The relationship between the general circulation of the ocean and, along-isopycnal and vertical mixing is explored. Firstly, advection down isopycnal tracer gradients is related to mixing in specific regions of the ocean. Secondly, a general inverse method is developed for estimating both mixing and the general circulation. Two examples of down gradient advection are explored. Firstly the region of Mediterranean outflow in the North Atlantic. Given a known transport of warm salty water out of the Mediterranean Sea and the mean hydrography of the eastern North Atlantic, the vertical structure of the along-isopycnal mixing coefficient, K, and the vertical mixing coefficient, D, is revealed. Secondly, the Southern Ocean Meridional Overturning Circulation, SMOC, is investigated. There, relatively warm salty water is advected southward, along-isopycnals, toward fresher cooler surface waters. The strength and structure of the SMOC is related to K and D by considering advection down along-isopycnal gradients of temperature and potential vorticity. The ratio of K to D and their magnitudes are identified. A general tool is developed for estimating the ocean circulation and mixing; the \textit{tracer-contour inverse method}. Integrating along contours of constant tracer on isopycnals, differences in a geostrophic streamfunction are related to advection and hence to mixing. This streamfunction is related in the vertical, via an analogous form of the depth integrated thermal wind equation. The tracer-contour inverse method combines aspects of the box, beta spiral and Bernoulli methods. The tracer-contour inverse method is validated against the output of a layered model and against in-situ observations from the eastern North Atlantic. The method accurately reproduces the observed mixing rates and reveals their vertical structure.

Thesis (Ph. D.)--University of Texas at Austin, 1998. / Vita. Includes bibliographical references (leaves 96-101). Available also in a digital version from Dissertation Abstracts.

In this thesis we will investigate the role of diapycnal mixing on the ocean general circulation. This thesis is divided into three main parts. In the first part we show that there exists an almost infinite number of pathways to turbulence in oceanic energetic shear zones at high Reynolds number. Such a large number of accessible routes to truly chaotic motion is not typical of most of the existing body of laboratory and numerical experiments of shear-induced diapycnal mixing, but is shown to be of relevance to diapycnal mixing in geophysical flows. A key finding is that the use of generally accepted empirical relations based on laboratory experiments for the quantification of diapycnal mixing leads to large inaccuracies. In the second part we perform high resolution numerical experiments of diapycnal mixing in the oceanographically relevant high Reynolds number parameter range. Through detailed analysis of the flow energetics and mixing properties of these flows, we show that the net buoyancy flux facilitated by turbulence, the efficiency of diapycnal mixing, and the resultant effective diffusivity, all depend in non-trivial ways on the specific route to turbulence for each individual mixing event. This has important implications for practical methods of estimating an effective diapycnal mixing diffusivity from observations as well as for parametrization of mixing in ocean general circulation models. We show quantitatively that such methods can be inaccurate to the extent that they will need to be completely revised or replaced. In the third and final part of the thesis we investigate the sensitivity of the meridional overturning circulation of the abyssal ocean to the intensity and spatial variations of diapycnal mixing. We show that changes in intensity of mixing by factors well within the errors associated with practical estimates (as discussed above) lead to significant changes in ocean circulation. We show that enhanced abyssal mixing, surface winds, and meso-scale eddies play leading roles in driving the abyssal ocean circulation and in setting the stratification. As an example of the application of our analysis we show that proper parametrization of enhanced abyssal mixing leads to realization of the important role of the (often neglected) geothermal heat flux in driving the Antarctic Bottom Water circulation.

In this thesis we will investigate the role of diapycnal mixing on the ocean general circulation. This thesis is divided into three main parts. In the first part we show that there exists an almost infinite number of pathways to turbulence in oceanic energetic shear zones at high Reynolds number. Such a large number of accessible routes to truly chaotic motion is not typical of most of the existing body of laboratory and numerical experiments of shear-induced diapycnal mixing, but is shown to be of relevance to diapycnal mixing in geophysical flows. A key finding is that the use of generally accepted empirical relations based on laboratory experiments for the quantification of diapycnal mixing leads to large inaccuracies. In the second part we perform high resolution numerical experiments of diapycnal mixing in the oceanographically relevant high Reynolds number parameter range. Through detailed analysis of the flow energetics and mixing properties of these flows, we show that the net buoyancy flux facilitated by turbulence, the efficiency of diapycnal mixing, and the resultant effective diffusivity, all depend in non-trivial ways on the specific route to turbulence for each individual mixing event. This has important implications for practical methods of estimating an effective diapycnal mixing diffusivity from observations as well as for parametrization of mixing in ocean general circulation models. We show quantitatively that such methods can be inaccurate to the extent that they will need to be completely revised or replaced. In the third and final part of the thesis we investigate the sensitivity of the meridional overturning circulation of the abyssal ocean to the intensity and spatial variations of diapycnal mixing. We show that changes in intensity of mixing by factors well within the errors associated with practical estimates (as discussed above) lead to significant changes in ocean circulation. We show that enhanced abyssal mixing, surface winds, and meso-scale eddies play leading roles in driving the abyssal ocean circulation and in setting the stratification. As an example of the application of our analysis we show that proper parametrization of enhanced abyssal mixing leads to realization of the important role of the (often neglected) geothermal heat flux in driving the Antarctic Bottom Water circulation.

Thesis (M.Sc.)--Memorial University of Newfoundland. / Restricted until October 1993. Typescript. Bibliography: leaves 142-144. Also available online.

<p>The timing of the spring phytoplankton bloom in the subpolar North Atlantic Ocean has important consequences for the marine carbon cycle and ecosystems. There are currently several proposed mechanisms to explain the timing of this bloom. The conventional theory holds that the bloom begins when the ocean warms and the seasonal mixed layer shoals in the spring, decreasing the depth to which phytoplankton are mixed and increasing the light available to the population. Recent work has attributed the beginning of the bloom to decreases in turbulence within the upper ocean, driven by the onset of positive heat fluxes or decreases in the strength of local winds. Other studies have focused on the increase in the seasonal mixed layer in the winter as a driver of changes in ecosystem interactions and a control on the spring bloom. Finally, submesoscale eddies, occurring as a result of lateral density gradients, have been proposed as a stratification mechanism that can create phytoplankton blooms prior to the onset of ocean surface warming.</p><p>This dissertation critically examines and compares the proposed theories for the initiation of the spring bloom and draws on these theories to propose a new framework: that blooms begin when the active mixing depth shoals, a process generally driven by a weakening of surface heat fluxes and consequent shift from convective mixing to wind-driven mixing. Using surface forcing data, we develop a parameterization for the active mixing depth from estimates of the largest energy-containing eddies in the upper ocean. </p><p>Using in situ records of turbulent mixing and biomass, we find that the spring phytoplankton bloom occurs after mixing shifts from being driven by convection to being driven by wind, and that biomass increases as the active mixing depth shoals. Using remote sensing data, we examine patterns of bloom initiation in the North Atlantic at the basin scale, compare current theories of bloom initiation, and find that the shoaling of the active mixing depth better predicts the onset of the bloom across the North Atlantic subpolar basin and over multiple years than do other current theories. Additionally, using a process study model, we evaluate the importance of submesoscale eddy-driven stratification as a control on the initiation of the spring bloom, determining that this mechanism has a relatively minor effect on alleviation of phytoplankton light limitation. Finally, we describe potential techniques and tools to examine whether interannual variability in the active mixing depth acts as a control on variability in the timing of the spring bloom.</p> / Dissertation

We present here a theory for the generation of mesoscale eddies, in the context of describing the generation of dipoles seen near the Queen Charlotte Islands in British Columbia. The Regional Ocean Modeling System (ROMS) is used to show dipoles forming from the coalescence of small headland eddies at Cape St. James. These headland eddies are formed by frictional generation of potential vorticity (PV) when the tide oscillates across the cape. Only 20% of the PV generated at the cape ends up in the headland eddies, with the remainder lost due to mixing of waters with PV of opposite signs. Coalescence of the headland eddies is achieved with a much higher efficiency - the PV contained in the final eddy is near 80% of the sum of that contained in the small eddies. Not all headland eddies coalesce. Coalescence of a positive PV eddy occurs only when the eddy is formed on a strong tidal flood followed by a weak ebb. Thus, a diurnal inequality in the tides is a requirement for coalescence. The eddies in the final dipole contain roughly equal amounts of PV; each has a radius of approximately 15 km and extends to nearly 100-m depth.

Turbulence is important since it affects the exchange of momentum, heat, and trace gases between the atmosphere and the ocean. However, measuring oceanic turbulence is not straightforward and that is why parameterizations that describe turbulence events are important. In this thesis turbulence data from the Baltic Sea is investigated and compared to already existing parameterizations.  The thesis considers turbulence in the ocean surface boundary layer (OSBL) and how atmospheric parameters act as driving mechanisms. Turbulence creates mixing that enables the dispersion of various particles and a more efficient gas transfer at the air-sea interface. This thesis aimed to investigate the connection between the drivers of oceanic turbulence, wind, waves, and buoyancy fluxes and how they contribute to the formation of enhanced turbulence events. To investigate this, turbulence data from the Baltic Sea from June to August 2020, collected by an ADCP (Acoustic Doppler Current Profiler), was used to find connections to meteorological data during the same time period. Since turbulence is difficult to measure, three already existing parameterizations were compared to the observed turbulence to investigate their performance. The results showed that conditions with higher wind speeds with corresponding waves gave a better correlation between surface turbulence and wind and waves. The parameterization that included wind and waves gave results closest to the observed turbulence at the surfaces, compared to when only wind shear was included. It was also detected that the parameterized turbulence was in almost all cases under-predicted in comparison to the observed turbulence. To clarify why this is the case, a more detailed analysis would be needed to find what parameters are missing for better predictions of the surface turbulence.

This thesis explores the use of U-Th series isotopes as tracers to study ocean mixing and chemical inputs to the open ocean from atmospheric dust, rivers, continental shelves and ocean sediments. The use of Th isotopes as an improved tracer of dust input has been tested by measuring ²³²Th and ²³⁰Th concentrations of upper-ocean seawater at six stations along a meridional Atlantic section that spans the Saharan dust plume. The results of ²³²Th-derived dust fluxes show good agreements with dust model depositions, and suggest that thorium may be a more accurate tracer of dust input than Aluminium, which is frequently used for this purpose. A new technique has been developed for the precise measurement of ²²⁸Ra/²²⁶Ra ratios and ²²⁸Ra and ²²⁶Ra concentrations in seawater by multi-collector ICP mass spectrometry (MC-ICP-MS). This methods offers improved analytical precision and detection limits relative to previous decay-counting approaches, though is more labour intensive. The accuracy of this method has been proved in the GEOTRACES Ra intercalibration, and shows consistent results with decay counting measurements from other labs. This technique has been applied to water samples in Loch Etive, a Scottish fjord, and in the Cape Basin during the UK-GEOTRACES cruise (GA10E) to investigate ocean mixing and trace-metal fluxes in the oceans. In Loch Etive, Ra data provide an estimation of sedimentary ²²⁸Ra flux of 5.5 ± 0.3 (× 10⁹ atoms m^-2 yr^-1) in the inner loch deep basin. Short-lived Ra isotope (²²³Raex) has also been used to estimate surface water transport rate, which is ~ 2.4 ±0.2 cm s^-1 from the mouth to the head of the loch. In the Cape Basin, seawater ²²⁸Ra and ²²⁶Ra activities have been used to estimate vertical and horizontal mixing in the surface ocean. The horizontal mixing (K_x) from the continental shelf to the open ocean is 3.8 ± 0.8 (× 10⁷ cm² s^-1) and the vertical mixing (K_z) in the upper 400 m layer is 0.9 – 2.1 cm² s^-1. These mixing rates enable the calculation of nutrient flux in the surface ocean. The calculated vertical nitrate fluxes in the Cape Basin are 0.4 – 0.5 mmol N m^-2 d^-1. This finding shed light on the nutrient inputs to the South Atlantic Subtropical Gyre.

L'Eau Antarctique de Fond constitue la principale masse d'eau océanique par son volume, et nourrit la composante la plus profonde et la plus lente de la circulation océanique. Les processus qui régissent son cycle de vie sont donc clé pour la capacité de stockage de l'océan en carbone et chaleur aux échelles centennales à multi-millénaires. Cette thèse tente de caractériser et quantifier les principaux processus responsables de la destruction (synonyme d'allègement et de remontée) de l'Eau Antarctique de Fond dans l'océan abyssal. A partir d'une estimée issue d'observations de la structure thermohaline de l'océan mondial et de diagnostics fondés sur le budget de densité des eaux profondes, les rôles respectifs du chauffage géothermal, du mélange turbulent par déferlement d'ondes internes et de la géométrie des bassins sont évalués. Il est montré que la géométrie de l'océan gouverne la structure de la circulation de l'Eau Antarctique de Fond. La contribution du déferlement des ondes internes, bien que mal contrainte, est estimée insuffisante pour maintenir un rythme de destruction de l'Eau Antarctique de Fond comparable à celui de sa formation. Le chauffage géothermal a quant à lui un rôle important pour la remontée des eaux recouvrant une large surface du lit océanique. Les résultats suggèrent une réévaluation de l'importance du mélange au niveau des détroits et seuils profonds, mais aussi du rôle fondamental de la forme des bassins, pour l'allègement et le transport des eaux abyssales. / Antarctic Bottom Water is the most voluminous water mass of the World Ocean, and it feeds the deepest and slowest component of ocean circulation. The processes that govern its lifecycle are therefore key to the ocean's carbon and heat storage capacity on centennial to multi-millennial timescales. This thesis aims at characterizing and quantifying processes responsible for the destruction (synonymous of lightening and upwelling) of Antarctic Bottom Water in the abyssal ocean. Using an observational estimate of the global ocean thermohaline structure and diagnostics based on the density budget of deep waters, we explore the roles of basin geometry, geothermal heating and mixing by breaking internal waves for the abyssal circulation. We show that the shape of ocean basins largely controls the structure of abyssal upwelling. The contribution of mixing powered by breaking internal waves, though poorly constrained, is estimated to be insufficient to destroy Antarctic Bottom Water at a rate comparable to that of its formation. Geothermal heating plays an important role for the upwelling of waters covering large seafloor areas. The results suggest a reappraisal of the role of mixing in deep straits and sills, but also of the fundamental role of basin geometry, for the lightening and transport of abyssal waters.