that a system with a single ion exchange column may have difficulty removing sufficient iron for the CRED design conditions. Therefore, consideration should be given to the possibility of utilizing a two column system (one column loading, one column stripping).

Biodiesel purification processes generate wastewater streams that require a large amount of energy when distillation is used as a treatment technology. Process simulation software was used to show that an alternative water treatment process involving ion exchange would require only 31% of the energy used by distillation. Experiments showed that multiple washing stages were required to meet the standard specification for sodium, an impurity present in crude biodiesel, when washing biodiesel made from used frying oil. A comparison was made between washing biodiesel in a cross-current washing configuration and a counter-current configuration. Both configurations met the specification for sodium within three washing stages; however, the counter-current configuration required less water, making it the more efficient process. Lastly, the removal of sodium from wastewater samples using an ion exchange resin was experimentally investigated. The results validated the use of ion exchange to reduce energy consumption in biodiesel purification.

On may 1, 1996, Ulysses spacecraft crossed the ion tail of comet Hyakutake, revealing an ion tail length of more than 3 times the Sun-Earth distance. The signatures of an ion tail, especially the ion tail far from the nucleus, are not well explored and many question marks remain. This report summarizes previous observations of spacecraft - ion tail crossings and what signatures that can be expected, as well as signatures of other known solar wind structures. A data analysis is made of possible ion tail encounters from Rosetta spacecraft measurements, Ulysses spacecraft measurements and Earth-orbiting spacecraft measurements. A search from Venus Express data to detect ion tails of sungrazing comets is presented.

The irradiation of metallic glasses to induce nanocrystallization was studied in two metallic glass compositions, Cu50Zr45Ti5 and Zr55Cu30Al10Ni5. Atomic mobility was described using a model based on localized excess free volume due to displace- ment cascades created by energetic particle irradiation. Due to the di erence in cascade size among di erent masses of projectiles, a mass-dependent study was per- formed. Metallic glass ribbon samples produced by melt-spinning were bombarded with electron, He, Ar, and Cu particles. Electron irradiation and characterization was performed "in-situ" by means of transmission electron microscopy. The di erent metallic glasses showed dissimilar levels of radiation stability under electron irradi- ation by Cu50Zr45Ti5 forming crystals 1-10 nm in diameter embedded in the amor- phous matrix after about 30 minutes of irradiation, while Zr55Cu30Al10Ni5 showed no such crystallization. Increasing projectile mass caused an increase in the maximum nanocrystal diameter up to approximately 100 nm in Cu irradiated Zr55Cu30Al10Ni5. Studies of di raction patterns of irradiated specimens showed nucleation of Cu10Zr7 phases in both specimens, as well as evidence of CuZr2 in Cu50Zr45Ti5 and both CuZr2 and NiZr2 in Zr55Cu30Al10Ni5. Crystal sizes in irradiated Zr55Cu30Al10Ni5 specimens showed bimodal distribution with many large (50-100 nm) crystals and many small (1-5 nm) crystals. The small crystals in irradiated Zr55Cu30Al10Ni5 were determined to be NiZr2 phase because of the low abundance of Ni. After exposure to 2 keV Ar ions, areas of composition roughly Cu10Zr7 were found by energy-dispersive X-ray spectroscopy but no crystallization was found. Further crystallization was achieved in decomposed specimens after electron irradiation. This shows that atomic segregation is a necessary step before nucleation in metallic glasses.

Multifragmentation reactions have been used to study many of the complexities of the nucleus. Recently, work has been done to tie observables from multifragmentation reactions to astrophysical observables used in supernova explosions. To make this connection, it is necessary to have a highly excited, equilibrated system. The creation of a highly excited system is done for this dissertation by the reaction of one projectile, ³²S, on three targets, ¹¹²⁾¹²⁴Sn and ^natAu at 45 MeV/nucleon. The forward array using silicon technology, FAUST, was used to collect the fragments produced from the excited projectiles. The motivation for this study was to isotopically identify the fragmenting source and to understand the relationship between its N/Z and the resulting fragmentation. This can then be used to constrain theoretical models which predict the evolution of supernova explosions. Using an isotropically identified source, the resulting fragmentation of the projectile has been studied. It is shown that there are dependencies on the fragment mass distribution, fragment charge distribution and source excitation energy from the source N/Z. Looking more specifically at the fragments produced, it was found that there is a parallel velocity anisotropy in the particle emission. This anisotropy is found to be a direct result of the presence of an external Coulomb field. Using DIT+SMM theoretical calculations, the anisotropy has been found to be dependent on the distance at which the projectile breaks up from the target (external Coulomb field). As the parallel velocity is related to the angle of emission, it is of interest to extract out the average kinetic energy of each isotope to determine if there are differences in the average kinetic energy by the angle of emission. It is found that the average kinetic energy is dependent on the emission angle in the quasi-projectile frame. Because of this, care should be taken when comparing between systems to ensure similar regions are being compared. However, the observation that the average kinetic energy changes as a function of the emission angle is not dependent on the presence of an external Coulomb field. Using DIT+SMM calculations, the differences between the average kinetic energy from different angles of emission are seen even when no external Coulomb field is present. These changes are attributed to the angular momentum. In all cases, a statistical framework, supplied by DIT+SMM calculations, can explain many phenomena seen from a fragmenting nucleus. However, the accuracy of the model varies when moving from a neutron-poor to a neutron-rich source.

On InGaAs/AlInAs heterostructures we made nanowires which were made by focus ion beam (FIB) and the width of nanowires making by FIB were 40nm¡B70nm¡B100nm and 200nm respectively. we studied electronic characterization of nanowires using Shubnikov-de Haas(SdH).In our research,by using SdH method there are no signal in our sample which processed by FIB,then we changed to process technology in our sample.For example: Increase thickness of the protection layer,size of change channel,etc.

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This thesis is to research connection process of multi-level conductor in integration circuits (ICs) manufacture technology. For the sake of sub-micro ICs which is gazed by people in the future, device¡¦s dimension have to be scaled down unceasingly; besides, the design of conductor connection of multi-level metal is also to be adopted for ULSI technology. However, the number of metal connection layer is increasing as well as the distance between wires is shorter and shorter, which leads to the fact that the RC delay time of metal interconnection is the primary reason of limiting the speed of semiconductor device while electronic signal is delivered among metal interconnection. In order to lower delay time of signal propagation, there are two parts in the following: In the aspect of lowering resistance, we substitute copper (resistance is 1.7£g£[-cm) at present for aluminum (resistance is 2.7£g£[-cm ) in the past so as to make copper be the wire for interconnection system. Furthermore, the scaled down device not only increase the current density of the wire but also increase the severity of electromigration inside the wire. Copper atoms are so heavier than aluminum atoms that copper atoms can restrain electromigration appropriately. In the aspect of decreasing capacitance, we will develop low dielectric constant (low-k). But copper with Damascene manufacture under the conditions of external operation such as temperature and electric field give rise to the fact that Cu diffuses into low-k material so easily that copper and low-k interact, which deteriorates the characteristic of the material¡Braises the leakage current and leads to the breakdown of the dielectric material. Therefore, it must be an important topic for study that we search for the dielectric barrier material with the characteristic against copper diffusion under the demand coinciding with integration process compatibility. At present, because of the material film called silicon carbide with low dielectric constant (k=4~6) attracts a lot of people¡¦s eyes deeply, it can applied to dielectric barrier technology to replace traditional dielectric barrier silicon nitride with high dielectric constant (k~8) for the purpose of alleviating delay time of the wire system. This thesis will discuss fundamental characteristics of silicon carbide film and some problems during the integration process. For instance, the impacts on silicon carbide under the conditions of fluorine plasma and thermal treatment; furthermore, this thesis will research the electric problems from the integration of low-k dielectric barrier and copper wire as well as probes into mechanism of leakage current.