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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Uso da tecnologia de troca i?nica no tratamento de ?guas contaminadas com Nitrato do Aq??fero Dunas-Barreiras, Natal/RN-Brasil

Fons?ca, Andr?a Lessa da 21 July 2008 (has links)
Made available in DSpace on 2014-12-17T15:01:45Z (GMT). No. of bitstreams: 1 AndreaLF.pdf: 804797 bytes, checksum: e48b62b20831c2372981d6edcc8e4608 (MD5) Previous issue date: 2008-07-21 / The city of Natal comprises an area of about 170 km? (65,63 squares miles). The Dunas-Barreiras Aquifer is the most important reservoir of the coastal basin of RN. It is being responsible for the water supplying of about 70% of the population, however, due to the sewage disposal system by cesspools and drains, it is presently affected in a great extent by nitrates contamination. Thus, the present work proposes to research the utilization of contaminated water by nitrates of this fountainhead and find cost of the potable water through the ionic exchange technology. This technology consists in the removal of mineral salts by the exchange of cations for one ion of hydrogen (H+), through the passage of water by cationic resin bed and, secondly, by the exchange of the anions for hydroxyl ions (OH-) through a anionic resin bed. The obtained results have showed the waters derived from fountains, big water holes and shallow wells were microbiologically contaminated, while the waters derived from deep wells (above 70 m 76,58 yards) were free of contamination. Thus, only these ones are suitable to the use of ionic technology. The experiments were conducted with the resin IMAC-HP-555 such as kinetic, thermodynamic, and adsorption by fixed bed studies, being obtained several project variables for the experimental column, as follow: work temperature of 25oC; resin maximum capacity maximum e mean of adsorption ==0,01692 g NO3-1/g R e 0,0110 g NO3-1/g R, respectively. On the experimental column were performed breakthrough tests which pointed for an average ideal average speed of work of 13.2 m / h, with an average efficiency of 45% of adsorption, an optimal concentration of NaCl desorption of 8%, and an ideal desorption time of 80 minutes for the equilibrium conditions of water from the Dunas-Barreiras aquifer. Scale projection for ion-exchange column for denitrification, for these variables, using a computer modeling programme, to project the column of ion exchange ROREX-420/2000, obtained a cost for the drinking water denitrified by this system of R$ 0,16 / m3 / A cidade de Natal-RN abrange uma ?rea de aproximadamente 170 km2. O aq??fero Dunas-Barreiras, mais importante reservat?rio da bacia costeira do RN, abastece cerca de 70% da cidade. Devido ? aus?ncia de sistema de saneamento municipal e a cidade ter adotado forma de disposi??o de esgotos atrav?s de fossas e sumidouros, este aq??fero apresenta-se, em grande parte, contaminado por nitratos. O trabalho em quest?o se prop?e a pesquisar o aproveitamento da ?gua contaminada desse manancial, assim como estimar o custo da ?gua pot?vel atrav?s da tecnologia de troca i?nica. O estudo da qualidade das ?guas do aq??fero Dunas-Barreiras mostrou que, as ?guas provenientes de fontes, cacimbas e po?os rasos apresentaram-se contaminadas microbiologicamente, enquanto as ?guas provenientes de po?os profundos (superior a 70 m) apresentaram-se isentas, sendo ent?o somente essas adequadas para aproveitamento pela tecnologia de troca i?nica. Foram realizados v?rios experimentos cin?tico, termodin?mico, utilizando (resina IMAC-HP-555) o m?todo da imers?o em volume finito e din?micos da adsor??o por troca i?nica usando-se uma coluna. A partir destes resultados foi projetada uma coluna piloto onde se usou uma resina ani?nica, operando no ciclo cloreto, para remo??o seletiva de nitrato. Os resultados obtidos indicaram uma temperatura de trabalho de 25oC, velocidade m?dia ideal de trabalho de 13,6 m/h, capacidade de adsor??o m?xima e m?dia da resina =0,01692 g NO3-1/g R e 0,0110 g NO3-1/g R, respectivamente, concentra??o ideal de dessor??o do NaCl de 8% e tempo ideal de dessor??o de 80 minutos para as condi??es de equil?brio da ?gua do aq??fero Dunas-Barreiras. Experi?ncia de proje??o de aumento de escala realizada para sistema de coluna de troca i?nica para desnitrifica??o, com as vari?veis determinadas, adotou-se um programa de modelagem computacional para projetos de coluna de troca i?nica, ROREX-420/2000, onde se obteve um custo da ?gua pot?vel desnitrificada de R$ 0,16/m3. Para um volume de ?gua pot?vel produzido igual a 2.100 m3/ ciclo de opera??o foi obtida uma efici?ncia m?dia de remo??o de nitratos de 45%

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