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Biomimetic models of the active site of the metalloenzyme nitrile hydratase /Schweitzer, Dirk, January 2001 (has links)
Thesis (Ph. D.)--University of Washington, 2001. / Vita. Includes bibliographical references (leaves 163-191).
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Kinetic studies of inorganic and organic peroxo complexes /Saleem al-Shaqri, Layla Mohammed, January 2003 (has links)
Thesis (Ph. D.)--University of Missouri-Columbia, 2003. / Typescript. Vita. Includes bibliographical references (leaves 110-113). Also available on the Internet.
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Electrochemical parametrization of redox potentials of metal complexes and its applicationsLu, Shuangxing. January 1999 (has links)
Thesis (M. Sc.)--York University, 1999. Graduate Programme in Chemistry. / Typescript. Includes bibliographical references (leaves 210-217). Also available on the Internet. MODE OF ACCESS via web browser by entering the following URL: http://wwwlib.umi.com/cr/yorku/fullcit?pMQ56188.
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Design and synthesis of luminescent branched multinuclear platinum(II)alkynyl complexes and the study of their two-photon absorptionpropertiesChan, Ka-man, Carmen, 陳嘉敏 January 2010 (has links)
published_or_final_version / Chemistry / Doctoral / Doctor of Philosophy
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The structural chemistry of coordination compounds containing d-block or f-block metalsSze-To, Lap., 司徒立. January 2010 (has links)
published_or_final_version / Chemistry / Doctoral / Doctor of Philosophy
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Novel organometallic precursors for the Chemical Vapor Deposition of metal thin filmsRivers, Joseph Henry 07 December 2010 (has links)
With the growing demand for miniaturization of devices and for new materials with useful properties, the use of Chemical Vapor Deposition (CVD) for the manufacture of thin films is receiving growing attention. The synthesis of potentially volatile metal complexes and investigation of their use as CVD precursors is an important part of this process. The research presented addresses several major areas of this process, (i) the identification and synthesis of ligands which can impart volatility to a metal complex, (ii) the synthesis, characterization, and assessment of volatility of metal complexes containing these ligands, and (iii) the full materials characterization of thin films grown with these complexes. The use of trimethylphosphine, bis(trifluoromethyl)pyrazolate, and bis(trifluoromethyl)pyrrolyl ligands have been successfully used to synthesize volatile new complexes of cobalt, rhodium, and nickel, some of which show promise for use as potential CVD precursors. / text
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Crystal structure analysis of imido, nitrido and oxo complexes of rhenium (V), osmium (VI) and ruthenium (III) and some complexes oftrinuclear gold (I)張碧玉, Cheung Pik-yuk, Christine. January 1991 (has links)
published_or_final_version / Chemistry / Master / Master of Philosophy
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Ruthenium anticancer complexes : a targeted approach to enzyme inhibitionPage, Simon Matthew January 2013 (has links)
No description available.
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Rotational Spectroscopy and Structures of Organometallic CompoundsKarunatilaka, Chandana January 2007 (has links)
High-resolution pulsed beam Fourier Transform Microwave Spectroscopy (PBFTMS) technique has been used to investigate the rotational spectra, molecular structures and electronic charge distribution of organometallic and organic molecules. The thesis reports high-resolution rotational spectral findings for nine different asymmetric-top molecules in the singlet electronic ground state including: Cyclopentadienyltungstentricarbonylhydride, Bis-(cyclopentadienyl)tungstendihydride, Tetracarbonylethyleneosmium, two substituted Ferrocenes and an organic keto-enol tautomeric system, Z-2-Hydroxypyridine and 2-Pyridone. Moreover, gas-phase rotational constants and distortion constants have also been reported for an excited vibrational state of Cyclopentadienylnickelnitrosyl complex using a high-resolution Fourier Transform Spectrometer (FTS) system at Kitt Peak Arizona, (KPNO). Preliminary microwave results for a fluxional molecule, Cyclopentadienyliridiumdicarbonyl are also presented in this work. Extensive Density Functional Theory (DFT) calculations have been performed in conjunction with the experiments to provide additional insight toward further understanding the equilibrium structures, structural isomers and electric field distributions of these molecules. These calculations were not only helpful in predicting the preliminary structure and rotational constants of the molecules of interest, but also advantageous in analyzing the observed spectra.
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Using cadmium-113 NMR spectrometry to study metal complexation by natural organic matterLi, Jian 05 1900 (has links)
No description available.
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