A numerical analysis of the loop tack test is presented to study the behavior of the strip and the influence of several factors, and the results are compared with experimental ones. The numerical results can be applied to model the performance of a pressure sensitive adhesive (PSA). Since the simulation of the loop tack test includes geometrical and material nonlinearities, it is solved numerically by the finite element method. The finite element program ABAQUS is used throughout the research. As the teardrop shaped loop is pushed down onto the adhesive and then pulled up, the variation of the loop behavior is investigated using two-dimensional (2D) and three-dimensional (3D) models. A bilinear elastic-plastic constitutive law is used for the strip. The deformation of the pressure sensitive adhesive is approximated as uniaxial extension of independent adhesive strands. A Winkler-type nonlinear elastic foundation and a viscoelastic foundation are used to model the PSA. A nonlinear elastic spring function is used, which is composed of a compression region for the bonding phase and a tension region for the debonding phase. A debonding failure criterion is assumed, in which an adhesive strand will debond when it reaches a certain length. During the bonding phase, it is assumed that the loop is perfectly bonded, and the contact time is not included. Curves of the pulling force versus the top displacement (i.e., tack curves) are obtained throughout the simulation. A parametric study is made with respect to the nonlinear spring function parameters, experimental uncertainties, and strip thickness. Anticlastic bending behavior is shown in the 3D analysis, and the contact patterns are presented. The effects of the elasticity modulus of the PSA for the elastic foundation and the displacement rate for the viscoelastic model are investigated. / Ph. D.

The loop tack test measures the tack (instant grip) of an adhesive. An analytical model of this test seems to be lacking and is the subject of this research. The strip is investigated using several mathematical formulations, and the solutions are obtained numerically. The loop is created from a flexible elastic strip that is bent into a teardrop shape, with its ends clamped together. The strip is tested in a cycle, in which the loop is first pushed onto the surface, compressing the adhesive. Then the loop is pulled up, and gradually debonds from the substrate. The loop is assumed to be nonlinearly elastic and inextensible. The mechanics of the loop tack test are studied in order to determine the impact of various factors on adhesive performance. These factors include the stiffness of the backing, the stiffness and thickness of the adhesive, the elongation of the adhesive before debonding, and the contact time. The relationship between the applied force and the vertical deflection of the loop's ends is determined, as well as that between the applied force and the contact length. Also, the maximum "pull - off" force needed to remove the substrate from the loop is obtained from the results. Shapes of the loop during the cycle are found. This research will increase understanding of the behavior of the adhesive and backing during the loop tack test. With the computer model that has been developed, any set of parameters and conditions can be analyzed, and improvements can be made in the test procedure. / Master of Science

Hot melt adhesives (HMA) are a class of adhesives that, unlike solvent-or waterborne counterparts, do not contain organic solvents or other carriers, and are produced and subsequently applied in a molten state. The main components of HMA are polymers, tackifying resins, and a plasticiser. HMA offer a more environmentally friendly option of adhesive materials.  This study was undertaken to investigate the performance of plasticisers based on renewable resources in HMA. Historically, mineral oil-based plasticisers have been used with great success in HMA formulations, offering a performance benchmark. This work selected suitable alternatives from renewable resources, ranging from fully renewable to fully conventional compositions. During the production stage, the compatibility of such plasticisers with the rest of the HMA formulation was studied while rheological methods were used to investigate the impact of different plasticisers on the properties of the final HMA. Adhesive properties were also assessed by loop tack and peel tests on polyethylene terephthalate (PET) and stainless steel (SS) substrates.   It was shown that some of the studied materials from renewable resources could offer a suitable component in the design of a biobased plasticiser, whose performance matched conventional plasticisers, while the ratio of the biobased fraction was up to 70 % and possibly even higher. The findings of this work show the potential of biobased alternatives in making HMA with a higher degree of sustainability. / Smältlim är en klass av lim som, till skillnad från lösningsmedels-eller vattenburna motsvarigheter, inte innehåller organiska lösningsmedel eller andra bärare, och som produceras och appliceras därefter i smält tillstånd. Huvudkomponenterna i HMA är polymerer, klibbgivande hartser och en mjukgörare. smältlim erbjuder ett mer miljövänligt alternativ för limmaterial. Denna studie genomfördes för att undersöka prestandan hos mjukgörare baserade på förnybara resurser i HMA. Historiskt har mineraloljebaserade mjukgörare använts med stor framgång i HMA-formuleringar, vilket ger ett prestandariktmärke. Lämpliga alternativ valdes ut från förnybara resurser, allt från helt förnybara till helt konventionella kompositioner. Under produktionsstadiet studerades kompatibiliteten av sådana mjukgörare med resten av smältlimsformuleringen medan reologiska metoder användes för att undersöka olika mjukgörares inverkan på egenskaperna hos det slutliga limmet. Vidhäftningsegenskaperna utvärderades också genom loop tack test och peel test på polyetylentereftalat (PET) och rostfritt stål (SS) substrat. Det visades att en del av de studerade materialen från förnybara resurser kunde erbjuda en lämplig komponent i designen av en biobaserad mjukgörare, vars prestanda matchade konventionella mjukgörare, medan förhållandet mellan den biobaserade fraktionen var upp till 70 % och möjligen ännu högre. Resultaten av detta arbete visar potentialen hos biobaserade alternativ för att göra HMA med en högre grad av hållbarhet.