abstract: Nitrate contamination to groundwater and surface water is a serious problem in areas with high agricultural production due to over application of fertilizers. There is a need for alternative technologies to reduce nutrient runoff without compromising yield. Carbon nanoparticles have adsorptive properties and have shown to improve germination and yield of a variety of crops. Graphite nanoparticles (CNP) were studied under a variety of different fertilizer conditions to grow lettuce for the three seasons of summer, fall, and winter. The aim of this thesis was to quantify the effect of CNPs on nitrate leaching and lettuce growth. This was accomplished by measuring the lettuce leaf yield, formulating a nutrient balance using the leachate, plant tissue, and soil data, and changing the hydraulic conductivity of the soil to assess the effect on nutrient mobility. summer and fall experiments used Arizona soil with different amounts of nitrogen, phosphorus, and potassium (NPK) fertilizer being applied to the soil with and without CNPs. The winter experiments used three different soil blends of Arizona soil, Arizona soil blended with 30% sand, and Arizona soil blended with 70% sand with a constant fertilizer treatment of 30% NPK with and without CNPs. The results showed that the 70% NPK with CNP treatment was best at reducing the amount of nitrate leached while having little to no compromise in yield. The winter experiments showed that the effectiveness of CNPs in reducing nitrate leaching and enhancing yield, improved with the higher the hydraulic conductivity of the soil. / Dissertation/Thesis / Masters Thesis Civil, Environmental and Sustainable Engineering 2018

South Florida continues to become increasingly developed and urbanized. My exploratory study examines connections between land use and water quality. The main objectives of the project were to develop an understanding of how land use has affected water quality in Miami-Dade canals, and an economic optimization model to estimate the costs of best management practices necessary to improve water quality. Results indicate Miami-Dade County land use and water quality are correlated. Through statistical factor and cluster analysis, it is apparent that agricultural areas are associated with higher concentrations of nitrogen, while urban areas commonly have higher levels of phosphorous than agricultural areas. The economic optimization model shows that urban areas can improve water quality by lowering fertilizer inputs. Agricultural areas can also implement methods to improve water quality although it may be more expensive than urban areas. It is important to keep solutions in mind when looking towards future water quality improvements in South Florida.

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Agricultural runoff is one of largest contributors of phosphorus (P), nitrogen (N), and sediment affecting freshwater systems in watersheds across the Northeastern U.S., including the Lake Champlain Basin in Vermont. Agricultural cropping systems, such as corn silage and haylands, used for dairy feed production have been shown to impact watershed hydrology and water quality. Agricultural best management practices (BMPs) have the potential to decrease runoff volumes and flow rates and the associated export of nutrients and sediment from agricultural fields. Many states in the Northeastern U.S., including Vermont, are beginning to require farmers to implement water quality BMPs and further improve risk evaluation of export of P in runoff using evolving P site assessment tools, such as the Phosphorus Index (P-Index). Quantifying the effects of BMPs on hydrologic and nutrient exports from fields is critical for informing site assessment tools that aid in the development of nutrient management plans and to help design agroecosystems that do not degrade water quality. However, there is a lack of data on the effects of BMPs on edge-of-field hydrologic and nutrient fluxes, especially in cold-climate regions with snow-melt induced runoff events. This thesis consists of four chapters, Chapter 1 is a comprehensive literature review on agricultural hydrology and water quality, BMP effectiveness, and P site assessment tools. Chapters 2 and 3 address research objectives related to the evaluation of BMP and P site assessment tool effectiveness. Chapter 4 is a summary of the conclusions drawn from the work done in Chapters 2 and 3, and suggestions for future work. Chapter 2 evaluates the effects of soil aeration prior to manure application on edge-of-field hydrology, water quality, and P fluxes in haylands with clay soils during both precipitation and snow-melt induced runoff events. Edge-of-field water quality monitoring techniques and passive-capillary lysimeter systems were used to continuously measure the losses of surface runoff, subsurface leachate, and the associated export of nutrients (total phosphorus, total dissolved phosphorus, total nitrogen, and total dissolved nitrogen) and total suspended solids resulting from runoff events year-round from 2012 to 2018. Annual P fluxes in the form of vegetative uptake and removal, manure additions, and soil test P were also recorded. Results from this study indicated that soil aeration had the potential to reduce nutrient and sediment exports from haylands with poorly-drained, high runoff producing soils in the Northeastern U.S. where winter freeze-thaw conditions exist. However, potential increases in surface and subsurface hydrologic flows can accompany these reductions; these implications should be considered before implementation. Chapter 3 identifies potential P-Index improvements through the representation of topographic controls on phosphorus (P) transport by comparing results from the Vermont P-Index (VT P-Index) and a more complex process-based model, TopoSWAT, across topographic regions in a small agricultural watershed (360 ha) in the Lake Champlain Basin. Scenarios of varying P management strategies were modeled for corn silage production fields with poorly-drained soils and rolling topography. Modeled outputs of P risk assessments and edge-of-field dissolved and particulate P losses were compared. Results from this study suggest that the VT P-Index could improve its ability to support farm nutrient management planning and other P-based management decisions by incorporating topographic controls of runoff production into its estimation of P transport.

In 2019, the Mississippi River watershed had a record-long flooding, which was comparable with the 1927 Great Mississippi River Flood. This study leveraged this flooded condition to assess the flood tolerance of eastern cottonwood (Populus deltoides) and black willow (Salix nigra) planted as short rotation woody crops (SRWCs) on seasonally flooded marginal land of the Lower Mississippi Alluvial Valley (LMAV) in 2018. The survival/mortality prediction models developed by using hydrologic and environmental variables suggested that only high flood depth affected the survival of black willow. However, eastern cottonwood was threatened by flood depth, flood duration, and cumulative flooding temperature calculated by summing air temperatures while trees were flooded in 2019, 2020, and 2021. During the growing season, the models predicted that black willow could tolerate flood depth of 1.38 m in April, 1.52 m in May, and 0.74 m in June, while eastern cottonwood could tolerate 1.18 m in April, 0.86 m in May, and 0.85 m in June. Due to having higher flood tolerance thresholds, black willow had better survival and biomass production than eastern cottonwood. This study also identified critical physiological parameters that affected the biomass productivity of eastern cottonwood, black willow, and American sycamore (Platanus occidentalis). Results showed that the growth of black willow was driven by nitrogen per unit leaf area (R2 = 0.41 and P-value = 0.004) and photosynthetic nitrogen use efficiency (R2 = 0.27 and P-value = 0.03); American sycamore was determined by stomatal conductance (R2 = 0.68 and P-value = 0.04) and transpiration rate (R2 = 0.70 and P-value = 0.04); and eastern cottonwood was not affected by either water or nitrogen factors. Understanding physiological strategies of these species provides useful information when matching site-species for riparian restoration in the LMAV. This study also found that a SRWC plantation could mitigate agricultural runoff by removing 78 to 83% of nitrate-nitrogen and 70 to 73% of orthophosphate-phosphorus from the groundwater before discharge to the Yazoo River. Therefore, rather than abandoning these areas, establishing SRWC plantations for bioenergy on marginal cropland can mitigate agricultural nutrient runoff and improve the water quality of the LMAV.

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