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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Catalytic Effects of Soil Components on the Nitrite Transformation in Buffer Acid Solutions

Kuratti, Laxman G. 01 May 1969 (has links)
Nitrite decomposition in buffer solutions of pH 3, 4, and 5 was observed to be a first order reaction with rate constants (k) 6.39 x 10-3, 1.15 x 10-3, and 0. 17 x 10-3, respectively . When 10 grams of two different soils were introduced, the reaction was catalyzed in all three pH conditions studied . This effect, however, was more pronounced in pH 5. When 10 grams of soil were introduced, all the added nitrite was not recovered. The deficit ranged from 17 to 30 parts per million when 150 parts per million nitrite nitrogen was added and allowed to react for 6 hours. The deficits seemed to increase when the incubated soil samples were used. The major portion of the deficit was suspected to be due to the formation of N2 gas. The effect of three amino acids was studied on the nitrite decomposition. Tryptophan and tyrosine increased the deficit whereas cystine did not have any effect.

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