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Thermochemical Structure and Dynamics of Earth's Lowermost MantleJanuary 2015 (has links)
abstract: Seismic observations have revealed two large low shear velocity provinces (LLSVPs) in the lowermost mantle beneath Pacific and Africa. One hypothesis for the origin of LLSVPs is that they are caused by accumulation of subducted oceanic crust on the core-mantle boundary (CMB). Here, I perform high resolution geodynamical calculations to test this hypothesis. The result shows that it is difficult for a thin (~ 6 km) subducted oceanic crust to accumulate on the CMB, and the major part of it is viscously stirred into the surrounding mantle. Another hypothesis for the origin of LLSVPs is that they are caused by thermochemical piles of more-primitive material which is remnant of Earth's early differentiation. In such case, a significant part of the subducted oceanic crust would enter the more-primitive reservoir, while other parts are either directly entrained into mantle plumes forming on top of the more-primitive reservoir or stirred into the background mantle. As a result, mantle plumes entrain a variable combination of compositional components including more-primitive material, old oceanic crust which first enters the more-primitive reservoir and is later entrained into mantle plumes with the more-primitive material, young oceanic crust which is directly entrained into mantle plumes without contacting the more-primitive reservoir, and depleted background mantle material. The result reconciles geochemical observation of multiple compositional components and varying ages of oceanic crust in the source of ocean-island basalts. Seismic studies have detected ultra-low velocity zones (ULVZs) in some localized regions on the CMB. Here, I present 3D thermochemical calculations to show that the distribution of ULVZs provides important information about their origin. ULVZs with a distinct composition tend to be located at the edges of LLSVPs, while ULVZs solely caused by partial melting tend to be located inboard from the edges of LLSVPs. This indicates that ULVZs at the edges of LLSVPs are best explained by distinct compositional heterogeneity, while ULVZs located insider of LLSVPs are better explained by partial melting. The results provide additional constraints for the origin of ULVZs. / Dissertation/Thesis / Doctoral Dissertation Geological Sciences 2015
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On the spatio-temporal distribution of aerosol particles in the upper troposphere and lowermost stratosphereAssmann, Denise 13 May 2019 (has links)
In der oberen Troposphäre und untersten Stratosphäre (OT/US) beeinflussen Aerosolpartikel im Submikrometerbereich den Strahlungshaushalt der Erde direkt und, was noch wichtiger ist, indirekt, da sie als Kondensationskern für Wolken dienen und somit die Spurengaskonzentrationen durch heterogene chemische Prozesse ändern können. Seit 1997 gibt es regelmäßige in situ Messungen der OT/US Partikel durch das Leibniz-Institut für Troposphärenforschung in Leipzig, Deutschland. Diese Messungen werden an Bord eines Passagierflugzeugs mit dem weltweit einzigartigen IAGOS-CARIBIC Messcontainer durchgeführt (www.iagos.org/iagos-caribic). In der vorliegenden Arbeit wurden die Partikelanzahlkonzentration und die Partikelgrößenverteilung im Submikrometerbereich der vergangenen Jahre ausgewertet. Dafür wurden die Daten von drei Kondensationspartikelzählern (CPC, Condensation Particle Counter) und einem optischen Partikelgrößenspektrometer (OPSS, Optical Particle Size Spectrometer) verwendet.
Zunächst wurde im Labor eine umfangreiche Charakterisierung des IAGOS-CARIBIC OPSS hinsichtlich der Zähleffizienz durchgeführt. Weiterhin wurde eine Kalibrierung mit Polystyrol-Latex im geräterelevanten Bereich von 140 nm bis 1050 nm vorgenommen und daraus mit Hilfe der Mie-Streuung eine Funktion zur Datenauswertung für die OT/US entwickelt.
Die statistische Analyse der IAGOS-CARIBIC OPSS und CPC Daten gibt einen guten Überblick über die in der OT/US vorkommenden Partikelanzahlkonzentrationen und stellt sicher, dass ein statistisch fundierter Datensatz für die Analyse zur Verfügung steht. Auf dieser Grundlage wurde zum ersten Mal eine detaillierte Analyse der raumzeitlichen Verteilung der Aitkenmode- und Akkumulationsmode-Partikelanzahlgrößenverteilung in der OT/US vorgenommen. Diese Analyse beinhaltet Weltkarten mit Medianwerten, Wahrscheinlichkeitsdichtefunktionen für spezielle Flugrouten und Partikelgrößenverteilungen entlang der Längengrade. Außerdem wurden die Partikelanzahlkonzentrationen zum ersten Mal mit dem globalen Klimamodell ECHAM-HAM verglichen. Dabei ergab sich, dass die Partikelanzahlkonzentration hauptsächlich von großräumigen Strömungsverhältnissen beeinflusst wird, was im Großen und Ganzen gut vom Modell wiedergegeben wird.
Für die einzelnen Jahreszeiten wurden mit Hilfe der potentiellen Temperatur und äquivalenten Breitengrade die vertikalen Profile ausgewertet. Für die Analyse in Bezug auf die Aerosol-Mikrophysik und den Transport durch die Tropopause wurden auch die in IAGOS-CARIBIC gemessenen Spurengase, wie z.B. Ozon und Wasserdampf, hinzugezogen. Die Auswertung zeigt ebenfalls deutlich den Einfluss von Wolken in der oberen Troposphäre und verschiedene Austauschprozesse zwischen der Stratosphäre und Troposphäre. Außerdem wurde der Einfluss verschiedener Austauschprozesse auf die Partikelanzahlkonzentration untersucht: die Brewer-Dobson Zirkulation, warm conveyor belts, Isentropentransport und der Transport durch tropische, hochreichende konvektive Bewölkung. In der Vergangenheit wurde diese Analyse nur für atmosphärische Spurengase durchgeführt, und nun zum ersten Mal auch für Aerosolpartikel.
Die hier präsentierten Ergebnisse zeigen eine umfangreiche Charakterisierung der Aitken- und Akkumulationsmode-Partikelanzahlkonzentration in der OT/US und den Einfluss von Austauschprozessen der Stratosphäre und Troposphäre auf die Partikel. Die Auswertungen tragen maßgeblich zum Verständnis und zur Vorhersage der Partikelanzahlkonzentration in Klimamodellen und damit schlussendlich zur Berechnung des Strahlungshaushalts der Erde und dessen zeitlicher Veränderung bei. / Submicrometer aerosol particles in the upper troposphere and lowermost stratosphere (UT/LMS) influence the Earth's radiation budget directly and, more important, indirectly, by acting as cloud condensation nuclei and by changing trace gas concentrations through heterogeneous chemical processes. Since 1997, regular in situ measurements of UT/LMS particles have been conducted by the Leibniz Institute for Tropospheric Research, Leipzig, Germany, using the world-wide unique IAGOS-CARIBIC observatory (www.iagos.org/iagos-caribic) onboard a passenger aircraft. In this thesis, UT/LMS aerosol particle number concentrations and the submicrometer aerosol particle size distribution as measured by three condensation particle counters (CPCs) and one Optical Particle Size Spectrometer (OPSS) are discussed.
Before analyzing the measurement data from the UT/LMS region a throughout characterization of the IAGOS-CARIBIC OPSS with respect to the counting efficiency was carried out in the laboratory for the OPSS-relevant particle size range of 140 nm to 1040 nm diameter. After calibration with polystyrene latex (PSL) particles a theoretical response function, representative for the UT/LMS, was calculated with Mie theory to ensure a correct data analysis.
The statistical analysis of the IAGOS-CARIBIC OPSS and CPC data gives a good overview of existing particle number concentrations in the UT/LMS and ensures a statistically sound data analysis. On this basis a detailed characterization of the spatio-temporal distribution of Aitken and accumulation mode particle number concentrations in the UT/LMS was carried out for the first time. This analysis includes global maps with median values, probability density functions for specific flight routes, and longitudinal distributions of the particle size distribution. Also a first comparison with the global climate model ECHAM-HAM was conducted. The analysis showed that the aerosol distributions are mainly influenced by large-scale circulation patterns which were, in gererel terms, well reflected by the global climate model.
Moreover, seasonal vertical cross-sections for particle number concentrations, the potential temperature, and the equivalent latitude were generated. The results are interpreted with respect to aerosol microphysics and cross-tropopause transport using IAGOS-CARIBIC trace gases like ozone and water vapor. The influence of clouds in the troposphere and the different stratosphere-troposphere exchange processes are clearly visible. Furthermore, the influence of the major transport processes into the UT/LMS region on the aerosol particle number concentrations was investigated: the Brewer-Dobson circulation, warm conveyor belts, isentropic transport, and tropical deep convective cloud outflow. In the past this was done only for atmospheric trace gases, but now for the first time for aerosol particles.
The findings presented in this study represent a comprehensive characterization of the Aitken and accumulation mode particle number concentration in the UT/LMS and the influence of stratospheric-tropospheric exchange processes on these particles. These findings may help to evaluate and improve predictions of particle number concentrations by climate models and finally the calculation of the Earth's radiation budget and its change over the years.
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High-Resolution Imaging of Structure and Dynamics of the Lowermost MantleJanuary 2012 (has links)
abstract: This research investigates Earth structure in the core-mantle boundary (CMB) region, where the solid rocky mantle meets the molten iron alloy core. At long wavelengths, the lower mantle is characterized by two nearly antipodal large low shear velocity provinces (LLSVPs), one beneath the Pacific Ocean the other beneath Africa and the southern Atlantic Ocean. However, fine-scale LLSVP structure as well as its relationship with plate tectonics, mantle convection, hotspot volcanism, and Earth's outer core remains poorly understood. The recent dramatic increase in seismic data coverage due to the EarthScope experiment presents an unprecedented opportunity to utilize large concentrated datasets of seismic data to improve resolution of lowermost mantle structures. I developed an algorithm that identifies anomalously broadened seismic waveforms to locate sharp contrasts in shear velocity properties across the margins of the LLSVP beneath the Pacific. The result suggests that a nearly vertical mantle plume underlies Hawaii that originates from a peak of a chemically distinct reservoir at the base of the mantle, some 600-900 km above the CMB. Additionally, acute horizontal Vs variations across and within the northern margin of the LLSVP beneath the central Pacific Ocean are inferred from forward modeling of differential travel times between S (and Sdiff) and SKS, and also between ScS and S. I developed a new approach to expand the geographic detection of ultra-low velocity zones (ULVZs) with a new ScS stacking approach that simultaneously utilizes the pre- and post-cursor wavefield.. Strong lateral variations in ULVZ thicknesses and properties are found across the LLSVP margins, where ULVZs are thicker and stronger within the LLSVP than outside of it, consistent with convection model predictions. Differential travel times, amplitude ratios, and waveshapes of core waves SKKS and SKS are used to investigate CMB topography and outermost core velocity structure. 1D and 2D wavefield simulations suggest that the complicated geographic distribution of observed SKKS waveform anomalies might be a result of CMB topography and a higher velocity outermost core. These combined analyses depict a lowermost mantle that is rich in fine-scale structural complexity, which advances our understanding of its integral role in mantle circulation, mixing, and evolution. / Dissertation/Thesis / Ph.D. Geological Sciences 2012
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シリア国ラッカ市近郊のユーフラテス河中流域にある最低位段丘堆積物の14C年代Ohta, Tomoko, Tsukada, Kazuhiro, Yoshida, Eiichi, Tanaka, Tsuyoshi, Katsurada, Yusuke, Hoshino, Mitsuo, Saito, Takeshi, Nakamura, Toshio, 太田, 友子, 束田, 和弘, 吉田, 英一, 田中, 剛, 桂田, 祐介, 星野, 光雄, 齊藤, 毅, 中村, 俊夫 03 1900 (has links)
タンデトロン加速器質量分析計業績報告
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Micropalaeontology, palaeoenvironments and sequence stratigraphy of the Sulaiy Formation of eastern Saudi ArabiaAlenezi, Saleh January 2016 (has links)
The Sulaiy Formation, which is the oldest unit in the Lower Cretaceous succession, is conformably overlain by the Yamama Formation and it is a challenge to identify the precise age of the two formations using foraminifera and other microfossil assemblages. In the eastern side of Saudi Arabia, the Sulaiy Formation and the base of Yamama Formation are poorly studied. The main objectives of this study is to enhance the understanding of the Sulaiy Formation sequence stratigraphical correlation, regional lateral variations and palaeoenvironmental investigation. Lithological and semi-quantitative micropalaeontological analysis of 1277 thin sections taken from core samples from nine cored wells providing a geographically representative distribution from the Saudi Arabian Gulf. These cores intersected the base of the Yamama Formation and the Sulaiy Formation in the total thickness of cored wells of 843.23 meters (2766.5 feet). On the evidence provided by the foraminifera, the Sulaiy Formation is considered to represent the Berriasian to the lowermost Valanginian. The investigation of the micropalaeontology has provided considerable insights into the biocomponents of Sulaiy and the base of Yamama formations in order to identify their biofacies. These microfossils include rotalid foraminifera, miliolid foraminifera, agglutinated foraminifera, calcareous algae, calcispheres, stromatoporoids, sponge spicules, problematica (e.g. Lithocodium aggregatum), molluscs, corals, echinoderms and ostracods. Systematics of planktic and benthic foraminifera is accomplished using the foraminiferal classification by Loeblich and Tappan (1988) as the main source. The assemblage contains foraminifera that recorded for the first time in the Sulaiy Formation. Other microfossils were identified and recorded to help in the identification of the sedimentary environments. The investigation of the micropalaeontology and the lithofacies analysis have provided evidence the identification of the various lithofacies. About twenty four microfacies were identified on the basis of their bio−component and non-skeletal grains. The lithofacies and the bio−component results have provided the evidence of the sedimentary palaeoenvironmental model namely the Arabian Rimmed Carbonate Platform. This palaeoenvironmental depositional model is characterised by two different platform regimes. They are the Platform Interior and the Platform Exterior each of which have unique sedimentary lithofacies zones that produce different types of lithofacies. Each lithofacies is characterised by special depositional conditions and palaeobathymetry that interact with sea level changes and the accommodation space. The important palaeoenvironments are intertidal, restricted lagoon (subtidal), open marine, deeper open marine, inner shoal, shoal and platform margin. Generating, and testing, a depositional model as a part of formulating a sequence stratigraphical interpretation of a region is a key to understanding its geological development and – ultimately – reservoir potential. The micropalaeontology and sedimentology of the Sulaiy Formation in the subsurface have indicated a succession of clearly defined shallowing−upwards depositional cycles. These typically commence with a deep marine biofacies with wackestones and packstones, capped with a mudstone-wackestone maximum flooding zone and an upper unit of packstone to grainstones containing shallow marine biofacies. The upper part of the Sulaiy Formation is highstand-dominated with common grainstones that host the Lower Ratawi reservoir which is capped by karst that defines the sequence boundary. This karst is identified by its abundant moldic porosity that enhanced the the reservoir quality by increasing its porosities into greater values. Integration of the sedimentology and micropalaeontology has yielded a succession of shoaling−upwards depositional cycles, considered to be 4th order sequences, that are superimposed on a large scale 3rd order system tract shallowing−upwards, highstand-associated sequence of the Sulaiy Formation. The Lower Ratawi Reservoir is located within the latest high-stand portion of a third-order Sulaiy Formation sequence. The reservoir consists of a succession of several sequences, each of which is sub-divided into a lower transgressive systems tract separated from the upper highstand systems tract by a maximum flooding surface (MFS/Z). The last of these depositional cycles terminates in beds of porous and permeable ooid, or ooidal-peloidal, grainstone. The reservoir is sealed by the finer-grained sediments of the Yamama Formation.
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