Thesis (Ph. D.)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2007. / Includes bibliographical references (p. 153-166). / The role of ocean dynamics in driving air-sea interaction is examined at two contrasting sites on 125°W in the eastern tropical Pacific Ocean using data from the Pan American Climate Study (PACS) field program. Analysis based on the PACS data set and satellite observations of sea surface temperature (SST) reveals marked differences in the role of ocean dynamics in modulating SST. At a near-equatorial site (3°S), the 1997-1998 El Nifio event dominated the evolution of SST and surface heat fluxes, and it is found that wind-driven southward Ekman transport was important in the local transition from El Nifio to La Nifia conditions. At a 10'N site near the summertime position of the Inter-tropical Convergence Zone, oceanic niesoscale motions played an important role in modulating SST at intraseasonal (50- to 100-day) timescales, and the buoy observations suggest that there are variations in surface solar radiation coupled to these mesoscale SST variations. This suggests that the mesoscale oceanic variability may influence the occurrence of clouds. The intraseasonal variability in currents, sea surface height, and SST at the northern site is examined within the broader spatial and temporal context afforded by satellite data. / (cont.) The oscillations have zonal wavelengths of 550-1650 km and propagate westward in a manner consistent with the dispersion relation for first baroclinic mode, free Rossby waves in the presenice of a, mean westward flow. The hypothesis that the intraseasonal variability and its annual cycle are associated with baroclinic instability of the North Equatorial Current is supported by a spatio-temporal correlation between the amplitude of intraseasonal variability and the occurrence of westward zonal flows meeting an approximate necessary condition for baroclinic instability. Focusing on 100N in the eastern tropical Pacific, the hypothesis that mesoscale oceanic SST variability can systematically influence cloud properties is investigated using several satellite data products. A statistically significant relationship between SST and columnar cloud liquid water (CLW), cloud reflectivity, and surface solar radiation is identified within the wavenumber-frequency band corresponding to oceanic Rossby waves. Analysis of seven years of CLW data and 20 years surface solar radiation data indicates that 10-20% of the variance of these cloud-related properties at intraseasonal periods and wavelengths on the order of 100 longitude can be ascribed to SST signals driven by oceanic Rossby waves. / by J. Thomas Farrar. / Ph.D.

Thesis (S.M.)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Mechanical Engineering; and the Woods Hole Oceanographic Institution), 2009. / Cataloged from PDF version of thesis. / Includes bibliographical references (p. 140-141). / A confluence of several coastal oceanographic features creates an acoustically interesting region with high variability along the New England Shelfbreak. Determining the effect of the variability on acoustic propagation is critical for sonar systems. In the Nantucket Shoals area of the Middle Atlantic Bight, two experiments, the New England Shelfbreak Tests (NEST), were conducted in May and June, 2007 and 2008, to study this variability. A comprehensive climatology of the region along with the experimental data provided detailed information about the variability of the water column, particularly the temperature and sound speed fields. Empirical orthogonal function (EOF) analysis of the ocean sound speed field defined a set of perturbations to the background sound speed field for each of the NEST Scanfish surveys. Attenuation due to bottom sediments is the major contributor of transmission loss in the ocean. In shallow water, available propagation paths most often include bottom interaction. Perturbations in the ocean sound speed field can cause changes in the angle of incidence of sound rays with the bottom, which can result in changes to the amount of sound energy lost to the bottom. In lieu of complex transmission loss models, the loss/bounce model provides a simpler way to predict transmission loss changes due to perturbations in the background sound speed field in the ocean. Using an acoustic wavenumber perturbation method, sound speed perturbations, defined by the ocean EOF modes, are translated into a change in the horizontal wavenumber, which in turn changes the modal angle of incidence. / (cont.) The loss/bounce model calculates the loss of sound energy (dB) per bottom bounce over a given distance based on the change in angle of incidence. Evaluated using experimental data from NEST, the loss/bounce model provided accurate predictions of changes to transmission loss due to perturbations of the background sound speed field. / by Heather René Hornick. / S.M.

Thesis (Ph. D.)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2008. / Includes bibliographical references (p. 110-119). / This study presents observations of turbulence dynamics made during the low winds portion of the Coupled Boundary Layers and Air-Sea Transfer experiment (CBLAST-Low). Observations were made of turbulent fluxes, turbulent kinetic energy, and the length scales of flux-carrying and energy-containing eddies in the ocean surface boundary layer. A new technique was developed to separate wave and turbulent motions spectrally, using ideas for turbulence spectra that were developed in the study of the bottom boundary layer of the atmosphere. The observations of turbulent fluxes allowed the closing of heat and momentum budgets across the air-sea interface. The observations also show that flux-carrying eddies are similar in size to those expected in rigid-boundary turbulence, but that energy-containing eddies are smaller than those in rigid-boundary turbulence. This suggests that the relationship between turbulent kinetic energy, depth, and turbulent diffusivity are different in the ocean surface boundary layer than in rigid-boundary turbulence. The observations confirm previous speculation that surface wave breaking provides a surface source of turbulent kinetic energy that is transported to depth where it dissipates. A model that includes the effects of shear production, wave breaking and dissipation is able to reproduce the enhancement of turbulent kinetic energy near the wavy ocean surface. However, because of the different length scale relations in the ocean surface boundary layer, the empirical constants in the energy model are different from the values that are used to model rigid-boundary turbulence. The ocean surface boundary layer is observed to have small but finite temperature gradients that are related to the boundary fluxes of heat and momentum, as assumed by closure models. However, the turbulent diffusivity of heat in the surface boundary layer is larger than predicted by rigid-boundary closure models. Including the combined effects of wave breaking, stress, and buoyancy forcing allows a closure model to predict the turbulent diffusivity for heat in the ocean surface boundary layer. / by Gregory Peter Gerbi. / Ph.D.

Thesis (S.M.)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Mechanical Engineering; and the Woods Hole Oceanographic Institution), 2009. / Includes bibliographical references (p. 88-91). / The work presented in this thesis addresses the problem of the detection, classification and localization of seabed objects in shallow water environments using a time reversal approach in a bistatic configuration. The waveguide is insonified at low frequency ('kHz) with an omnidirectional source and the resulting scattered field is sampled by a receiving array towed behind an Autonomous Underwater Vehicle (AUV). The recorded signals are then processed to simulate onboard the AUV, the time reversed transmissions which serve to localize the origin of the scattered field on the seabed and estimate the position of the targets present. The clutter rejection based upon the analysis of the singular values of the Time Reversal operator is investigated with simulated data and field measurements collected off the coast of Palmaria (Italy) in January 2008. / by Alexis J. Dumortier. / S.M.

Thesis: Ph. D., Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Department of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2018. / Cataloged from PDF version of thesis. / Includes bibliographical references. / This thesis examines abiotic processes controlling the transformation and distribution of carbon compounds in seafloor hydrothermal systems hosted in ultramafic rock. These processes have a direct impact on carbon budgets in the oceanic lithosphere and on the sustenance of microorganisms inhabiting hydrothermal vent ecosystems. Where mantle peridotite interacts with carbon-bearing aqueous fluids in the subseafloor, dissolved inorganic carbon can precipitate as carbonate minerals or undergo reduction by H2(aq) to form reduced carbon species. In Chapters 2 and 3, I conduct laboratory experiments to assess the relative extents of carbonate formation and CO2 reduction during alteration of peridotite by C02(aq)-rich fluids. Results from these experiments reveal that formation of carbonate minerals is favorable on laboratory timescales, even at high H2(aq) concentrations generated by serpentinization reactions. Although CO2(aq) attains rapid metastable equilibrium with formate, formation of thermodynamically stable CH4(aq) is kinetically limited on timescales relevant for active fluid circulation in the subseafloor. It has been proposed that CH4 and potentially longer-chain hydrocarbons may be sourced, instead, from fluid inclusions hosted in plutonic and mantle rocks. Chapter 4 analyzes CH4-rich fluid inclusions in olivine-rich basement rocks from the Von Damm hydrothermal field and the Zambales ophiolite to better understand the origin of abiotic hydrocarbons in ultramaficinfluenced hydrothermal systems. Comparisons of hydrocarbon abundances and stable isotopic compositions in fluid inclusions and associated vent fluids suggest that fluid inclusions may provide a significant contribution of abiotic hydrocarbons to both submarine and continental serpentinization systems. / by Niya Gueorguieva Grozeva. / Ph. D.

Thesis (S.M.)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Mechanical Engineering; and the Woods Hole Oceanographic Institution), 2006. / This electronic version was submitted by the student author. The certified thesis is available in the Institute Archives and Special Collections. / Includes bibliographical references (p. 89-96). / Blainville's beaked whales (Mesoplodon densirostris) use broadband, ultrasonic echolocation signals (27 to 57 kHz) to search for, localize, and approach prey that generally consist of mid-water and deep-water fishes and squid. Although it is well known that the spectral characteristics of broadband echoes from marine organisms are a strong function of size, shape, orientation and anatomical group, little is known as to whether or not these or other toothed whales use spectral cues in discriminating between prey and non-prey. In order to study the prey-classification process, a stereo acoustic tag was mounted on a Blainville's beaked whale so that emitted clicks and corresponding echoes from prey could be recorded. A comparison of echoes from prey selected by the whale and those from randomly chosen scatterers suggests that the whale may have, indeed, discriminated between echoes using spectral features and target strengths. Specifically, the whale appears to have favored prey with one or more deep nulls in the echo spectra as well as ones with higher target strength. A three-dimensional, acoustic scattering model is also developed to simulate broadband scattering from squid, a likely prey of the beaked whale. / (cont.) This model applies the distorted wave Born approximation (DWBA) to a weakly-scattering, inhomogeneous body using a combined ray trace and volume integration approach. Scatterer features are represented with volume elements that are small (less than 1=12th of the wavelength) for the frequency range of interest (0 to 120 kHz). Ranges of validity with respect to material properties and numerical considerations are explored using benchmark computations with simpler geometries such as fluid-filled spherical and cylindrical fluid shells. Modeling predictions are compared with published data from live, freely swimming squid. These results, as well as previously published studies, are used in the analysis of the echo spectra of the whale's ensonified targets. / by Benjamin A. Jones. / S.M.

Thesis (Ph. D.)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Biology; and the Woods Hole Oceanographic Institution), 2008. / This electronic version was submitted by the student author. The certified thesis is available in the Institute Archives and Special Collections. / Includes bibliographical references. / Ecological processes at deep-sea hydrothermal vents on fast-spreading mid-ocean ridges are punctuated by frequent physical disturbance. Larval dispersal among disjunct vent sites facilitates the persistence of sessile invertebrate species in these geologically and chemically dynamic habitats despite local extinction events. Regional population extension and rapid recolonization by the siboglinid tubeworm Riftia pachyptila have been well documented along the East Pacific Rise and the Galápagos Rift. To analyze spatial and temporal population genetic patterns and the processes governing them at ephemeral and disjunct habitats, a suite of 12 highly variable microsatellite DNA markers were developed for this species. Eight of these loci were used to assess the regional and within-ridge genetic structure of recent colonists and resident adults collected from nine sites in the eastern Pacific Ocean over period of three to seven years. A significant seafloor eruption during the seven-year sampling period allowed investigation into the role of local extinction in population genetic diversity at the Tica vent site at 9°N EPR, while collections within two and five years of an eruption that created the Rosebud vent field at 86°W GAR provided insights into genetic diversity input over population establishment. For the first time, this thesis demonstrated significant genetic differences between Riftia populations on the East Pacific Rise and Galápagos Rift. Moreover, the separate treatment of colonist and resident subpopulations revealed a high potential for local larval retention at vent sites. This mechanism for recruitment likely sustains disjunct populations and supports the recolonization of locally extinct areas after disturbance events, while episodic long-distance dispersal maintains genetic coherence of the species. / (cont.) Temporal population genetic consideration at the Tica site on the East Pacific Rise suggests that the 2005-2006 seafloor eruption had little to no discernable effect on local population genetic composition. Yet local populations appear to exhibit a small degree of genetic patchiness, with a high degree of relatedness (half-sibs) among subsets of individuals within both colonist and resident cohorts. This thesis broadens the application of recently developed molecular techniques to study the effect of ridge-crest processes and offers new perspectives into marine dispersal, gene flow, and population differentiation. / by Abigail Jean Fusaro. / Ph.D.

Thesis (Ph. D.)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2013. / Cataloged from PDF version of thesis. / Includes bibliographical references. / Pb and Pb isotopes in the ocean have varied on decadal to centennial time scales due to anthropogenic Pb inputs. Thus, tracing the temporal variation of Pb and Pb isotopes in the ocean provides information on the major sources of Pb and the transport of Pb from sources to the ocean surface and into the ocean interior. In this thesis study, first, a method was developed for the analysis of dissolved Pb and other trace elements in seawater using single batch nitrilotriacetate resin extraction and isotope dilution ICP-MS, which was applied in analyzing seawater Pb concentrations in the rest of the study. A -550 year history of the Pb and Pb isotopes in the deep North Atlantic Ocean is reconstructed using a deep-sea coral, showing the infiltration of anthropogenic Pb to deep sea. Comparing the results to the surface North Atlantic Ocean Pb record using a Transit Time Distribution model, the mean transit time of Pb is estimated to be -64 years. This is longer than the transit time estimate assuming simple advection from a source, showing the importance of advective-diffusive mixing in the transport of Pb to the ocean interior. The later part of the thesis investigates Pb in the Indian Ocean, where no useful Pb data have been previously reported. First, using annually-banded surface growing corals, I reconstruct variations of Pb and isotopes in the surface waters of the central and eastern Indian Oceans during the past half-century. Results of the study show the increase of Pb concentrations from the mid-1970s, and major sources of the Pb are discussed, including leaded gasoline and coal burning, based on their emission histories and Pb isotope signatures. Second, Pb concentration and isotope profiles are presented from the northern and western Indian Oceans. Higher Pb concentrations and lower Pb isotope ratios (206Pb/ 207Pb, 208Pb/207Pb) are found in the upper water column (<I 500m) as a result of anthropogenic Pb inputs, and their distributions are largely controlled by the water circulation in the Indian Ocean. / by Jong-Mi Lee. / Ph.D.

Thesis: Ph. D., Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Department of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2016. / Cataloged from PDF version of thesis. Page 156/Figure B-1 contains text that runs off the edge of the page margin. / Includes bibliographical references. / Paleoclimate archives place the short instrumental record of climate variability in a longer temporal context and allow better understanding of the rate, nature and extent by which anthropogenic warming will impact natural and human systems. The ocean is a key component of the climate system and records of past ocean variability are thus essential for characterizing natural variability and quantifying climate sensitivity to radiative forcing. Coral skeletons are high-resolution archives of tropical sea surface temperatures (SSTs), but inconsistencies call the accuracy of existing coral proxy records into question. In this thesis, I first quantify the errors associated with the traditional coral thermometer, Sr/Ca, by comparing in situ logged SST with Sr/Ca-derived SST in four corals on the same reef. I show that intercolony disparities in mean Sr/Ca, amplitude of variability, and trend are not due to differences in water temperature, but rather to "vital effects" that result in a ±2° C uncertainty on reconstructed SST. I then expand, refine, and test a new paleothermometer, Sr-U, across multiple coral species and through time. I show that Sr-U captures spatial SST variability with an uncertainty of ±0.6° C. When applied to two corals outside of the calibration, Sr-U accurately captures the mean SST and the 20th century trend in the Western Tropical Atlantic. Finally, I apply Sr-U to a coral from the Little Ice Age (LIA) to address uncertainties in the magnitude of western tropical Atlantic cooling during a 95-year period spanning 1465-1560. Results suggest the region was 1.1° C±0.6°C cooler than the 1958-1988 mean, but within error of early 20th century SST at this site. Critically, several periods of warmth, equivalent to the 1958-1988 mean, occurred during a solar minimum that is widely believed to have been a cool period of the LIA. My results indicate that Sr/Ca exaggerates the actual cooling by almost 3° C. My record demonstrates the value of Sr-U and highlights the need for continuous accurate SST records to better constrain the amplitude, drivers, and mechanisms of LIA tropical climate change. / by Alice Elizabeth Alpert. / Ph. D.

Thesis (S.M.)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Mechanical Engineering; and the Woods Hole Oceanographic Institution), 2008. / Includes bibliographical references (p. 54-56). / Landmines and mine-like traps are effective weapons that are difficult to detect and discriminate from a safe distance. The ability to detect landmines in their host environment at a distance and to discriminate them from other objects would be valuable for countering the landmine threat. This paper explores a standoff acoustic/laser technique to discriminate landmines from other forms of man-made objects (clutter) in an urban environment. A novel approach currently under investigation by MIT Lincoln Labs, University of Mississippi, and other groups employs a non-contact acoustic/laser technique to detect landmines from a safe standoff range. This technique uses a sound source to excite vibrations in targets with an acoustic wave. These vibrations are in turn measured remotely with a Laser Doppler Vibrometer (LDV). In this thesis, the vibration responses of landmine variants are measured, analyzed, and compared to those of common urban objects likely to be found on a landmine field or roadside. The Fourier Transform of the vibration of the target as measured by the LDV is used to generate a target vibration spectrum. Target vibration spectra in response to a sound source were experimentally measured for 59 trials, 28 of which were of simulated landmine variants and the remaining trials were of urban clutter objects. Using an algorithm adapted from a methodology for mass spectral analysis, parameters of the target signatures are estimated; then individual target signatures are classified using a Support Vector Machine (SVM) with a training set composed of parameters from the remaining members of the total population. The best results obtained from this methodology had a 71% probability of detection and a 3% false alarm rate corresponding to 20 of 28 of the simulated landmine variants correctly identified and a single clutter object misidentified as a landmine variant. / by John Houston Doherty. / S.M.