Orientador: Jorge Isaias Llagostera Beltran / Dissertação (mestrado profissional) - Universidade Estadual de Campinas, Faculdade de Engenharia Mecanica / Made available in DSpace on 2018-08-04T02:56:29Z (GMT). No. of bitstreams: 1 Nascimento_UbiraciSilva_M.pdf: 4551351 bytes, checksum: d36f11b4eb3e73786c0d3e1a3785be33 (MD5) Previous issue date: 2004 / Resumo: Neste trabalho procurou desenvolver-se uma análise teórica da utilização integral do babaçu como fonte energética, procurando da ênfase às potencialidades agregadas ao carvão. Foi realizado um estudo de caso em municípios maranhenses, visando diagnosticar aspectos que relacionam o homem do campo a essa importante fonte de biomassa. Um forno foi projetado para a produção do carvão do babaçu com melhores índices de qualidade e quantidade. O sistema de refrigeração consta de um acoplamento do forno acionado com carvão de babaçu uma geladeira de absorção tipo Platen-Munters, através de um termosifão bifásico fechado. Os resultados obtidos decorreram de uma análise comparativa a um experimento já realizado com um sistema similar, movido a um fogão à lenha, onde percebe-se claramente uma melhoria significativa da eficiência do sistema proposto / Abstract: In this work a theoretical analysis of the integral use of Babaçu looked for to develop itself as energy source, looking for to give emphasis to the aggregate potentialities to the coal. A study of case in maranhenses cities was carried through, aiming at to diagnosis aspects that relate the man of the field to this important source of biomass. The refrigeration system consists of a coupling of the oven a set in motion with coal of Babassu na absorption refrigerator Platen-Munters type, through a closed two-phase thermosiphon. The gotten results had a similar system, moved to a stove to the firewood, where a significant improvement of the efficiency of the considered system is perceived clearly / Mestrado / Refrigeração de Condicionamento Ambiental / Mestre Profissional em Engenharia Mecanica

This project was established with the aim of assessing the extent of the development of new mining communities and the extent to which sport has been involved in the development of new communities around the Witbank district. The development of this project was an endeavour to understand the extent of change in settlement practices of miners, a subject on which there is not much academic literature. From the earlier settlement of small-scale farmers in Witbank, coal mining sprouted. Until the 1980s, a large number of African workers on these mines were migrant labourers housed in single-sex compounds. When the National Union of Mineworkers (NUM) called for the abolition of hostels, the migrant system was seriously affected. With the decline of the migrant labour system, mine workers’ families have been settling with them in units located on or close to the mines. As compounds were converted into family units, African workers tasted the freedom of living with their families. The move from hostels to houses has led to the development of new ‘normal’ communities; ‘normal’ in the sense that they comprise men, women and children. The research shows that the development of new communities has not been automatic, but one that has relied, in particular, on the self-activity of the miners and their families, though often with support from colliery managers. As in the UK and US, various institutions have been involved in developing mining communities, and this study focuses on one of these, a sports association, specifically the Mpumalanga Collieries’ Human Resources Association (MCHRA). Whilst in many respects the new mining communities are similar to those considered in the UK and US, apartheid divisions continue to mark the geography of settlement, with class replacing race as the main marker of division. Sport is crucial in the secondary development of these communities; secondary in that it promotes social cohesion rather than gives rise to the emergence of communities. Nonetheless, sport has already shown its importance in Witbank. It does not only allow families to entertain themselves, but also gives the communities some escape-valve mechanism, as it keeps people busy and away from crime, drugs and alcohol abuse. This study provides valuable evidence of ordinary people taking responsibility for new social problems arising in the post-apartheid era, and they are doing this, in particular, through the mechanism of sport. / Prof. Peter Alexander Ms. Claire Ceruti

M.Tech. (Mechanical Engineering) / Eskom fossil fuel power stations operate under various conditions and the ageing fleet of fossil fuel power stations are under strain due to the rising demand in electricity. The quest for cheaper electricity in growing businesses and bringing foreign investment into South Africa is significant for economic growth. Therefore, minimizing operation costs and improving availability, reliability and thermal heat rate are key objectives for the operation of the business. Thermal heat rate calculation is a method used to assess the performance of fossil fuel power stations. It provides an indication of the thermal performance which reflects the condition and operation of the plant. This dissertation refers to the tools used to measure the condenser performance and to identify the reason for unhealthy condenser performance and an increase in thermal heat rate. Problem: Poor condenser performance causes significant losses in generation and thermal heat rate in fossil fuel plants. Loss in generation and thermal heat rate is caused by condenser backpressure. This has an adverse effect on turbine thermal heat rate and henceturbine efficiency. The performance of the condenser affects the turbine performance to a large extent. Decreased condenser performance will increase the turbine thermal heat rate, i.e. kJ/kWh, because of the increased steam consumption per kWh of energy generated and therefore lowering the overall turbine efficiency. This will result in poor thermal heat rate efficiency resulting in an increased coal burn rate, i.e. kg/kWh, and an increased fuel bill and carbon foot print for the fossil fuel power station. The aim of this dissertation is to determine the effects of condenser performance on thermal heat rate and to provide the engineering and operating personnel with a guide for monitoring condenser back pressure in order to improve turbine thermal heat rate and turbine efficiency. Method and Procedure: Chapter 4 describes the method and procedure used for the pre and post outage evaluation to cost-effectively determine the current condition of the condenser and to quantify the increase in thermal heat rate due to condenser degradation. The pre and post outage evaluation offered an opportunity to evaluate and quantify the effectiveness of the maintenance program and the value of the capital layout undertaken during the scheduled Unit outage. Findings: Chapter 5 discusses the findings of the pre and post outage data analysis of the condenser using the EtaPRO system as the tool. Re-tubing 50% of the condenser inner loop tubes and cleaning the other 50% of the outer loop tubes demonstrated a decrease in condenser backpressure and therefore an improvement in thermal heat rate. This will also result in an improvement in turbine cycle efficiency and reduce coal cost.

M.Sc. (Geology) / The purpose of this study was to assess the MLA’s ability to characterise (e.g. modal mineralogy, elemental assay, particle size distribution, particle density distribution and mineral associations) a coal product from New Vaal Colliery, with the aim to determine any liberation and beneficiation characteristics. In general the MLA assessment on coal is comparatively new and novel, especially at Spectrum (University of Johannesburg), hence research in this regard is required. For the first time New Vaal coal product was characterised with the MLA 600 FEG SEM. The coal product supplied to Lethabo Power Station for the study’s samples, consisted of Top Seam and Middle Seam coal from New Vaal Colliery which is located in the Cornelia subbasin of the Vereeniging-Sasolburg coalfield, South Africa. The proximate analysis characterised the coal as a high-ash (42.25% air-dried) and low calorific value (13.92 MJ/kg air-dried) product. Chemically SiO2 was the most abundant oxide followed by Al2O3 for the XRF analysis, which was mostly derived from the abundant kaolinite clay mineral (determined by petrography, XRD and MLA analysis). Mineralogically inertinite was the most abundant coal maceral encountered during the petrographic analysis. With geochemical characterisation, chalcophile, siderophile, lithophile and radioactive trace elements were found to be mostly comparable to the global average.

M.Sc. / Worldwide, coal is one of the major sources of energy. In 1999 it was estimated that the global electricity generation from coal was about 36% of the total world electricity production (Knapp, 1999:11). With the combustion of coal for electricity generation however, negative environmental impacts occur. These are mainly caused by carbon dioxide, nitrous oxides, sulphur dioxide and particulate matter emissions. With an ever-growing global population, the need and demand for electricity is increasing. These needs and demands need to be addressed in an economically, socially and environmentally acceptable manner. In this study the author examines, analyses and compares the emissions from coalfired power stations in South Africa, Australia, Canada, Germany, India and the United States of America over a chosen period of time (1995-2001). The results of the study indicate, that, within the comparative group, South Africa is not the greatest producer of emissions from coal-fired power stations. It is the fourth biggest emitter of CO2. It has the highest SO2 emissions, because of the low-grade coal burned in the power stations that have been specifically designed to burn this type of coal. It is the second biggest emitter of NOx, and the third biggest emitter of particulates. Germany is the country that has shown the greatest progress in emissions reductions. This has been the result of restructuring and economic incentives. Overall, South Africa can be ranked third, on par with Australia.

Philosophiae Doctor - PhD / The mining industry in South Africa has a huge potential to impact negatively on the environment. Negative impacts include generation of reactive tailings and acid mine drainage (AMD). AMD is highly acidic (pH 2-4), sulphate-rich and frequently carries a heavy metal burden. South Africa uses more than 100 million tonnes of low grade bituminous coal annually to produce cheap electricity. The associated mining operations result in millions of tonnes of polluted water and in turn coal burning power stations produce vast amounts of waste ash such as fly ash. The highly soluble CaO occurring as sub-micron fragments on the fly ash particles is highly reactive and can be utilized in the neutralization of acid mine drainage. Acid mine drainage (AMD) was reacted with two different South African fly ashes in a batch setup in an attempt to evaluate their neutralization and inorganic contaminants removal capacity. The concentrations of major constituents in the AMD were found to determine the final pH attained in the reaction mixture and the reaction time of breakthrough to circum-neutral and alkaline pH. Efficiency of elemental removal in the AMD by the FA was directly linked to the amount of FA in the reaction mixture and to the final pH attained. Most elements attained ≈ 100 % removal only when the pH of minimum solubility of their hydroxides was achieved. In the second part of the study, Acid mine drainage (AMD) was reacted with coal fly ash in a 24 hour equilibration time using 1:3 and 1:1.5 FA: AMD ratios by weight to produce neutral and alkaline process waters. The capacity of the fly ash to remove the major inorganic contaminants from AMD was examined with time. The geochemical computer software PHREEQC and WATEQ4 database were used for geochemical modeling of the process water chemistry at selected reaction times. The collected solid residues were analyzed by X-ray diffraction, scanning electron microscopy (SEM) and scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDX). At both ratios the reaction mixture was at saturation or oversaturated with alunite, basaluminite, jurbanite, boehmite, gibbsite, diaspore, gypsum, barite, K, Na-jarosites, ettringite, amorphous Fe (OH)3 and goethite at specific contact times. The precipitation of the many inorganic contaminants was established in terms of the mineral phases at saturation or over-saturation. Sequential extraction revealed the amorphous fraction to be the most important in retention of the major and minor inorganic contaminants at pH > 6.32 which implies that the concentration of total Fe and Al in the AMD being treated has a direct effect on the clean-up efficiency of the process. In the third part of the study, a column leaching of the solid residues (SR) blended with varying amounts of fly ash (5 %, 25 %, 40 %) and 6 % Ordinary Portland Cement (OPC) was carried out to assess the contaminant attenuation with time. The columns were drained with synthetic acid mine drainage (SAMD) over a period of 165 days. In addition the solid residues were modified with 1-6% OPC and their strength development monitored over a period of 365 days. The column solid cores were observed to acidify in a stepwise fashion, exhibiting three buffer zones. The SR alone and SR blended with fly ash exhibited strong buffering capacity at pH (7.5-9) for an extended period of time (97-110 days). Encapsulation of solid residue particles by the calcium silicate hydrate gels (CSH) in OPC blended solid residues obscured the appearance of the sustained buffering at pH 7-9.5. The fly ash and OPC blend solid residues exhibited decontamination efficiencies of (82-99 %) for Al, Fe, Mn and SO4 2- over the study period. However the OPC blend SR exhibited high attenuation efficiency even as the pH dropped to below 4. SR + 6 % OPC core was observed to be the most efficient interms of retention of highly mobile elements such as B and Mo. pH was observed to be the main determining factor in contaminants attenuation. Geochemical modeling results revealed that pH and SO42- concentrations in the leachate had a significant impact on the mineral phases controlling Fe and Al concentration in the leachates. In the SR + 6 % OPC solid cores, EDX analysis revealed that CSH gels and calcium aluminate hydrate gels were being precipitated. These gels were either incorporating Fe, Mg, Mn in their matrix or encapsulating the solid residue particles that were rich in these elements. Sequential extractions of the leached solid cores revealed the amorphous fraction to be the most important in retention of the major contaminants and were most enhanced in the OPC blend solid residues. The OPC blend solid residue slurries developed unconfined compressive strength (UCS) (2-3 Mpa) comparable to paste formulated from sulphidic rich mine tailings confirming that the solid residues can be used for backfilling. Therefore the solid residues (SR) can successively be applied for a dual purpose in mined out areas namely, to remediate acid mine drainage waters and also provide support for the overburden. Keywords: Acid Mine Drainage; Fly Ash; Neutralization; Sulphates; Metal ions; Solid Residues (SR); Column Leaching; Geochemical Modeling; Sequential Extraction; Buffering. / South Africa

Doctor Scientiae / The management of the large volumes of solid wastes produced as coal combustion residue is of particular concern due to the presence of leachable metals and salts which may constitute a long term environmental risk and potential contamination of both surface and groundwater systems of the surrounding environment. In order to implement an efficient monitoring scheme and to assess the impact of the ash dump on the hydrologic system, a thorough knowledge on the migration of solutes fluxes in dry ash dumps as well as the controls on the transport of these solutes to the underlying groundwater system is required. The conventional methods which have been widely used for such applications are centred on extracting and analysing several samples from observation wells are drilled on the dump. This has however created a potentially hazardous situation as the installation of monitoring wells may result in the creation of new fluid pathways and results in further migration of leachates. Nevertheless, non–invasive characterization has often been useful in the determination of subsurface hydraulic properties and is a key step towards the solution of real-life problems in hydrology, hydrogeology and soil science. In contaminant transport non-invasive methods have often proved to be an efficient tool as compared to traditional drilling and sampling techniques which in most cases results in the creation of preferential flow paths and do not allow for the space and time resolution needed for the monitoring of hydrological and environmental processes. In this context, this study seeks to develop a generic conceptual model for the ash dump through the use of non-invasive geophysical techniques and numerical modelling techniques at the Tutuka Ash dump, Mpumalanga South Africa. Changes in electrical resistivity were used correlate changes in moisture contents during moisture and salt leachate ingression in ash dumps with a sufficient accuracy. A determination of the suitability of Archie‘s law to describe the relationship between electrical resistivity and solute transport ash medium was achieved through empirical laboratory experiments. Electrical resistivity tomography was then used as an appropriate tool for the elucidation of potential flow paths and brine dispersion in the ash dump. The flow rates through the ash dump were estimated by considering the rate of brine injection and the distance travelled by the brine plume over the time spanned in time lapse infiltration experiments. Additional geophysical profiles managed to show the lithostratigraphy of underlying hydro-geology, thereby ensuring that the knowledge of the geology can be established without the application of any intrusive methods. To ensure that development of the conceptual model of the unsaturated zone transport of the ash dump was developed with sufficient accuracy, numerical models were also used to describe solute transport in the vadose zone. The HYDRUS2D numerical package was used simulate the flux dynamics within the unsaturated zone of the coal ash medium, so as to develop a conceptual understanding of water flow and salt transport through the unsaturated zone of the coal ash medium. The results from the study suggested a conceptual solute transport model that consists of a two layers. The upper layer represented the unsaturated zone of the ash dump which was the source of any potential contaminant transport that could be of concern. The lower layer describe the underlying the subsurface environment to the ash dump which include the soil zone, the shallow aquifer and the deep fractured rock aquifer. To enable this conceptualisation, results from the numerical simulations and geophysical interpretations of the electrical resistivity profiles were the critical components for optimising the site-specific subsurface water flow and solute transport processes, as well as producing the most acceptable conceptualisation of the ash dump system that could be used in hazard assessment and mitigation against potential groundwater pollution. The conceptual models developed in this study proposed an explanation on impact of the ash dump to the hydro-geologic and the eco-hydrologic environment by proposing a scenario of contamination of the underling ash dump and the existing. In this regard, the study managed to provide important scenarios that may be necessary during mitigation procedures for both the ash dump and the wetland. Key words: non-invasive, coal ash, time lapse, electrical resistivity tomography, numerical models, HYDRUS2D, conceptual model.

>Magister Scientiae - MSc / Lab conducted proximate analysis of coal bearing rock units calculates the weight percentage of ash, moisture, fixed carbon and volatile matter through a series of combustion steps. The data obtained is quintessential in establishing the coal rank and in the case of coal bed methane the gas-in-place estimates. In this study 105 proximate analysis samples, from 7 drilled wells, are taken from the south-eastern Kalahari Basin in Botswana. The pseudo proximate analysis, the method proposed in this thesis, calculates the lab proximate analysis results using the neutron, density and gamma ray wireline logs. The uniqueness of the method lies in the fact that no cut off values are needed for the wireline logs, nor are the results of the lab proximate analysis required for calibration. An in depth study of the relationship between the wireline logs and proximate analysis is conducted using a principle component analysis and the results tested using a combination of statistical techniques to determine the significance of the relationship. It is shown that the density and neutron logs model the proportion of ash and volatile matter in the rock matrix, respectively, with a high degree of accuracy. The multiple regression analysis shows that percentages fixed carbon and moisture components of the rock matrix correlate poorly to the proposed well logs, thus most error lies in the determination of these two components. It is statistically proven that the pseudo proximate analysis results are significantly different to the lab measured proximate analysis. This implies that the proposed pseudo proximate analysis method is unable to accurately determine the components of a coal bearing rock matrix using the density, neutron and gamma ray wireline logs. The application of the proposed method is a model to identity the coal bearing rock matrix and provide a predictive estimation of the coal quality, a priori lab measured data.

>Magister Scientiae - MSc / In South Africa coal combustion constitutes up to 90 % of the country’s energy need. This coal combustion activity is known to contribute to the amount of about 40 % of the total CO2 atmospheric emissions worldwide that are responsible for global warming effects. In addition burning of coal generates a large quantity of fly ash which creates environmental pollution since only a small portion of it is currently used in some applications. In order, on one hand to mitigate and sequester CO2 and on the other hand to reprocess fly ash and reuse it, this study focuses on developing new technologies with cost-effective and less energy consumption in the domain of CO2 capture and sequestration. CO2 has priority attention for being the largest contributor to global warming. Various techniques have been used for CO2 capture and sequestration, such as aqueous alkylamine absorption or adsorption onto a solid adsorbent such as zeolites. In this study NaA zeolite adsorbent was hydrothermally synthesised from South African fly ash. This fly ash based NaA zeolite was then used as starting material to prepare LiA, CaA, and MgA zeolite catalysts via ion-exchange for comparative CO2 adsorption capacity. A systematic design of the ion-exchange procedure was undertaken at either 30 °C or 60 °C for a contact time of 1 hr, 4 hrs, and 8 hrs with 1, 2 and 3 consecutive exchanges in each case in order to determine the optimum conditions for loading each cation exchanged. The adsorption of CO2 on the ion- exchanged fly ash based zeolite-A catalysts was carried out at 40 °C similar to the temperature of flue gas since the catalysts obtained in this study were also prepared with a view to their applications in flue gas system. The CO2 desorption temperature ranged between 40-700 °C. All materials used in this study, starting from fly ash feedstock, werecharacterized using various techniques to monitor the mineral and structural composition, the morphology, surface area and elemental composition and the adsorption capacity. The techniques included mainly Fourier transform infra-red, X-ray diffraction, Scanning electron microscopy, Transmission electron microscopy, Energy dispersive spectroscopy, X-ray fluorescence, Temperature programmed desorption.The results obtained from both Fourier transform infra-red and the X-raydiffraction spectroscopy for samples exchanged at either 30° C or 60 °C showedlower crystallinity in CaA and MgA zeolite samples. This decrease in crystallinitymainly affected the D4R (0-20° 2) and was demonstrated in the study to beinversely proportional to the increase of the atomic radius of cations (Li+ > Mg2+ >Ca2+). In the Fourier transform infra-red, the vibration band at 677 cm-1 attributedto the extra-framework cation, also proportionally increased with the decrease ofthe atomic radius or size of the cations, and was intense in LiA zeolite samples.

Philosophiae Doctor - PhD / The Yayo district in southwest Ethiopia is a biodiversity hotspot area historically containing a rich diversity of wild coffea arabica cultivars and Afromontane forest species of commercial and scientific value. Informed by political ecology and using qualitative research methods, notably participant observation, personal interviews, transect walks and analysis of secondary literature and videos, the study documents three major shifts in access, use, control and management of wild coffee and other natural resources in the Yayo district: first, village-level small-scale wild coffee cultivation and forest product harvesting; second, conservation and designation of protected forest areas and use zones, and most recently, coal mining and the future development of a fertiliser plant. The study details in depth how these three resource control regimes came to be and especially the social impacts they entailed on local (indigenous) communities residing in four villages in the Yayo district: Achebo, Gechi, Wabo and Wutete. It concludes with a discussion on the local socio-ecological impact and challenges facing the long-term survival of the local communities and wild coffea arabica forest biodiversity in the area. Since the early 1900s, the wild coffee forests were managed and used by local, indigenous communities based on customary social institutions including Abbaa lafaa, Ciiqaashuum, Qoroo, Tullaa, Xuxxee, and Shaanee. These institutions eroded overtime as the Ethiopian state working in tandem with professional conservationists valued the wild coffee forests for their forest biodiversity and strove to control historic wild coffee use through protectionist approaches. The thesis discusses how the restriction of access not only resulted in a range of negative social effects (such as displacement, joblessness, and landlessness) but also gave rise to occasional local conflicts and formal and informal resistance towards the conservationists and their programmes. As such, the protectionist approach did not succeed in safeguarding the wild coffees or the livelihoods of the local communities. Threats to the wild coffee forests were subsequently raised again with the rise of largescale coal mining operations in the forest. Driven by concern for economic growth, the state has shifted its attention from biodiversity preservation to supporting a coal mining operation in the area and the construction of the first-ever in country fertiliser factory in Yayo. With the advent of coal mining interests, not only have the historic customary rights and livelihoods of local communities been further weakened but also those of the power of the conservation regime. The early construction phases of the fertiliser factory have led to involuntary displacements, unfair expropriation of villagers’ properties, forest and wild coffee clearance, emergence of new diseases such as malaria, and damage to physical infrastructure. Overall, the study shows that the progressive shifts in resource access, control and use have occurred as a result of changing ecologies, ecological knowledge and values, community dynamics, economies, and the shifting policies and strategies of the government of Ethiopia. These changes, especially the control of resources by mining proponents, suggest major challenges for the future existence of wild coffea arabica cultivars in the area and the wellbeing of local communities who had used and managed them in the past.