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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

In-medium width of the η' meson

Niblaeus, Carl January 2013 (has links)
In this master’s thesis the width of the <img src="http://www.diva-portal.org/cgi-bin/mimetex.cgi?%5Ceta'" /> meson is studied as a function of temperature. We consider a background medium consisting of a pion gas and assume a vanishing net baryon chemical potential. The width is obtained in the framework of large <img src="http://www.diva-portal.org/cgi-bin/mimetex.cgi?N_%7Bc%7D" /> chiral perturbation theory and we consider terms up to next-to-leading order in the effective Lagrangian. We use a low-density approximation to calculate the width increase due to scattering with pions from the heat bath. The results suggest that the in-medium width for the <img src="http://www.diva-portal.org/cgi-bin/mimetex.cgi?%5Ceta'" /> may become of considerable size: at a temperature <img src="http://www.diva-portal.org/cgi-bin/mimetex.cgi?T%5Capprox%2075" /> MeV we find a width increase of <img src="http://www.diva-portal.org/cgi-bin/mimetex.cgi?%5CDelta%5CGamma%5Capprox%203-4" /> MeV, comparable to the inverse lifetime of the fireball created in a heavy-ion collision. The <img src="http://www.diva-portal.org/cgi-bin/mimetex.cgi?%5Ceta'" /> is of particular interested since it is intimately connected to the <img src="http://www.diva-portal.org/cgi-bin/mimetex.cgi?U(1)_%7BA%7D" /> anomaly of Quantum Chromodynamics (QCD). It has been speculated that <img src="http://www.diva-portal.org/cgi-bin/mimetex.cgi?U(1)_%7BA%7D" /> may become a symmetry of QCD at high temperatures and studies of the <img src="http://www.diva-portal.org/cgi-bin/mimetex.cgi?%5Ceta'" /> could indicate if that is the case. Depending on for how large temperatures the results from large <img src="http://www.diva-portal.org/cgi-bin/mimetex.cgi?N_%7Bc%7D" /> can be trusted, they indicate that the <img src="http://www.diva-portal.org/cgi-bin/mimetex.cgi?%5Ceta'" /> may be possible to study experimentally in heavy-ion collisions due to its sizable in-medium width.
2

Aspects of Porous Graphitic Carbon as Packing Material in Capillary Liquid Chromatography

Törnkvist, Anna January 2003 (has links)
<p>In this thesis, porous graphitic carbon (PGC) has been used as packing material in packed capillary liquid chromatography. The unique chromatographic properties of PGC has been studied in some detail and applied to different analytical challenges using both electrospray ionization-mass spectrometry (ESI-MS) and ultra violet (UV) absorbance detection. </p><p>The crucial importance of disengaging the conductive PGC chromatographic separation media from the high voltage mass spectrometric interface has been shown. In the absence of a grounded point between the column and ESI emitter, a current through the column was present, and changed retention behaviors for 3-O-methyl-DOPA and tyrosine were observed. An alteration of the chromatographic properties was also seen when PGC was chemically oxidized with permanganate, possibly due to an oxidation of the few surface groups present on the PGC material. </p><p>The dynamic adsorption of the chiral selector lasalocid onto the PGC support resulted in a useful and stable chiral stationary phase. Extraordinary enantioselectivity was observed for 1-(1-naphthyl)ethylamine, and enantioseparation was also achieved for other amines, amino acids, acids and alcohols. </p><p>Finally, a new strategy for separation of small biologically active compounds in plasma and brain tissue has been developed. With PGC as stationary phase it was possible to utilize a mobile phase of high content of organic modifier, without the addition of ion-pairing agents, and still selectively separate the analytes. </p>
3

Aspects of Porous Graphitic Carbon as Packing Material in Capillary Liquid Chromatography

Törnkvist, Anna January 2003 (has links)
In this thesis, porous graphitic carbon (PGC) has been used as packing material in packed capillary liquid chromatography. The unique chromatographic properties of PGC has been studied in some detail and applied to different analytical challenges using both electrospray ionization-mass spectrometry (ESI-MS) and ultra violet (UV) absorbance detection. The crucial importance of disengaging the conductive PGC chromatographic separation media from the high voltage mass spectrometric interface has been shown. In the absence of a grounded point between the column and ESI emitter, a current through the column was present, and changed retention behaviors for 3-O-methyl-DOPA and tyrosine were observed. An alteration of the chromatographic properties was also seen when PGC was chemically oxidized with permanganate, possibly due to an oxidation of the few surface groups present on the PGC material. The dynamic adsorption of the chiral selector lasalocid onto the PGC support resulted in a useful and stable chiral stationary phase. Extraordinary enantioselectivity was observed for 1-(1-naphthyl)ethylamine, and enantioseparation was also achieved for other amines, amino acids, acids and alcohols. Finally, a new strategy for separation of small biologically active compounds in plasma and brain tissue has been developed. With PGC as stationary phase it was possible to utilize a mobile phase of high content of organic modifier, without the addition of ion-pairing agents, and still selectively separate the analytes.

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