In this study, we prepare the zinc oxide nanotip with aqueous solution deposited on ZnO nucleation layer. The thermal annealing with N2 ambiance at 300 oC for 1 hr increase the UV emission and decrease the defects. We use ZnO nanotip as an anti-reflection layer because of surface roughness and optical interference. ZnO nanotip with rough surface decreases reflection, so we use ZnO nanotip as an anti-reflection layer, after grown ZnO nanotip on solar cell the efficiency of solar cell was enhancement. The coordination modes were measured by Fourier-transform infrared spectrometer (FTIR). The physical properties were characterized by X-ray diffraction (XRD). The optical properties were measured by Micro-photoluminescence (Micro-PL). The morphology was observed by field emission scanning electron microscope (FE-SEM). The performance of the cells was measured by a semiconductor device analyzer. In our results, we grow the high performance of ZnO nanotip on solar cell to increase the efficiency. The short-circuit current increased from 42 to 51 mA, and the efficiency increased from 15.7 to 18.8 %.