Plastics fuel tanks have been used successfully abroad ; metal counterparts are still predominant in this country plastics tanks have to satisfy stringent performance regulations : low temperature impact tests ; permeability ; and fire resistance. Blow moulded high density polyethylene (HDPE) fuel tanks have superior strength to mass ratio compared with metal equivalents (the density of steel is about 8000 kg/m3 compared with HDPE, which has a density of under 1000 kg/m3 ). HDPE will tend to drip in a fire situation, thus reducing explosion risk. HDPE is the chosen material because it possesses inherent properties suitable for the blow moulding process : it has a high viscosity at low stresses ; and is highly inert. Rotational moulded HDPE fuel tanks can also be considered. However, these are shown to have inferior properties when compared with blow moulded tanks ; attraction of rotational moulding is the cheapness of equipment. Petrol immersion was found to enhance impact properties of HDPE, although yield stresses were lowered slightly. The thickness distributions of blow moulded fuel tanks were found to vary ; this is because of the present difficulty of predicting parison behaviour with respect to time. Thickness is important because of impact strength and permeation considerations. Impact properties of fuel tanks were assessed ; peak force of impact was found to be heavily dependent on thickness (raised to the power 1.1) and temperature of mould in the blow moulding process (a low mould temperature led to inferior properties). Pinch-offs were found to be particularly detrimental to impact properties. Cooling behaviour was investigated. With the aid of a cooling model for blow mouldings, it was found that a warm mould (40·C) could be used with internal air circulation to obtain a cooling time the same as that with a cold mould and no air circulation. Thus optimising mechanical strength and maintaining economic viability. Welding of injection moulded fittings to the main blow moulded body of the fuel tank was found to be faulty, in all of the tanks examined ; many weld failures have been reported in use. This work determines optimum welding conditions for HDPE grades, these are Rigidex H060-45P and Lupolen 426l-A.

The concept of stay-in-place (SIP) structural formwork has the potential to simplify and accelerate the construction process to a great extent. Fibre-reinforced polymer (FRP) SIP structural formwork offers further potential benefits over existing formwork systems in terms of ease and speed of construction, improved site safety and reduced long-term maintenance in corrosive environments. However, it is not without its limitations, including primarily the possibility of a lack of ductility, which is a key concern regarding the use of FRP structural formwork in practice. This thesis presents the findings of an experimental and analytical investigation into a novel FRP SIP structural formwork system for a concrete slab with a particular emphasis on its ability to achieve a ductile behaviour. The proposed composite system consists of a moulded glass fibre-reinforced polymer (GFRP) grating adhesively bonded to square pultruded GFRP box sections. The grating is subsequently filled with concrete to form a concrete-FRP composite floor slab. Holes cut into the top flange of the box sections allow concrete studs to form at the grating/box-section interface. During casting, GFRP dowels are inserted into the holes to further mechanically connect the grating and box sections. An initial experimental investigation into using GFRP grating as confinement for concrete showed that a significant increase in ultimate strength and strain capacity could be achieved compared to unconfined concrete. This enhanced strain capacity in compression allows greater use of the FRP capacity in tension when used in a floor slab system. Further experimental investigation into developing ductility at the grating/box-section interface showed that the proposed shear connection exhibited elastic-‘plastic’ behaviour. This indicated the feasibility of achieving ductility through progressive and controlled longitudinal shear failure. Following these component tests on the concrete-filled grating and the shear connectors, a total of six (300 x 150 x 3000) mm slab specimens were designed and tested under five-point bending. It was found that the behaviour of all specimens was ductile in nature, demonstrating that the proposed progressive longitudinal shear failure was effective. A three-stage analytical model was developed to predict the load at which the onset of longitudinal shear failure occurred, the stiffness achieved during the post elastic behaviour and, finally, the deflection at which ultimate failure occurred. Close agreement was found between experimental results and the theory.

This thesis deals with the production of a plastic body of the aperture by the method of injection moulding. The work includes a design of the injection mould for the given component. First, an appropriate material for the moulded piece was chosen and then the necessary calculations for the injection mould were made. A quadruplex injection mould with a heated inlet nozzle and pullout cores was designed based on these calculations. Modular components were chosen when designing the injection mould. The next part of the thesis contains the selection of the injection moulding machine for the given mould. The conclusion contains a technical-economical evaluation including the cost estimating for the injection mould and cost estimating for one moulded piece.

For production of double moulded chesses are used lactic acid bacteria, which can be present in a form of non-starter lactic acid bacteria or as starter or adjunct culture. Genera Lactobacillus spp. and Enterococcus spp. are prevalent microorganisms present in these cultures. Of course, these microorganisms are for us interesting because of their possibility of coagulation, proteolytic possibility, probiotic function and antibiotic resistance, but especially because of their decarboxylation abilities. Bacteria contain decarboxylation enzymes, which are able to decarboxylized free amino acid, which rising at proteolysis during process of manufacturing and cheese ripening. Biogenic amines are the result of proteolytic activity. Biogenic amines occur practically in all foodstuffs as a common product of metabolic processes. BA are mainly presented in fermented food (cheeses), where rice just microbial action. Typical representatives of biogenic amines, which occurs in double moulded cheeses (Sedlčanský Vltavín, Bresse bleu) and in blue cheeses (Bleu des Causses, Bleu d'Auvergne) are cadaverine, putrescine, tyramine a 2 fenylethylamine and in much smaller amount histamine, spermidine and spermine too. On assessment concentration of BA is used high pressure liquid chromatography with reverse phase (RP HPLC) with utilizing simple direct derivatization with dansyl chloride and detection by UV VIS detector.

No / The goal of this study was to investigate the fibre orientation distribution (FOD), and subsequent mechanical properties, of an injection moulded plate with two different number averaged fibre lengths, termed in this paper medium (1.35 mm) and long (2.40 mm). Fibre orientation measurements (FOD) were made using the 2D elliptical section method and an in-house developed image analyser. The samples were injected from a pin gate located at the centre and top of the plate. Expansion flow on the divergent flow front from this pin gate resulted in a core region with circumferential alignment, while through thickness shear resulted in the usual realignment of fibres in the flow direction either side of the core, termed the shell layers. Two interesting aspects were discovered from these measurements. First, and most importantly, the FOD was found to be independent of the two fibre lengths in this study, and so predominantly controlled by the mould shape and the interaction with the flow front. Second, the fibres in the core region were found to be much closer packed than those in the shell regions. The interaction between the flow front and the mould shape resulted in a range of FOD across the moulded plate, from equal in-plane orientation at the centre of the plate, to highly aligned at the plate edge. This gave a very useful set of samples from which to test out the well known modified rule of mixtures (MROM). Often the fibre orientation distribution cannot be measured directly, but indirectly using the modified rule of mixtures model in reverse. The samples from this moulding (at two different average fibre lengths) gave an excellent opportunity to validate this often used approach. Both the tensile modulus and strength (measured parallel to the injection direction) were found to show a strong correlation with the measured fibre orientation, with a significant increase in both measures between the centre and the edge of both plates. The increased length of the ‘long’ fibre plate was found to give only a small increase in tensile modulus but a much larger increase in tensile strength. The tensile modulus showed a linear dependence with the measured fourth order orientation tensor average, 〈cos4 θ〉, with respect to the injection direction of the plate, as predicted by the modified rule of mixtures. Excellent agreement was found between the measured modulus and the predictions from the modified rule of mixtures, based only on measured quantities (matrix modulus, fibre fraction and average fibre length) for both plates.

La gran parte de productos de consumo contienen partes realizadas a través del proceso de inyección de termoplásticos, esto constata la importancia de este proceso de conformado con respecto a otros procesos de transformación de plástico. La minimización de los costes para ser más competitivos así como la eliminación o reducción de defectos en las piezas inyectadas, han sido los motivos principales para controlar el proceso a través de la optimización de las variables que entran en juego en este proceso, es por ello que se han realizado numerosos estudios referentes a obtener las relaciones existentes entre las variables del proceso y los aspectos de rentabilidad, estética y defectología de las piezas inyectadas. Modelizar dichas relaciones a través de algoritmos matemáticos con el fin de optimizar los resultados obtenidos y predecir el estado final de las piezas inyectadas han sido los objetivos de la mayoría de estudios. Uno de los efectos intrínsecos a la inyección es la deformación de la pieza, esta deformación tiene lugar debido a distintos factores que intervienen en el diseño del proceso en su conjunto, diferencias en la contracción, diferencias en la refrigeración, las esquinas de la pieza, la orientación molecular, etc son elementos condicionantes de la deformación que se han estudiado en infinidad de artículos, en esta divulgación científica se estudiará la deformación bajo aspectos dimensionales de la pieza con la finalidad de intentar descubrir y optimizar las condiciones de entrada que en este caso serían las dimensiones de la pieza a través de la observación y modelización de las variables de salida que seria la deformación. Y la pregunta que nos realizamos es ¿Cómo varían las deformaciones modificando las dimensiones de la pieza? ¿Cuáles son las dimensiones de la pieza a estudio que minimizan los efectos negativos de la deformación? ¿se puede predecir la deformación que obtendremos en una pieza solo con las dimensiones de una pieza? A todas estas preguntas intentamos dar respuesta en el estudio siguiente. / Gámez Martínez, JL. (2014). ANÁLISIS DE LA DEFORMACIÓN EN LA INYECCIÓN DE TERMOPLÁSTICOS BAJO VARIABLES DE FORMA DE LA PIEZA MEDIANTE RED NEURONAL Y SUPERFICIES RESPUESTA [Tesis doctoral]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/39350

Bacteria are known to adhere to surfaces, which allows for the formation of biofilms, possibly causing a surge in hospital-offset infections, perilous diseases, and in some cases, death. Although certain bacteria are present in the natural flora of the human skin, some present extreme clinical significance due to the ability to transmit and adhere, and can be resistant to antibiotics. They also evolve over time to survive in harsh environmental conditions. Current research reveals that design of plastic surfaces containing submicron structures, is becoming a popular approach to tackle issues concerning infection transmission, with inspiration being derived from biomimetics and self-cleaning surfaces, such as the surface of a gecko skin, and the hydrophobic wax layer of forest leaves. Main barriers to adoption include that these surfaces alone are difficult to manufacture on 3D products, expensive to fabricate on a large scale and do not last long when subjected to environmental wear. Replication of nano-scale ridges was carried out using micro-injection, and the various samples were characterised using a range of tools to determine physical and biomechanical parameters. The sample surfaces were then cultured with the pathogenic bacterium Staphylococcus aureus under several environmental conditions, and the results were statistically analysed to reveal that anti-fouling LIPSS (laser induced periodic surface structures) ridges perform better to reduce bacteria cell-substrate adhesion, when compared to flat surfaces, or surfaces containing dual structures (anti-fouling ridges combined with anti-wear walls). It was therefore demonstrated that nanotextured polymeric surfaces with hydrophobic characteristics have exceptional non-fouling properties, preventing S. aureus, a very significant bacterial strain, from initial adhesion, a critical primary mechanism in its ability to proliferate. Collectively, the findings of this study strongly support the literature, suggesting that the bacteria struggle to adhere onto polymeric topography with increased water contact angles and simple nanostructures. However, the addition of certain anti-wear micro-features increased bacterial adhesion, reducing the efficacy of the non-fouling nanostructures from preventing biofilm formation.

Polyethylene Terephthalate (PET) is one of the most important polymers in use today for packaging due to its outstanding properties. The usage of PET has grown at the highest rate compared with other plastic packaging over the last 20 years, and it is anticipated that the increase in global demand will be around 6% in the 2010-2015 period. The rheological behaviour, thermal properties, tensile modulus, permeability properties and degradation phenomena of PET/clay nanocomposites have been investigated in this project. An overall, important finding is that incorporation of nanoclays in PET gives rise to improvements in several key process and product parameters together - processability/ reduced process energy, thermal properties, barrier properties and stiffness. The PET pellets have been compounded with carefully selected nanoclays (Somasif MAE, Somasif MTE and Cloisite 25A) via twin screw extrusion to produce PET/clay nanocomposites at various weight fractions of nanoclay (1, 3, 5, 20 wt.%). The nanoclays vary in the aspect ratio of the platelets, surfactant and/or gallery spacing so different effect are to be expected. The materials were carefully prepared prior to processing in terms of sufficient drying and re-crystallisation of the amorphous pellets as well as the use of dual motor feeders for feeding the materials to the extruder. The rheological properties of PET melts have been found to be enhanced by decreasing the viscosity of the PET i.e. increasing the 'flowability' of the PET melt during the injection or/and extrusion processes. The apparent shear viscosity of PETNCs is show to be significantly lower than un-filled PET at high shear rates. The viscosity exhibits shear thinning behaviour which can be explained by two mechanisms which can occur simultaneously. The first mechanism proposed is that some polymer has entangled and few oriented molecular chain at rest and when applying high shear rates, the level of entanglements is reduced and the molecular chains tend to orient with the flow direction. The other mechanism is that the nanoparticles align with the flow direction at high shear rates. At low shear rate, the magnitudes of the shear viscosity are dependent on the nanoclay concentrations and processing shear rate. Increasing nanoclay concentration leads to increases in shear viscosity. The viscosity was observed to deviate from Newtonian behaviour and exhibited shear thinning at a 3 wt.% concentration. It is possible that the formation of aggregates of clay is responsible for an increase in shear viscosity. Reducing the shear viscosity has positive benefits for downstream manufacturers by reducing power consumption. It was observed that all ii three nanoclays used in this project act as nucleation agents for crystallisation by increasing the crystallisation temperature from the melt and decreasing the crystallisation temperature from the solid and increasing the crystallisation rate, while retaining the melt temperature and glass transition temperatures without significant change. This enhancement in the thermal properties leads to a decrease in the required cycle time for manufacturing processes thus potentially reducing operational costs and increasing production output. It was observed that the nanoclay significantly enhanced the barrier properties of the PET film by up to 50% this potentially allows new PET packaging applications for longer shelf lives or high gas pressures. PET final products require high stiffness whether for carbonated soft drinks or rough handling during distribution. The PET/Somasif nanocomposites exhibit an increase in the tensile modulus of PET nanocomposite films by up to 125% which can be attributed to many reasons including the good dispersion of these clays within the PET matrix as shown by TEM images as well as the good compatibility between the PET chains and the Somasif clays. The tensile test results for the PET/clay nanocomposites micro-moulded samples shows that the injection speed is crucial factor affecting the mechanical properties of polymer injection moulded products.

Integrally moulded hinges and tension bands are important features in packaging components for plastic closures and their function is critically dependent on the flow induced micromorphology in the hinge section. Polymer characteristics and processing of the hinge also have an influence on the hinge properties obtained. This study is aimed at obtaining interrelationships between polymer characteristics, in-cavity flow, microstructure development and hinge properties, to produce hinges with enhanced functional properties. Three different virgin polypropylene (PP) grades were investigated (homopolymer PP-H, random copolymer PP-RC and impact copolymer PP-IC) and injection moulding simulation was carried out using Moldflow software. In-cavity data acquisition has been carried out for different sets of injection moulding conditions, using high performance transducers and a data acquisition system. A comparison between Moldflow simulation and practical injection moulding data suggests that, for thin wall injection moulded components the real time pressure data are in close agreement during the injection stage. During the packing stage there is some disagreement between these data, since the thickness of hinge and tension band sections are 0.4 mm and 0.5 mm respectively, suggesting that these dimensions are extending the capability of the software. An extensive study using a design of experiments (DoE) approach was carried out on both practical and predictive data. Injection velocity and melt temperature were the most influential factors on the component mechanical properties. From the optical micrographs it is observed that PP-RC has a finer micro-structure compared to PP-H and PP-IC and some micrographs confirm Moldflow simulation results in which hesitation effects are evident, as the flow converges into the thin hinge and tension band sections. PP-clay nanocomposites (PP-CN) were prepared using a twin screw compounder. Transmission electron microscopy (TEM) has shown some evidence of dispersion and exfoliation of the clay particles in the PP matrix. However, X-ray diffraction (XRD) results show a reduction in inter-layer spacing of PPCN s possibly due to clay compaction. The addition of nano-clay however has not resulted in any significant improvements in the mechanical properties of hinges and tension bands. The high degree of molecular orientation induced in the hinge and tension-band sections appears to mask any improvements attributed to the addition of nano-clay. From the reprocessed and post consumer recyclate (PCR) study conducted on hinges and tension bands, it is seen that with an increase in both the re-processing and PCR content there is a decrease in the component strength of around 14%, giving scope to potentially use PCR in future packaging applications. Investigations conducted on colour pigments (violet and green) reveal that the onset of crystallisation for green pigmented mouldings is considerably higher (16°C) than for natural and violet mouldings. Optical micrographs also reveal a finer microstructural texture for green components, indicating a high nucleating capability of the green pigment. Irrespective of the colour, both for hinges and tension bands, the yield stress values were around twice as high as the values quoted in the manufacturer s data sheet for isotropic PP, due to the high levels of molecular orientation in the hinge and tension band sections. In order to industrially validate the findings from the DoE study, commercial closures were produced in industry on a production tool then characterised. In the case of tension bands, there was a good agreement between the results obtained from lab scale and industrial study due to the relatively simple geometry. For hinges this agreement is not so clear. Finally a comparison of mechanical properties of the 3 PP grades shows that PP-H has a higher yield stress compared to PP-IC and PP-RC and yield stress is significantly higher (yield strain values are lower) than values quoted by the manufacturer. The PhD study has confirmed the process conditions that are able to optimise all the interactive effects to improve functional properties in high volume parts in the packaging industry.

Polyethylene Terephthalate (PET) is one of the most important polymers in use today for packaging due to its outstanding properties. The usage of PET has grown at the highest rate compared with other plastic packaging over the last 20 years, and it is anticipated that the increase in global demand will be around 6% in the 2010 ¿ 2015 period. The rheological behaviour, thermal properties, tensile modulus, permeability properties and degradation phenomena of PET/clay nanocomposites have been investigated in this project. An overall, important finding is that incorporation of nanoclays in PET gives rise to improvements in several key process and product parameters together ¿ processability/ reduced process energy, thermal properties, barrier properties and stiffness. The PET pellets have been compounded with carefully selected nanoclays (Somasif MAE, Somasif MTE and Cloisite 25A) via twin screw extrusion to produce PET/clay nanocomposites at various weight fractions of nanoclay (1, 3, 5, 20 wt.%). The nanoclays vary in the aspect ratio of the platelets, surfactant and/or gallery spacing so different effect are to be expected. The materials were carefully prepared prior to processing in terms of sufficient drying and re-crystallisation of the amorphous pellets as well as the use of dual motor feeders for feeding the materials to the extruder. The rheological properties of PET melts have been found to be enhanced by decreasing the viscosity of the PET i.e. increasing the ¿flowability¿ of the PET melt during the injection or/and extrusion processes. The apparent shear viscosity of PETNCs is show to be significantly lower than un-filled PET at high shear rates. The viscosity exhibits shear thinning behaviour which can be explained by two mechanisms which can occur simultaneously. The first mechanism proposed is that some polymer has entangled and few oriented molecular chain at rest and when applying high shear rates, the level of entanglements is reduced and the molecular chains tend to orient with the flow direction. The other mechanism is that the nanoparticles align with the flow direction at high shear rates. At low shear rate, the magnitudes of the shear viscosity are dependent on the nanoclay concentrations and processing shear rate. Increasing nanoclay concentration leads to increases in shear viscosity. The viscosity was observed to deviate from Newtonian behaviour and exhibited shear thinning at a 3 wt.% concentration. It is possible that the formation of aggregates of clay is responsible for an increase in shear viscosity. Reducing the shear viscosity has positive benefits for downstream manufacturers by reducing power consumption. It was observed that all ii three nanoclays used in this project act as nucleation agents for crystallisation by increasing the crystallisation temperature from the melt and decreasing the crystallisation temperature from the solid and increasing the crystallisation rate, while retaining the melt temperature and glass transition temperatures without significant change. This enhancement in the thermal properties leads to a decrease in the required cycle time for manufacturing processes thus potentially reducing operational costs and increasing production output. It was observed that the nanoclay significantly enhanced the barrier properties of the PET film by up to 50% this potentially allows new PET packaging applications for longer shelf lives or high gas pressures. PET final products require high stiffness whether for carbonated soft drinks or rough handling during distribution. The PET/Somasif nanocomposites exhibit an increase in the tensile modulus of PET nanocomposite films by up to 125% which can be attributed to many reasons including the good dispersion of these clays within the PET matrix as shown by TEM images as well as the good compatibility between the PET chains and the Somasif clays. The tensile test results for the PET/clay nanocomposites micro-moulded samples shows that the injection speed is crucial factor affecting the mechanical properties of polymer injection moulded products.