Temperature dependent magnetization measurements were conducted on Fe-based heterostructures. A linear increase of the magnetic critical temperature with increasing Fe thickness was found for Fe/V superlattices with strong interlayer exchange coupling. For weakly coupled Fe/V superlattices anomalous values of the critical exponent β were attributed to differences in the effective interlayer exchange coupling in the surface region and in the interior of the superlattice stack. Hydrogen loading of a sample containing a thin Fe film, up to a maximum pressure of 4 mbar gave an increase of the magnetic critical temperature of ≈21 K. A sample with a double layer of Fe, exchange coupled over V, showed oscillations in the critical temperature when loaded to increasing pressure of hydrogen. The oscillations in the critical temperature indicate the presence of quasi-2D phases. Superlattices of Fe and V were investigated by x-ray magnetic circular dichroism. It was found that the orbital magnetic moment shows the same trend as the magnetic anisotropy energy with thickness of the Fe layers. A model which takes into account a varying strain and interface density successfully described the changes in the orbital magnetic moment. The magnetization was measured as a function of temperature for a series of magnetically δ-doped Pd samples. A thin film of Fe induced a magnetic moment in surrounding Pd layers, leading to a magnetic thickness one order of magnitude larger than the thickness of the Fe film. A crossover in the magnetic spatial dimensionality was found as the thickness of the Fe film increased from ≈0.4 monolayers to ≈1 monolayer. First principle calculations of the magnetization profile together with a spin wave quantum well model were used to explain the dimensionality crossover by an increase in the available thermal energy for population of perpendicular spin wave modes.