Corrosion is a major challenge in the use of molten fluoride salt as a coolant in molten salt reactors (MSRs). A promising way of satisfying the two requirements of high strength and corrosion resistance is to clad structural alloys with a corrosion resistant material. Four candidate cladding and structural alloy combinations—stainless steel 316L and Incoloy 800H structural alloys either diffusion bonded to Hastelloy N or electroplated with nickel—were thermally aged at 700 °C for two to eight months. Based on measured concentration profles, the diffusion resistance of the four material combinations was compared and diffusion results were extrapolated to an end of reactor lifetime. The most important conclusion from this work is that Hastelloy N is highly likely to be signifcantly more diffusion resistant than nickel. The difference in diffusion resistance between Incoloy 800H and stainless steel 316L is relatively small. Two methods were used for extrapolating experimental diffusion results: (1) a diffusion model and calculated diffusion coeffcients and (2) simulations with Thermo-Calc DICTRA. Some simulations were carried out with a corrosion boundary condition of near-zero chromium concentration, demonstrating the potential of simulations for predicting diffusionlimited corrosion in molten fluoride salts. A surprising result of these simulations is that decreasing the thickness of Ni plating did not increase the thickness of diffusion zones in underlying structural alloys. / Thesis / Master of Applied Science (MASc)

This is a report of a verification study of the multiphysics simulation framework MOOSE which was preformed at the company Seaborg Technologies. In the process of designing molten salt reactors there is a special need of making credible multiphysics simulations since the fuel is in motion. In this study the incompressible version of Navier-Stokes equations of finite volumes available in the Navier-Stokes module of the MOOSE framework is verified by modelling and simulations of fluid flow and heat transfer in two different systems with available benchmarks. The first system, a thin buoyancy driven molten sodium hydroxide test loop which is verified by a similar model made with the high fidelity CFD software STAR-CCM+ as benchmark. The second system, forced convection of air through a straight pipe with heated walls which is verified by comparisons with an analytical solution. The resulting velocity profiles from simulations of the first system corresponds well with the benchmark but certain conclusions can not be drawn from it since the the transient simulations stops to converge before reaching equilibrium. The results from simulations of the second system corresponds well with the analytical solution and no convergence issues arise. The conclusion from the results is that the incompressible version of Navier-Stokes equations of finite volumes available in the Navier-Stokes module of the MOOSE framework has potential to be used in multiphysics simulations of molten salt reactors but seemingly not in cases of buoyancy driven flows in thin geometries. Two proposals for further work is recommended. The first is that this implementation is applied in a context with forced fluid flow or a context with thicker fluid domain. The second proposal is that the other available abilities of MOOSE such as finite element method and/or the compressible version of the Navier-Stokes equations should be tested.