<p> A study of the inter-multiplet Ml transition probability for states populated by the (n,γ) reaction in a number of odd-odd nuclei has been performed. Using a high resolution delayed coincidence system and specially developed calibration and data analysis techniques, lifetime measurements have been made for low energy transitions in 28Al, 32P, 40K, 46Sc, 52v and 56Mn. A theoretical model which uses the static magnetic dipole moments of the corresponding odd-A nuclei as the base states has been investigated and was shown able to produce a very satisfactory agreement with the experimental inter-multiplet B(Ml) values.</p> / Thesis / Doctor of Philosophy (PhD)

Afin de clarifier et caractériser les mécanismes fondamentaux de formation des réseaux étendus cellulaires et dendritiques en régime diffusif, des expériences de solidification dirigée permettant l’observation in situ en temps réel de l’interface solide-liquide d’un alliage transparent ont été réalisées dans l’instrument « DECLIC-DSI» à bord de la Station Spatiale Internationale. Des procédures spécifiques d'analyse d'images ont été développées pour caractériser les réseaux et extraire des données de référence à comparer aux modèles théoriques ou numériques. Les mécanismes d’évolution et de sélection de l'espacement primaire sont décrits et reliés à la courbure macroscopique de l'interface qui apparait comme un paramètre important de la dynamique de réseau. L’obtention de réseaux homogènes étendus nous a permis d'observer des instabilités secondaires du régime cellulaire pour la première fois dans des systèmes tridimensionnels: Oscillation et multiplet structure. Nos analyses mettent en évidence l'absence de cohérence globale de l’oscillation, exceptée dans des zones localement ordonnées dans lesquelles les oscillations de cellules voisines peuvent être synchronisées. Dans une autre gamme de paramètres de contrôle, la formation de multiplets -autre type d'instabilité secondaire- a été observée. La structure et la dynamique de ces multiplets est décrite. Enfin, des essais comparatifs ont été réalisés au sol, pour les mêmes paramètres de croissance, afin de clarifier l'influence de la convection. Les différences entre les expériences au sol et en microgravité, en particulier concernant l'espacement primaire, sont reliées à l'amplitude de la convection. / To clarify and characterize the fundamental physical mechanisms active in the formation of three-dimensional (3D) arrays of cells and dendrites, in situ monitoring of series of experiments on a transparent alloy was carried out under low gravity in the DECLIC-DSI on-board the International Space Station. Image analysis procedures have been developed to characterize the patterns and get benchmark data to compare with theoretical or numerical modelling. The mechanisms of primary spacing evolution and selection are described and related to the macroscopic interface curvature that appeared to be a critical parameter. The extended homogeneous patterns obtained in microgravity enabled us to observe secondary instabilities of the cellular pattern for the very first time in 3D patterns: cell oscillation and multiplet structure. Our analyses highlight the absence of global coherence of cell oscillations, except in locally ordered areas where synchronization of neighbor cells may happen. In another range of control parameters, another type of secondary instability has been identified that corresponds to multiplet formation; the structure and dynamics of those multiplets are also described. Finally, comparative experiments have been performed on ground with similar growth parameters to point out the influence of convection. The differences between ground and microgravity results, especially regarding the primary spacing, are related to fluid flow magnitude.

Les travaux de cette thèse s'efforcent d'apporter une solution au problème persistant de grande pauvreté des lasers à fibre à modes bloqués, en termes de fonctionnalités et de flexibilité. La thèse propose une cavité laser fibrée ayant comme spécificité d'être multifonctionnelle. La cavité est dotée de composants accordables, qui apportent la flexibilité nécessaire pour réaliser des fonctions allant de la génération d’impulsions aux profils complexes (solitons, bi-solitons, tri-solitons, etc) jusqu’à la sculpture des profils d’impulsion, en passant par la régulation des puissances crête, et la régénération de profils d’intensités sévèrement dégradés. La cavité laser que nous proposons a comme spécificité d'être pilotée par un composant clé, qui est un miroir à boucle optique non-linéaire (NOLM : Nonlinear Optical Loop Mirror) multifonction. Nous avons conçu ce NOLM en apportant des modifications structurelles dans l'architecture usuelle de ce dispositif, et en lui adjoignant : une fibre compensatrice de dispersion, un filtre passe bande à bande passante accordable, et un amplificateur (précédé d'un filtre égaliseur de gain, selon le besoin). Le NOLM ainsi conçu est doté de deux paramètres manuellement accordables, à savoir: la bande passante du filtre passe bande et la puissance de pompage de l'amplificateur. Ces deux paramètres permettent de régler sa fonction de transfert, et à accroître ainsi ses fonctionnalités et sa flexibilité. Ainsi, en plus de son rôle comme élément déclencheur du blocage de modes, ce NOLM réalise des fonctions optiques essentielles telles que la régénération des profils d'intensité fortement dégradés par des phénomènes de propagation ; ce qui contribue au renforcement de la stabilité du laser. Nous démontrons également la possibilité de réguler la puissance crête des impulsions, en la verrouillant à une valeur prédéfinie. Nous montrons enfin que le laser multifonction offre la possibilité de réaliser la sculpture des profils d'impulsion, c'est-à-dire, de générer des impulsions dotées d'une puissance crête et une largeur temporelle fixés à l'avance via un réglage approprié des paramètres de contrôle du NOLM.Les applications visées par ce laser multifonction, concernent toutes les activités qui requièrent des sources d'impulsions finement accordables, tant au niveau de puissance crête des impulsions que de leur largeur temporelle. Ces activités, nombreuses dans le domaine Télécom, incluent les opérations de remise en forme des porteuses d'information, les opérations de compression ou étirement de profil d'impulsion, les diagnostics de composants optiques et contrôles non destructifs des lignes de transmission par réflectométrie. / The work of this thesis strives to provide a solution to the persistent problem of poverty of mode-locked fiber lasers, in terms of functionality and flexibility. The thesis proposes a fiber-laser cavity having the specificity of being multifunctional. The cavity is equipped with tunable components, which provide the flexibility to realize functions ranging from the generation of pulses with complex profiles (solitons, bi-solitons, tri-solitons, etc.) up to the carving of pulse profiles, passing through the regulation of peak powers, and the regeneration of severely degraded intensity profiles. The laser cavity that we propose has the specificity of being controlled by a key component, which is a multifunctional nonlinear optical loop mirror (NOLM). We have designed this NOLM by making structural modifications in the usual architecture of this device, and by adding to it: a dispersion compensating fiber, a bandpass filter with tunable bandwidth, and an amplifier (preceded by a gain flattening filter, as needed) with tunable gain. These two parameters make it possible to adjust its transfer function, and thus to increase its functionalities and its flexibility. Thus, in addition to its role as a trigger for mode locking, this NOLM performs essential optical functions such as the regeneration of strongly degraded intensity profiles; which contributes to strengthening the stability of the laser.We also show the possibility of regulating the pulse peak power by locking it around a predefined value. Finally, we show that the multifunction laser offers the possibility to carve pulse profiles, that is, to generate pulses endowed with a peak power and a temporal width set in advance through an appropriate adjustment of the NOLM control parameters. The applications targeted by this multifunction laser are those requiring pulses with finely tunable peak power and temporal width. These activities, include the pulse reshaping in Telecoms, operations of compression or stretching of pulse profiles, optical component diagnostics, and non-destructive control of transmission lines

The electronic structure of some transition metal compounds, specifically, Ca-doped LaMnO3, fundamental Mn oxides (MnO, Mn2O3, Mn3O4, and MnO2), and Fe-doped ZnO is studied using a combination of soft X-ray spectroscopy and atomic multiplet calculations. X-ray absorption spectroscopy (XAS) and X-ray emission spectroscopy (XES) are used as experimental tools to probe the unoccupied and occupied partial density of electronic states,respectively.<p> Ca-doped LaMnO3 perovskites have attracted great attention due to their colossal magnetoresistance and a wide range of magnetic and structural transitions. The magnetic and charge transport properties of these perovskites are directly related with Mn 3d-occupancy or Mn-valency and therefore, an investigation of the Mn-valence at Ca-doped LaMnO3 system is important. In this system, the Mn-valency is generally considered as a mixture of Mn3+ and Mn4+. But my research suggests the presence of Mn2+ at the surface of Ca-doped LaMnO3 samples. It is observed that increasing Ca-doping decreases Mn2+ concentration, and conversely, increases Mn3+ concentration. High temperature annealing at 1000 °C in air leads to the full reduction of surface Mn2+. Mechanisms for these observations are proposed in this study.<p> Mn oxides (MnO, Mn2O3, Mn3O4, and MnO2) are often used as reference standards for determining the Mn-valency in Mn-related complex systems and therefore a detailed understanding of their electronic structure is necessary. The Mn L2,3 XAS and O K XAS are measured for the four Mn oxides consisting of three common Mn oxidation states (Mn2+ in MnO, Mn3+ in Mn2O3, mixture of Mn2+ and Mn3+ in Mn3O4, and Mn4+ in MnO2). A significant energy shift with a systematic trend is observed in measured Mn L2,3 and O K absorption edges. These energy shifts are identified as a characteristic shift for different Mn oxidation states. Mn L2,3 Resonant Inelastic X-ray Scattering (RIXS) spectroscopy is demonstrated as a powerful tool in describing low energy excitations, e.g. d-d excitations and charge-transfer excited states in Mn oxides. For the first time, a RIXS study of Mn2O3,Mn3O4, and MnO2 is accomplished. Atomic multiplet calculations are used to successfully reproduce the energy positions and intensity variations of d-d excitation peaks observed in the experiment, and thus to describe the experimental RIXS spectra.<p> Finally, the local electronic structure of Fe implanted ZnO samples, a useful diluted magnetic semiconductor for spintronics, is investigated to shed light on the existing debate about the origin of ferromagnetism in these materials. Fe L2,3 XAS reveals that doped Fe ions are present in both Fe2+ and Fe3+ valence states. A combined theoretical and experimental study shows that doped ions are incorporated into Zn-sites of ZnO in tetrahedral symmetry. Fe L3- RIXS measurements demonstrate that a high Fe-ion dose of 8 × 107 cm-2 causes formation of FeO clusters, while low dose samples exhibit more free carriers.

The electronic structure of some transition metal compounds, specifically, Ca-doped LaMnO3, fundamental Mn oxides (MnO, Mn2O3, Mn3O4, and MnO2), and Fe-doped ZnO is studied using a combination of soft X-ray spectroscopy and atomic multiplet calculations. X-ray absorption spectroscopy (XAS) and X-ray emission spectroscopy (XES) are used as experimental tools to probe the unoccupied and occupied partial density of electronic states,respectively.<p> Ca-doped LaMnO3 perovskites have attracted great attention due to their colossal magnetoresistance and a wide range of magnetic and structural transitions. The magnetic and charge transport properties of these perovskites are directly related with Mn 3d-occupancy or Mn-valency and therefore, an investigation of the Mn-valence at Ca-doped LaMnO3 system is important. In this system, the Mn-valency is generally considered as a mixture of Mn3+ and Mn4+. But my research suggests the presence of Mn2+ at the surface of Ca-doped LaMnO3 samples. It is observed that increasing Ca-doping decreases Mn2+ concentration, and conversely, increases Mn3+ concentration. High temperature annealing at 1000 °C in air leads to the full reduction of surface Mn2+. Mechanisms for these observations are proposed in this study.<p> Mn oxides (MnO, Mn2O3, Mn3O4, and MnO2) are often used as reference standards for determining the Mn-valency in Mn-related complex systems and therefore a detailed understanding of their electronic structure is necessary. The Mn L2,3 XAS and O K XAS are measured for the four Mn oxides consisting of three common Mn oxidation states (Mn2+ in MnO, Mn3+ in Mn2O3, mixture of Mn2+ and Mn3+ in Mn3O4, and Mn4+ in MnO2). A significant energy shift with a systematic trend is observed in measured Mn L2,3 and O K absorption edges. These energy shifts are identified as a characteristic shift for different Mn oxidation states. Mn L2,3 Resonant Inelastic X-ray Scattering (RIXS) spectroscopy is demonstrated as a powerful tool in describing low energy excitations, e.g. d-d excitations and charge-transfer excited states in Mn oxides. For the first time, a RIXS study of Mn2O3,Mn3O4, and MnO2 is accomplished. Atomic multiplet calculations are used to successfully reproduce the energy positions and intensity variations of d-d excitation peaks observed in the experiment, and thus to describe the experimental RIXS spectra.<p> Finally, the local electronic structure of Fe implanted ZnO samples, a useful diluted magnetic semiconductor for spintronics, is investigated to shed light on the existing debate about the origin of ferromagnetism in these materials. Fe L2,3 XAS reveals that doped Fe ions are present in both Fe2+ and Fe3+ valence states. A combined theoretical and experimental study shows that doped ions are incorporated into Zn-sites of ZnO in tetrahedral symmetry. Fe L3- RIXS measurements demonstrate that a high Fe-ion dose of 8 × 107 cm-2 causes formation of FeO clusters, while low dose samples exhibit more free carriers.

Telica Volcano, Nicaragua, is a persistently restless volcano with high rates of seismicity that can vary from less than ten events to over a thousand events per day. Low-frequency (LF) events dominate the seismic catalogue and seismicity rates at Telica show little clear correlation with periods of eruption. As such, traditional methods of forecasting of volcanic activity based on increases in seismicity and recognition of LF activity are not applicable. A single seismic station has been operating at Telica since 1993, and in 2010 we installed a broadband seismic and continuous GPS network (TESAND network) at Telica. In this study we investigate the seismic characteristics surrounding a nine-month period of phreatic to phreatomagmatic explosions in 1999, and also from the initial three-and-a-half year deployment of the TESAND network, including a three-month phreatic vulcanian eruptive period in 2011. We demonstrate that pertinent information can be obtained from analysis of single-station data, and while large seismic networks are preferable when possible, we note that for many volcanoes this is not possible. We find unusual patterns of seismicity before both eruptive periods; rather than a precursory increase in seismicity as is observed prior to many volcanic eruptions, we observe a decrease in seismicity many months prior to eruption. We developed a new program for cross-correlation of large seismic data catalogues and analysed multiplet activity surrounding both eruptive periods. We observed that the formation of new multiplets corresponds to periods of high event rates (during inter-eruptive periods) and high percentages of daily events that belong to a multiplet. We propose a model for the seismicity patterns observed at Telica, where changes in seismicity are related to a cyclic transition between open-system degassing and closed-system degassing. Periods of open-system degassing occur during non-eruptive episodes and are characterised by high event rates, a broad range of frequency content of events and high degrees of waveform correlation. A transition to closed-system degassing could be due to sealing of fluid pathways in the magmatic and/or hydrothermal system, or due to magma withdrawal. Periods of closed-system degassing are characterised by low event rates, higher frequency contents and low degrees of waveform correlation. Eruptive periods may then represent a transition from closed-system degassing to open-system degassing, however the system must also be capable of transitioning to open-system degassing without eruption. These observations have important implications for volcano monitoring and eruption forecasting at persistently restless volcanoes. Rather than a precursory increase in seismicity as is often observed prior to eruption at other volcanoes, our observations indicate that phreatic eruptions at Telica occur after a decrease in seismicity, a corresponding change in the frequency content of events, and a decrease in waveform correlation. These changes may represent a period of closed-system degassing that could culminate in phreatic eruptions. The inclusion of real-time analysis of variations in frequency content and multiplet activity provides critical information for volcano monitoring institutions.

The aim of this work is to predict the influence of phonon modulations (Kozina et al. 2019 [1]) on the x-ray absorption near-edge fine structure of the Ti-L2,3-edge (Yamaguchi et al. 1982 [2], Thole et al. 1985 [3], De Groot 1990 [4]) in cubic SrTiO3. Employing Density Functional Theory in combination with Multiplet Ligand Field Theory (Haverkort et al. 2012 [5], Luder et al. 2017 [6]), previous experimental and theoretical data on the octahedrally symmetric structure are reproduced with good agreement. Phonon modulations with a maximum atomic displacement of 5% of the lattice parameter are shown to cause polarization-dependent changes in the x-ray absorption spectra just within reach of experimental resolution. This is suggested to reflect the strong susceptibility of the electronic structure to collective lattice excitations in SrTiO3.

La partie ouest du rift de Corinthe, en Grèce, s'ouvre à une vitesse d'environ 15 mm par an générant un taux de déformation parmi les plus élevés au monde, quelques séismes destructeurs de magnitude M>6 par décennie, et une forte activité microsismique irrégulière spatialement et temporellement. Afin de mieux comprendre les mécanismes liés à cette déformation crustale et de préciser les structures majeures actives, ce travail de recherche exploite la base de données sismologiques du Corinth Rift Laboratory de 2000 à 2015 en analysant finement les microséismes et leur évolution spatio-temporelle. La relocalisation globale des sources sismiques ainsi que leur classification en multiplets ont permis de préciser la géométrie des failles et d'identifier des comportements mécaniques différents. La zone ouest, au milieu du golfe, est affectée par des variations de pressions de fluides dans une couche géologique, entraînant des migrations des essaims de microséismes à des vitesses d'environ 50 m par jour. Les multiplets profonds de la partie centrale, près de la côte nord, sont persistants et semblent déclenchés par des épisodes de glissements lents asismiques sur un détachement immature pouvant atteindre la croûte ductile. Le faible pourcentage de déclenchement dynamique par les ondes sismiques suggère que l'état global du système de failles n'est pas au seuil critique de rupture. La magnitude des séismes est corrélée à l'impulsivité initiale de la rupture. Ces résultats précisent la dynamique de déformation du rift, les interactions sismique-asismiques, et permettront d'améliorer les modèles d'aléas sismiques de la région / The western part of the Corinth Rift in Greece is opening at about 15 mm per year, generating one of the highest deformation rates in the world, some destructive earthquakes of magnitude M>6 per decade, and high microseismic activity irregular in space and time. In order to better understand the mechanisms related to this crustal deformation and to specify the major active structures, this research work makes use of the seismological database of the Corinth Rift Laboratory from 2000 to 2015 by finely analyzing microearthquakes and their spatio-temporal evolution. The global relocation of the seismic sources and their classification into multiplets enable to refine the geometry of the faults and to identify different mechanical behaviors. The western zone, in the middle of the gulf, is affected by fluctuations of fluid pore pressures in a geological layer, resulting in microseismic swarm migrations at a velocity of about 50 m per day. The deep multiplets of the central part, near the northern coast, are persistent and appear to be triggered by episodes of slow aseismic slip along an immature detachment, which can reach the ductile crust. The low percentage of dynamic triggering by passing seismic waves suggests that the overall state of the fault system is not at the critical breaking point. The magnitude of earthquakes is correlated with the initial impulsiveness of the rupture. These results specify the dynamics of the rift deformation, the seismic-aseismic interactions, and will make possible the improvement of the seismic hazard models of the region

Un suivi des processus microstructuraux prenant place au cours de la fatigue oligocyclique de l’aluminium pur est assuré par la technique d’émission acoustique EA par ces deux types: émission continue et discrète. Cette technique est intéressante car elle permet de suivre l’évolution dynamique de la structure tout le long de l’essai. Les différents stades du comportement macroscopique du matériau au cours des sollicitations cycliques sont clairement différenciés par l’activité acoustique. Nous distinguons cinq stades : écrouissage primaire, adoucissement primaire, écrouissage secondaire, adoucissement secondaire et rupture. Les trois premiers stades mettent en jeu des phénomènes microstructuraux liés à la plasticité du matériau tandis que des phénomènes relatifs à l’endommagement (micro et macro-fissuration) dominent les derniers stades. L’EA continue résulte de l’effet cumulatif de nombreux mouvements de dislocations de faible amplitude et décorrélés entre eux. Cette plasticité continue diminue au cours du 1er stade mais copie l’évolution de la réponse macroscopique de l’échantillon au cours des stades suivants. Ce comportement est lié aux structures de dislocations établies à travers les différents stades de fatigue. En revanche, l’EA de type discret enregistrée lors des trois premiers stades est associée à un autre type de plasticité : la plasticité intermittente, se manifestant à travers des mouvements coopératifs de grande ampleur, les avalanches de dislocations. Ces avalanches de dislocations génèrent des signaux acoustiques de tailles variables, distribuées en loi de puissance. La plasticité intermittente est alors invariante d’échelle tandis que la plasticité continue met en jeu des mouvements ayant une taille caractéristique. Nous mettons ainsi en évidence pour la première fois la coexistence de ces deux types de plasticité dans un matériau cubique à faces centrées CFC, qui ne sont donc pas incompatibles. Au cours des deux derniers stades de fatigue, les signaux acoustiques enregistrés se catégorisent également en deux groupes: l’un est caractérisé par des invariances d’échelle, l’autre associé à une taille caractéristique. La première catégorie comprend des signaux acoustiques indépendants, apparaissant aléatoirement au cours des cycles. Ces signaux sont générés par des phénomènes de microfissuration au sein du volume de l’échantillon (nucléation, percolation…). Le second groupe, réunit des signaux acoustiques générés quasiment au même niveau de contrainte sur plusieurs cycles successifs et ayant une signature acoustique quasi identique. Nous nommons ces signaux multiplets en référence à la sismologie. Nous émettons l'hypothèse que de tels multiplets d’EA sont la signature de la propagation, cycle après cycle, d'une fissure de fatigue dont la trace peut être vu post-mortem avec les stries de fatigue sur une surface de fracture, ou encore la signature de frottements entre les aspérités présentes de part et d’autre des lèvres de fissures. / An analysis of microstructural processes taking place during low-cycle fatigue of pure aluminum is performed by the Acoustic Emission technique (AE) with its two types: continuous and discrete. The main interest of this technique is that it enables the following of the dynamic evolution of the microstructure during the fatigue test. We distinguished five fatigue stages: primary hardening, primary softening, secondary hardening, secondary softening and failure. The various stages of the material’s macroscopic behavior during cyclic loading are clearly differentiated by the acoustic activity. During the first three stages, mainly microstructural phenomena related to plasticity of material are taking place, whereas damage (micro and macro-cracking) dominate the last two stages. The continuous AE results from the cumulative effect of many uncorrelated dislocations’ movements of low amplitude. This continuous plasticity decreases during the 1st stage but reproduces the evolution of the macroscopic behavior of the sample during following stages. This behavior is related to the dislocation structure established during the various fatigue stages. On the other hand, the discrete AE recorded at the time of the first three stages is associated to another type of plasticity: intermittent plasticity. This plasticity is associated to co-operative dislocation movements of great amplitude; dislocation avalanches. These dislocation avalanches generate acoustic signals power law distributed in amplitude and energies. Intermittent plasticity is then scale invariant while continuous plasticity is associated to dislocation movements with a characteristic size. We highlight for the first time the coexistence of these two types of plasticity in FCC materials, which are therefore not incompatible. During the last two stages of fatigue, the recorded acoustic signals are categorized in two groups: the first one is characterized by scale invariance whereas the other is associated to a characteristic size. The first category comprises independent acoustic signals, appearing randomly during cycles. These signals are generated by micro-cracking events within the volume of the sample (nucleation, percolation…). The second group contains acoustic signals generated almost at the same stress level during several successive cycles and having a nearly identical acoustic signature. We name these signals multiplets in reference to seismology. We put forth the hypothesis that such AE multiplets are the signature of fatigue crack propagation, one cycle after the other, whose trace can be observed post-mortem with fatigue striations on fracture surface, or a signature of frictions between the asperities present on both sides of the crack.

No description available.