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Geochemistry of Major and Trace Elements in the Kaoping River:Weathering and Human Influences.Lai, I-Chen 14 August 2003 (has links)
Abstract
This study aims to understand the influence of weathering and human perturbation on spatial and temporal variability of major and trace element distributions in the Kaoping River basin. The collected data are used to elucidate the production, transport and export of major and trace elements from the Kaoping River basin.
Experimental results show that the weathering index of the Kaoping River basin is rather high. The significant loss of major ions and enrichment of iron and aluminum from river suspended matter indicate the characteristic of high weathering rate in most tropical rivers. Particulate Si/Al mole ratios range from 1 to 2 showing that the distributions of dissolved and particulate matter are largely controlled by the weathering process of kaolinite and /or smectite formation.
During the study period (2002), the physical and chemical weathering rates were estimated about 655.8 and 416.2 g/m2/yr, respectively. Both physical and chemical weathering rates are much lower than those estimated by Yang (2001) during the period of 1999-2000 [3601 g/m2/yr (physical weathering rate), 1146 g/m2/yr (chemical weathering rate)], due to significant difference in river discharge. However, the estimated physical and chemical weathering rates are still much higher than the world averages of physical (150 g/m2/yr) and chemical (33-40 g/m2/yr) weathering rates. The marked difference between this and Yang¡¦s estimates is caused from large difference in river discharge. Silicate weathering was estimated about 97.09 ¡Ó 2.41% of total chemical weathering in the Kaoping River basin.
The temporal variations of enrichment factor (EF) for most particulate trace metals (Mn, Zn, Cu, Cr, Pb, Cd, and Hg) reveal a greater pollution status in the dry season than in the wet season. Spatial variations of EF also reveal a greater pollution in the downstream zone than in the upstream zone. Time-series observation showed that concentrations of particulate trace elements were inversely correlated with discharge. The significant correlation between the fluxes of dissolved and particulate trace elements and discharge suggesting that river discharge controlled largely the fluxes of major and trace elements. The annual variations of elemental fluxes were determined critically by the annual difference of river discharge.
The distributions of particulate organic carbon (POC) and particulate nitrogen (PN) were similar between suspended matter in the Kaoping River and surface sediments in the Kaoping Canyon. The data of £_13Corg show that about 77.2% of organic matter derived from the Kaoping River basin deposit in the Kaoping Canyon. The Kaoping Canyon appears to play an important role on the transport and deposition of organic matter from the Kaoping River basin.
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Major element composition of the Hadean crust: constraints from Sm-Nd isotope systematics and high-pressure melting experiments / 冥王代地殻の主成分元素組成 : Sm-Nd同位体系と高圧融解実験からの制約Kondo, Nozomi 26 March 2018 (has links)
京都大学 / 0048 / 新制・課程博士 / 博士(人間・環境学) / 甲第21186号 / 人博第858号 / 新制||人||204(附属図書館) / 29||人博||858(吉田南総合図書館) / 京都大学大学院人間・環境学研究科相関環境学専攻 / (主査)教授 小木曽 哲, 教授 石川 尚人, 教授 酒井 敏, 准教授 飯塚 毅 / 学位規則第4条第1項該当 / Doctor of Human and Environmental Studies / Kyoto University / DGAM
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Characterizing Dust from National Wind Erosion Research Network Sites Using Strontium Isotopes, Major and Trace Element Chemistry, and MineralogyMangum, Abby L. 26 June 2023 (has links) (PDF)
The frequency of dust storms is increasing globally yet it is often difficult to determine dust sources in mixed events. Dust events may negatively impact human health, but the composition of major dust sources is not well characterized in arid regions globally. In the western US, the National Wind Erosion Research Network (NWERN) has various sites evaluating seasonal dust emissions to quantify dust fluxes. We used existing dust samples to characterize the isotopic, chemical, and mineralogical composition of dust over multiple seasons from ten representative NWERN sites and compared with land use, vegetation, and surficial geology. Our results show variability in dust chemistry across the ten sites primarily related to differences in surficial geology (local bedrock and sediment) with other factors playing a minor role. In some cases, seasonal vegetation and wind direction played a role in controlling dust composition. For example, the El Reno site showed seasonal differences in mineralogy related to carbonate precipitation and dissolution in the soil during wet summers and dry winters. The Holloman Air Force Base (HAFB) site had distinct seasonal changes in dust chemistry with spikes in Na, Mg, Ca, Ni, and Sr during the spring months possibly related to changes in wind direction and inputs from neighboring White Sands National Park. The Lordsburg Playa site had distinct chemistry relative to other sites with high concentrations of Li, Na, Ca, and Sr due to the prevalence of evaporite minerals. Mineralogy results show the presence of quartz, phyllosilicates, and feldspar minerals at each of the NWERN sites with HAFB also containing calcium sulfate and iron oxide minerals. The 87Sr/86Sr results showed lower ratios correlating with younger bedrock (e.g., ~0.7075 at the Red Hills site surrounded by Miocene volcanic rocks), but some of the sites with recent surficial sediments had higher ratios (e.g., ~0.714 at the CPER site with Tertiary sediments). By creating a library of isotopic, chemical, and mineralogical data for dust sources across the western US, our dataset has implications for identifying characteristics that may be used for tracking dust sources.
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