To investigate the fundamental mechanism of friction stir welding to form a butt joint, two additional tests are performed, one using the rotating probe pin only, the other using the rotating shoulder only. In the first case, the pin tool is plunged into the joint interface, but the shoulder is not in contact with the workpiece. When the pin tool is feeding, the material in the vicinity of the pin tool is scratched and piled on the retreating side, but a butt joint is not formed by this test on two thin plates of aluminum alloy 6061-T6. In the second case, when the shoulder is feeding, the plastic shear deformation of the material in the vicinity of the shoulder can be observed and then it is joined together due to the heat generated from the shoulder to cause the material diffusion. According to these additional experiments and the friction stir welding process, the mechanism to form a butt joint is as following. When the probe plunge into the material and the shoulder is in contact with the workpiece, a large amount of frictional heat is generated from the shoulder and the pin. When the tool moves forward, the soft material in front of the pin is squeezed, so that the material is refilled into the space behind the pin by the rotating pin and shoulder. According to the observation of cross-section of butt joint, an interface curve can be found. This curve is formed by the plastic shear deformation of the material in the vicinity of the shoulder and the pin at high frictional temperature. It can be explained by the boundary layer theory.