Thesis (MScEng (Mathematical Sciences. Applied Mathematics))--University of Stellenbosch, 2006. / An analytical modelling procedure for predicting the streamwise pressure gradient for steady laminar incompressible flow of a Newtonian fluid through homogeneous isotropic granular porous media is introduced. The modelling strategy involves the spatial volume averaging of a statistical representative portion of the porous domain to obtain measurable macroscopic quantities from which macroscopic transport equations can be derived. A simple pore-scale model is introduced to approximate the actual complex granular porous microstructure through rectangular cubic geometry. The sound physical principles on which the modelling procedure is based avoid the need for redundant empirical coefficients. The model is generalized to predict the rheological flow behaviour of non-Newtonian purely viscous power law fluids by introducing the dependence of the apparent viscosity on the shear rate through the wall shear stress. The field of application of the Newtonian model is extended to predict the flow behaviour in fluidized beds by adjusting the Darcy velocity to incorporate the relative velocity of the solid phase. The Newtonian model is furthermore adjusted to predict fluid flow through Fontainebleau sandstone by taking into account the effect of blocked throats at very low porosities. The analytical model as well as the model generalizations for extended applicability is verified through comparison with other analytical and semi-empirical models and a wide range of experimental data from the literature. The accuracy of the predictive analytical model reveals to be highly acceptable for most engineering designs.

Orientador: Geraldo de Freitas Maciel / Resumo: Esta tese de doutorado traz uma abordagem experimental sobre mecanismos de geração, desenvolvimento e propagação em canal de instabilidade na superfície livre de um escoamento de fluido não-Newtoniano. Estas instabilidades, quando evoluem para um padrão estável, exibem comprimento, amplitude e celeridade bem definidos, sendo denominadas roll waves. Na literatura existe uma lacuna no que diz respeito às medições destes fenômenos em condições controladas de laboratório, e com pouquíssimos registros, quando presentes em eventos naturais. Assim, buscou-se neste trabalho projetar e implementar um aparato experimental operacional e de baixo custo com o objetivo de gerar e aferir tais instabilidades, sob condições controladas e sem a influência de vibrações externas (canalete posicionado sobre uma mesa inercial), seguindo metodologia de ensaio proposta e testada. O fluido teste utilizado foi o gel de carbopol 996, que apresentou boa estabilidade e propriedades reológicas aderentes ao modelo de Herschel-Bulkley, tal qual as lamas encontradas em pés de barragens, lamas oriundas de fluxos hiperconcentrados ou de corridas propriamente ditas. Um sistema de sucção-recalque, através de uma bomba hidráulica de cavidade progressiva, impulsionava o gel para o canal de ensaio, garantindo fluxo contínuo do material em regime de recirculação. Para gerar as instabilidades na superfície livre, foi imposta, a montante do canal, uma perturbação, por meio de um pulso de ar controlado em intensidade e... (Resumo completo, clicar acesso eletrônico abaixo) / Doutor

Submitted by EVANDRO FERNANDES DA CUNHA (evandro.cunha@unesp.br) on 2018-11-18T20:13:14Z No. of bitstreams: 1 Tese Evandro Cunha.pdf: 10054124 bytes, checksum: f324825069efc486e2637a46c1b85371 (MD5) / Approved for entry into archive by Cristina Alexandra de Godoy null (cristina@adm.feis.unesp.br) on 2018-11-21T15:21:55Z (GMT) No. of bitstreams: 1 cunha_ef_dr_ilha.pdf: 10054124 bytes, checksum: f324825069efc486e2637a46c1b85371 (MD5) / Made available in DSpace on 2018-11-21T15:21:55Z (GMT). No. of bitstreams: 1 cunha_ef_dr_ilha.pdf: 10054124 bytes, checksum: f324825069efc486e2637a46c1b85371 (MD5) Previous issue date: 2018-07-31 / Esta tese de doutorado traz uma abordagem experimental sobre mecanismos de geração, desenvolvimento e propagação em canal de instabilidade na superfície livre de um escoamento de fluido não-Newtoniano. Estas instabilidades, quando evoluem para um padrão estável, exibem comprimento, amplitude e celeridade bem definidos, sendo denominadas roll waves. Na literatura existe uma lacuna no que diz respeito às medições destes fenômenos em condições controladas de laboratório, e com pouquíssimos registros, quando presentes em eventos naturais. Assim, buscou-se neste trabalho projetar e implementar um aparato experimental operacional e de baixo custo com o objetivo de gerar e aferir tais instabilidades, sob condições controladas e sem a influência de vibrações externas (canalete posicionado sobre uma mesa inercial), seguindo metodologia de ensaio proposta e testada. O fluido teste utilizado foi o gel de carbopol 996, que apresentou boa estabilidade e propriedades reológicas aderentes ao modelo de Herschel-Bulkley, tal qual as lamas encontradas em pés de barragens, lamas oriundas de fluxos hiperconcentrados ou de corridas propriamente ditas. Um sistema de sucção-recalque, através de uma bomba hidráulica de cavidade progressiva, impulsionava o gel para o canal de ensaio, garantindo fluxo contínuo do material em regime de recirculação. Para gerar as instabilidades na superfície livre, foi imposta, a montante do canal, uma perturbação, por meio de um pulso de ar controlado em intensidade e frequência. Após evolução e estabilização, a onda (roll wave) era aferida por meio de sistema de medição ultrassônico na configuração de pulso-eco e, seguindo metodologia inovadora proposta nesta tese, por meio de técnica fotométrica em função da absorção luminosa de um corante (azul de metileno) adicionado ao fluido teste em escoamento. Para confirmação da qualidade dos resultados obtidos pela aplicação das técnicas de medição experimental, foram feitas confrontações entre as técnicas experimentais propostas e entre estas e um modelo numérico, desenvolvido pelo grupo de pesquisa. Por fim, foram testados dois estudos de caso de formação e propagação de roll waves no canal, o primeiro visando a obtenção e tratamento das amplitudes em diversos pontos ao longo do canal, e, no segundo, a influência da frequência de perturbação sobre a amplitude da roll wave, todos para cenários experimentais com números de Froude superiores ao Froude mínimo, condição necessária à geração do fenômeno. / This doctoral thesis brings an experimental approach on generation, development and propagation mechanisms of instabilities free-surface flows of a non-Newtonian fluid. When these instabilities evolve to a stable pattern, they display well-defined length, amplitude and celerity, being denominated as roll waves. There is a great gap in literature concerning experimental data. Few experiments are found relating laboratory measurements of these phenomena in controlled conditions; this is also true when it comes to in situ measurements from natural events. Thus, the aim of this project was to design and implement a low cost operational experimental apparatus to generate and measure such instabilities under controlled conditions, isolated from external vibration influences. This project follows a previous methodology developed which was tested and approved. Carbopol gel 996 was used as test fluid, presenting good stability and rheological properties matching to Herschel-Bulkley model, oftenly used for modeling industrial sludge, slurry fluids, natural mud, among others. A hydraulic circuit was installed in which a progressive cavity hydraulic pump pushed the gel to the inlet of the testing channel, ensuring continuous flow of material, capturing the fluid at the channel outlet. A free-surface disturbance was imposed to the flow through a controlled pulse of air (intensity and frequency) on the upstream flow to produce the free-surface instabilities. After evolution and stabilization, the wave (roll wave) was measured through ultrasonic measurement system in the pulse-echo configuration and also through photometric technique using light absorption by a dye (methylene blue) added to the test fluid. Confrontations of the experimental data were made among the proposed experimental techniques and also with numerical simulations developed by the research group in order to assess the quality of the results obtained by the application of the experimental measurement techniques. Lastly, two case studies of formation and propagation of roll waves were tested: the first one aimed to obtain and process the amplitudes in several points along the channel; the second one, the influence of frequency of disturbance over the amplitude of the roll wave was studied. All the experimental scenarios were tested for Froude number over the minimum value necessary for the generation of the phenomenon.

Fluidos Não-newtonianos estão presentes em grande quantidade na natureza e em muitas aplicações industriais. Tais fluidos apresentam uma variedade de comportamentos específicos. Dentre eles podemos citar: elasticidade, plasticidade, viscosidade variando com a taxa de deformação, tixotropia. Esta tese de doutorado apresenta um recente modelo para Fluidos Estruturados Tixotrópicos (de Souza Mendes, 2009), no qual baseasse nas tradicionais equações de balanço de momentum e massa, em uma equação constitutiva de Maxwell-b modificada e uma equação de evolução para o nível de estrutura do material. Na equação constitutiva de Maxwell-b modificada, tempo de relaxação e viscosidade estrutural são funções da estrutura do material. A equação evolutiva para o parâmetro de estruturação prevê efeitos de tixotropia, dependentes do tempo de equilíbrio do material. As equações que constituem o modelo mecânico para Fluidos Estruturados Tixotrópicos são aproximadas numericamente através do Método de Elementos Finitos de Galerkin Mínimos-quadrados (GLS). Tal método adicionou termos dependentes de malha ao método clássico de Galerkin, de forma a aumentar a estabilidade da formulação original, proporcionando compatibilizar os sub-espaços de velocidade e pressão. São investigados escoamentos creeping flow de Fluidos Estruturados Tixotrópicos em dois problemas clássicos de engenharia: em torno de um cilindro confinado entre duas placas e em uma expansão planar abrupta. Parâmetros relevantes ao modelo são variados em faixas pertinentes ao problema físico simulado e os resultados demonstraram uma boa capacidade de previsão. / Non-Newtonian fluids are present in large quantities in nature and in many industrial applications. Such fluids exhibit a variety of specific behaviors. Among them we can mention: elasticity, plasticity, viscosity varying with the strain rate, thixotropy, etc. This thesis presents a new model for thixotropic Structured Fluids (de Souza Mendes, 2009), in which were a basis in traditional balance equations of mass and momentum, the constitutive equation of Maxwell-type and an evolution equation for the level structure of the material. In the modified constitutive equation of Maxwell-b, relaxation time and structural viscosity are functions of material structure. The structure parameter evolutive equation provides effects of thixotropy, dependent on the equilibration time of the material. The equations which constitute the mechanical model for Structured Thixotropic fluids are approximated numerically using the Galerkin Least-squares Finite Element Method (GLS). Such a method added mesh dependent terms to the classical method of Galerkin in order to increase the stability of the original formulation, providing compatibility between sub-spaces of velocity and pressure. Are investigated Structured Thixotropic Fluids creeping flow in two classical problems in engineering: around a cylinder confined between two plates and in a planar abrupt expansion. Relevant parameters to the model are varied in pertinent ranges to physical problem simulated and the results demonstrated a good predictive capability.

Orientador: Geraldo de Freitas Maciel / Banca: Edson Del Rio Vieira / Banca: Jefferson B. Libardi Liborio / Resumo: Esta dissertação de mestrado traz à discussão o comportamento reológico de misturas formadas por água+colóides+detritos (areia fina), visando entender e esclarecer os processos físicos e mecânicos, tais como sedimentação e ressuspensão de materiais inertes no seio da massa fluida não-newtoniana (água+colóides), bem como verificar a validade ou adeqüabilidade do modelo reológico de Herschel-Bulkley (modelo previamente investigado e validado para misturas compostas de água+colóides) para misturas viscoplásticas com presença de grãos. A variação das propriedades reológicas das misturas, em função das características físicas dos grãos (diâmetro, massa específica e área superficial), é investigada, e um modelo de estimativa de tensão crítica é apresentado. Ademais foram realizados ensaios preliminares de escoamento de fluidos hiperconcentrados em canais inclinados, na tentativa de calibrar uma lei de atrito. Dentro dessas perspectivas, a dissertação é composta de 6 Capítulos com um denso Estado da Arte que descreve os fenômenos e mecanismos que regem os escoamentos desse tipo de compósito. Com base na literatura estudada e, a partir da análise dos resultados experimentais, pôde-se concluir que, para misturas compostas de água+colóides+detritos, o comportamento reológico das misturas é o mesmo que aquele do fluido intersticial (água+colóides), desde que a homogeneidade da mistura seja garantida (não ocorrência de sedimentação e ressuspensão sucessivas). Neste caso, o modelo reológico de Herschel-Bulkley continua sendo válido para explicar as curvas de escoamento ou de fluxo das misturas viscoplásticas com grãos. Para misturas que apresentem os fenômenos de sedimentação e ressuspensão, o modelo de Bagnold, adaptado a fluidos hiperconcentrados... (Resumo completo, clicar acesso eletrônico abaixo) / Abstract: This work retakes the discussion about the rheological behavior of mixtures composed by water+ kaolinitic clay+fine sand in order to investigate the physical and mechanical processes such as sedimentation and suspension of inert materials into the non-Newtonian or interstitial fluid (water+colloids), as well as verify the adaptability of the Herschel-Bulkley rheological model (model previously investigated and validated for composed mixtures of water+ kaolinitic clay) for explain the viscoplastic+coarse materials rheological properties. The variation of the rheological properties of the mixtures in function of the coarse material characteristics (diameter, specific mass and superficial area) was investigated and a model predicting yield stress was proposed. Furthermore, some tests were performed in an inclined canal to determine a friction law for this kind of fluids. Inside of these perspectives, this dissertation is composed of 6 Chapters whit a dense State of the Art describing the phenomena and their mechanisms were pointed up. Based on literature and from the experimental results, one could concluded that the viscoplastic + coarse material mixtures behavior is the same of the interstitial fluid one, since that the homogeneity of the mixture is guaranteed (not occurrence of successive sedimentation and resuspension). In this case, Herschel-Bulkley rheological model is still valid to explain the curves of flow of the viscoplastic + coarse material. For mixtures that present the phenomena of sedimentation and resuspension, Bagnoldþs model, adapted to the hyperconcentrated fluids, describes well the variations of rheological parameters in function of the shear rates applied. Finally, it could be concluded that the experiments of free surface in canals, despite partial, can... (Complete abstract click electronic access below) / Mestre

Dissertation submitted in fulfilment of the requirements for the degreerequirements Master of Technology: Civi Engineering in the Faculty of Engineering at the Cape Peninsula University of Technology Supervisor: APN. Sutherland Co-supervisor: Prof. R. Haldenwang Cape Town October 2013 / The reliable prediction of pressure drop versus flow rate for non-Newtonian pipe flow is important in many industrial processes. In laminar flow scale up is straightforward, but transitional velocity and turbulent flow predictions remain a practical problem. Various theoretical models exist, but nothing in literature shows conclusively which of these is the most reliable and consistent, nor is it evident what effect the choice of rheological model has on the predictions. The aim of this work was to i) evaluate the influence of different rheological models when used in existing prediction techniques for non-Newtonian flow ii) characterise each material type using selected (commonly used) rheological models and iii) predict laminar, transitional and turbulent pipe flow characteristics for each material type using existing prediction techniques, for comparison with experimental results. Only time-independent, homogeneous, non-Newtonian fluids in pipe sizes from 13mm to 200mm were investigated. Rheological models and laminar flow predictions used only the power law, Bingham plastic, Herschel-Bulkley, Casson and Hallbom yield plastic models. The techniques used to predict transitional velocity were Ryan & Johnson, Metzner-Reed, Hedström intersection method, Slatter and Hallbom. For turbulent flow the Newtonian approximation, Dodge & Metzner, Wilson & Thomas, Slatter, Hallbom modified Wilson & Thomas and the Bowen correlation methods were used. The study documents the relevant theory and presents an assessment of the influence of rheology on pipe flow predictions, summarised in terms of the practical performance of the various rheological model/prediction method combinations for the different materials. In laminar flow at practical pseudo shear rates (8V/D; taken as 40s-1) the choice of rheological model does not significantly influence pressure drop predictions. For yield-pseudoplastic materials (eg. kaolin) the Hedström intersection and the Slatter Reynolds number method with Bingham plastic or Casson rheology predicted transitional velocity most accurately. For Bingham plastic materials (eg. bentonite) the best predictions were obtained using the Metzner & Reed Reynolds number with Bingham plastic rheology, although similar results were observed for this technique with all rheologies. The transitional velocity for pseudoplastic materials (eg. CMC) was best predicted by the Slatter and Metzner & Reed Reynolds number methods, using power law or Casson rheology. For turbulent flow of yield pseudoplastic materials the Slatter method using the Casson rheology gave the most accurate predictions overall. Turbulent flow of Bingham plastic materials was best predicted by the Slatter, Hallbom pseudo fluid Nikuradse and Dodge & Metzner methods, using Bingham plastic, Casson or yield plastic rheology. For pseudoplastic materials the Slatter and Wilson & Thomas methods were the most accurate, when used with yield plastic or power law rheology. Transitionalal velocity and turbulent flow predictions for materials with a yield stress vary significantly with rheological model. Laminar data should therefore be examined thoroughly and rheological models fitted with care. For pseudoplastic fluids there is little difference in predictions between the various techniques as long as power law rheology is used.

Thesis (MTech (Chemical Engineering))--Cape Peninsula University of Technology, 2013 / Centrifugal pumps are the most commonly used pumps in slurry transport systems. The design of pumping systems dealing with liquids more viscous than water requires a reliable method of pump performance prediction for the pump selection. For Newtonian fluids, the Hydraulic Institute method is well established, but there is no generally accepted method for non-Newtonian fluids. Many authors have fallen back on using the Hydraulic Institute method for non-Newtonian fluids. This requires a constant viscosity while non-Newtonian fluid viscosity varies with the shear rate. The question arises: What viscosity should be used in this method for non-Newtonian fluids? Two approaches have been developed: the use of a Bingham plastic viscosity made by Walker and Goulas (1984) and the use of the apparent viscosity calculated using an “equivalent hydraulic pipe” diameter, designed by Pullum et al. (2007). Previous results obtained from these two approaches are not in agreement. Therefore, the aim of this study is to explore a suitable procedure to determine a representative non-Newtonian viscosity to be used in the Hydraulic Institute method to predict the pump performance. To achieve this goal, a set of data was experimentally obtained and the existing data were reused. Test work was conducted using the pump test rig in the Flow Process Research Centre at the Cape Peninsula University of Technology. A Warman 4/3 pump was tested, using four concentrations of kaolin suspension and three concentrations of CMC solution. Five pump speeds were chosen to run these tests: 1200, 1400, 1600, 1800, and 2000 rpm. An additional data set obtained by testing two submersible centrifugal pumps with eight concentrations of sludge, in Stockholm, Sweden, was also analysed. These sets of data were analysed firstly according to the Walker and Goulas (1984) approach and secondly according to the Pullum et al. (2007) approach. The use of the apparent viscosity led to the better pump head prediction. The results of this prediction were close to those obtained in the Pullum et al. (2007) work, and even better in some cases. On the other hand, the use of the Bingham plastic viscosity showed better pump efficiency prediction, although the Walker and Goulas (1984) efficiency prediction range was achieved only for one pump out of five. The apparent viscosity reflected the non-Newtonian behaviour but it could not represent alone the non-Newtonian viscosity because of the poor efficiency predictions and the sensitivity of the Pullum et al. (2007) approach to a change in viscosity. From the results of this work, it is advisable that the pump performance prediction be done using both apparent and Bingham plastic viscosity, the apparent viscosity for the head prediction and the Bingham plastic viscosity for the efficiency prediction.

A dissertation submitted to the Faculty of Engineering, Cape Peninsula University of Technology, Cape Town, in partial fulfilment of the requirements for the MTech Degree in Mechanical Engineering 2012 / Flow features provide considerable guidance for the rational selection of techniques to predict hydraulic behaviour and for suitable operating conditions for pipelines. Traditionally, water was used to transport coarse particles, and it was necessary to operate at velocities at which the flow was turbulent in order to avoid blockage. Consequently the friction losses were too high for economic operation. In addition, wear on pipes, fittings and pumps presented serious problems. Nowadays, it is well established that it is possible to operate at very high solids concentration in a heavy vehicle (carrier fluid). Similar solids throughputs may be achieved at very much lower velocities by operating in the laminar flow regime. This results not only in lower power requirement, but it also reduces wear and water consumption. In spite of these potential benefits, only a few studies dealing with the transport of coarse particles in heavy media have been reported. Since the distinction between different flow patterns is of paramount importance for modelling purposes, as equations are flow pattern dependent, and given the importance of avoiding excessive wear of pipes at low and high velocities, the present work was carried out in the context of dense or non-Newtonian carrier fluid. This project comprised analysis of existing data acquired at the Flow Process and Rheology Centre of the Cape Peninsula University of Technology. Kaolin in the range of 6% to 15% volumetric concentration was used as a carrier fluid and coarse material in the range of 10% to 30% volumetric concentration was simulated by silica sand ranging in size from 1 mm to 3 mm. For the purpose of this study flow patterns derived from resistance curves for various mixtures, particle concentrations, particle grading and flow conditions were compared with “concentration profiles” and images obtained from electrical resistance tomography (ERT). It appeared from this work that the sand concentration does not change the flow pattern but increases or reduces the pressure gradients depending on the case. The concentration of kaolin carrier can change the flow patterns from layered to homogeneous flow, inducing an increase in total pressure gradients as it increases. Flow patterns obtained from ERT compared reasonably well with those derived from pressure gradients profiles. The transition velocities from layered to heterogeneous flow obtained from both methods were similar, especially for low and moderate carrier concentrations. As the kaolin carrier concentration or as the sand concentration increased it became more difficult to distinguish the transition velocity between heterogeneous and layered flow. More work is still needed to improve the ERT instrument and its image reconstruction software.

The increasing activity of oil and gas extraction in deep water has stimulated several studies to solve problems encountered in drilling wells. During the drilling operation, a fluid (drilling mud) is pumped through the column to the bottom, carrying to the surface the drill cuttings generated, through the annular space formed between the column and the borehole wall. In this type of flow may appear a kind of hydrodynamic instability characterized by the appearance of toroidal vortices. This type of instability (Taylor-Couette) may profoundly alter the pressure drop of the flow, the shear stress at the borehole wall and the ability of carrying the solids. Moreover, during the process of drilling a well it is necessary promotes the well cementing and coating to provide a mechanical support, as well as, to isolate it from different rock formations traversed. For this step to be successful, the drilling mud must be completely removed from the annular space, and this removal may be impaired in wells which have varying eccentricity along the tube. Due to high costs of correction transactions and loss of drilling time, it is crucial to predict the mud flow around the annular. The effects of this variation of the eccentricity have not been much discussed in the literature, and they may have great influence on the displacement of the mud in the annular space. As an initial phase of work, numerical simulations were performed to study the flow and the emergence of Taylor- Couette instabilities in a concentric annular section, in order to compare them with literature data. Numerical simulations were developed in annular periodic sections, concentric and eccentric (E = 0.5) in order to obtain average profiles of axial and tangential velocities using different turbulence models, aiming at a comparison of simulated results with experimental data from literature. Later, it was made an experimental study and simulation to assess the effect of internal axis rotation on the pressure drop in the flow of non-Newtonian fluids (aqueous solutions of xanthan gum and carboxymethyl cellulose with 0.2% by weight) in a section annular concentric and the other with fixed eccentricity (E = 0.75). Finally, it was elaborated an experimental design (3k) with four variables, such as, xanthan gum concentration (0.05%, 0.10% and 0.15% by weight), eccentricity (0.0, 0.23 and 0.46), fluid flow rate (5, 7 and 9 m3/h) and internal rotation axis (0, 100 and 200 rpm). Following this planning, experimental data of pressure drop were collected, as well as, numerical simulations (CFD) in periodic annular sections to get results of axial velocity, in order to evaluate the effect of variable eccentric rotation on the fluid dynamics of non-Newtonian flows in annular spaces. / A crescente atividade de extração de petróleo e gás em águas cada vez mais profundas tem impulsionando diversos estudos para solucionar problemas encontrados na perfuração de poços. Durante a operação de perfuração, um fluido (lama de perfuração) é bombeado através da coluna até o fundo do poço, retornando à superfície carreando os cascalhos gerados pela broca, passando pelo espaço anular formado entre a coluna e a parede do poço. Neste tipo de escoamento pode ocorrer um tipo de instabilidade hidrodinâmica caracterizada pelo aparecimento de vórtices toroidais. Este tipo de instabilidade (Taylor-Couette), pode alterar profundamente a perda de carga do escoamento, a tensão cisalhante na parede do poço e a capacidade de carreamento de cascalho. Além disto, durante o processo de perfuração de um poço é necessário promover o revestimento e a cimentação do poço para fornecer a sua sustentação mecânica, bem como, para isolá-lo das diferentes formações rochosas atravessadas. Para esta etapa ser bem sucedida, a lama de perfuração deve ser completamente removida do anular, sendo que, esta remoção pode ser prejudicada em poços que apresentem excentricidade variando ao longo do tubo. Devido aos altos custos das operações de correção e a perda de tempo de perfuração, é fundamental prever este deslocamento da lama ao redor do anular. Os efeitos desta variação da excentricidade ainda não foram muito abordados na literatura e podem apresentar grande influência no deslocamento da lama no espaço anular. Como etapa inicial do trabalho, foram realizadas simulações numéricas para estudar o escoamento com surgimento de instabilidades do tipo Taylor-Couette em uma seção anular concêntrica, com intuito de compará-las com trabalhos da literatura. Depois foram desenvolvidas simulações numéricas em seções anulares periódicas, concêntrica e excêntrica (E = 0,5), a fim de obter perfis médios de velocidades axial e tangencial usando diferentes modelos de turbulência, visando uma comparação dos resultados simulados com os dados experimentais da literatura. Posteriormente, foi feito um estudo experimental e de simulação para avaliar o efeito da rotação do eixo interno sobre a queda de pressão no escoamento de fluidos não-Newtonianos (soluções aquosas de Goma Xantana e de Carboximetilcelulose a 0,2% em peso) numa seção anular concêntrica e outra com excentricidade fixa (E = 0,75). Finalmente, elaborou-se um planejamento fatorial de experimentos do tipo 3k com quatro variáveis, tais como, concentração de Goma Xantana (0,05%, 0,10% e 0,15%), excentricidade (0,0; 0,23 e 0,46), vazão volumétrica (5, 7 e 9 m3/h) e rotação do eixo interno (0, 100 e 200 rpm). Seguindo este planejamento foram levantados dados experimentais de queda de pressão, bem como, simulações numéricas (CFD) em seções periódicas para obtenção de resultados de velocidade axial, com intuito de avaliar efeito do movimento de rotação excêntrica variável sobre a dinâmica do escoamento de fluidos não-Newtonianos em espaços anulares. / Doutor em Engenharia Química

Fluidos Não-newtonianos estão presentes em grande quantidade na natureza e em muitas aplicações industriais. Tais fluidos apresentam uma variedade de comportamentos específicos. Dentre eles podemos citar: elasticidade, plasticidade, viscosidade variando com a taxa de deformação, tixotropia. Esta tese de doutorado apresenta um recente modelo para Fluidos Estruturados Tixotrópicos (de Souza Mendes, 2009), no qual baseasse nas tradicionais equações de balanço de momentum e massa, em uma equação constitutiva de Maxwell-b modificada e uma equação de evolução para o nível de estrutura do material. Na equação constitutiva de Maxwell-b modificada, tempo de relaxação e viscosidade estrutural são funções da estrutura do material. A equação evolutiva para o parâmetro de estruturação prevê efeitos de tixotropia, dependentes do tempo de equilíbrio do material. As equações que constituem o modelo mecânico para Fluidos Estruturados Tixotrópicos são aproximadas numericamente através do Método de Elementos Finitos de Galerkin Mínimos-quadrados (GLS). Tal método adicionou termos dependentes de malha ao método clássico de Galerkin, de forma a aumentar a estabilidade da formulação original, proporcionando compatibilizar os sub-espaços de velocidade e pressão. São investigados escoamentos creeping flow de Fluidos Estruturados Tixotrópicos em dois problemas clássicos de engenharia: em torno de um cilindro confinado entre duas placas e em uma expansão planar abrupta. Parâmetros relevantes ao modelo são variados em faixas pertinentes ao problema físico simulado e os resultados demonstraram uma boa capacidade de previsão. / Non-Newtonian fluids are present in large quantities in nature and in many industrial applications. Such fluids exhibit a variety of specific behaviors. Among them we can mention: elasticity, plasticity, viscosity varying with the strain rate, thixotropy, etc. This thesis presents a new model for thixotropic Structured Fluids (de Souza Mendes, 2009), in which were a basis in traditional balance equations of mass and momentum, the constitutive equation of Maxwell-type and an evolution equation for the level structure of the material. In the modified constitutive equation of Maxwell-b, relaxation time and structural viscosity are functions of material structure. The structure parameter evolutive equation provides effects of thixotropy, dependent on the equilibration time of the material. The equations which constitute the mechanical model for Structured Thixotropic fluids are approximated numerically using the Galerkin Least-squares Finite Element Method (GLS). Such a method added mesh dependent terms to the classical method of Galerkin in order to increase the stability of the original formulation, providing compatibility between sub-spaces of velocity and pressure. Are investigated Structured Thixotropic Fluids creeping flow in two classical problems in engineering: around a cylinder confined between two plates and in a planar abrupt expansion. Relevant parameters to the model are varied in pertinent ranges to physical problem simulated and the results demonstrated a good predictive capability.