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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Molecular Fullerides

Fullagar, Wilfred Kelsham, w_fullagar@hotmail.com January 1997 (has links)
The closed shell structures of certain all-carbon fragments originally observed in mass spectroscopy experiments leads to the enhanced stability of these species, known as fullerenes, which have excited sufficient interest amongst chemists and physicists over the last decade to warrant the award of the 1996 Nobel Prize for Chemistry to their discoverers. ¶ Studies of the stability, symmetry, and consequent remarkable properties of fullerenes began in earnest in 1991 with the development of a technique enabling the production and purification of macroscopic quantities of material. The best known and most widely studied fullerene is the truncated icosahedral C[subscript 60] molecule, which forms the basis of the present work. ¶ One important property of C[subscript 60] is that it forms salts with sufficiently electropositive species, such as the alkali metals. The resulting salts contain C[subscript 60] anions and are known as fullerides. Certain of these salts display metallic behaviour, and some superconduct at temperatures as high as 33 K. ¶ Three aspects of fulleride research are addressed in this work. These are: i) the preparation, crystal structure determination and superconductivity characterization of several new fullerides, particularly those including ammonia as an additional intercalant; ii) the electronic structure of the C[superscript n-, subscript 60] (n = 1 - 6) anions, as probed by solution-phase near infrared absorption spectroscopy; and iii) the molecular dynamics of a number of fullerides, superconducting and non-superconducting, by inelastic neutron scattering. ¶ This work has grown out of an Honours project also concerning C[subscript 60], the combined duration of the two studies covering essentially the entire history of this widely and competitively studied field.

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