The principal aims of this thesis were to examine whether there were hydraulic links between individual on-site wastewater systems in sandy soils at Salt Ash and the Tilgerry Creek estuary near Port Stephens, New South Wales, and whether the chemical and microbiological contaminants from on-site systems could reach surface and groundwaters, and possibly lead to impacts on estuarine oyster growing waters. The research outcomes are contained within the thesis and in four refereed papers presented at conferences, and which have been subsequently published, or are in press. Copies of each of these papers are contained within the thesis Appendices. The presence of faecal contamination from domestic systems in the estuary, and surface drains in particular, has been confirmed by work contained in this thesis. The potential level of risk to human health from the consumption of contaminated oysters is, however, regarded as very low, although an assessment of health risk using established microbial assessment models has not been undertaken / Doctor of Philosophy (PhD)

Residential on-site wastewater systems (OWS) are a potential source of phosphorus (P) which can negatively impact surface water quality in rural watersheds. The magnitude of P loading from OWS is typically not monitored, and is further complicated when agricultural land-uses are intermixed with residential dwellings. Watershed-scale computer simulations are commonly used tools for evaluating the impacts of land-use changes on P loading. Existing models simulate OWS P treatment via vertical flow transport in native soils. However, in Nova Scotia (NS) OWS designs rely pre-dominantly on lateral flow and imported sand filter media. In this thesis, a watershed-scale computer modeling framework for simulating P loads from agriculture and lateral flow OWS designs was developed and tested. The framework consists of the P on-site wastewater simulator (POWSIM), designed specifically for this study, which is used in conjunction with the Soil and Water Assessment Tool (SWAT) model. The POWSIM loading tool has three computational components: (i) OWS disposal field design type selection and treatment media mass calculation; (ii) disposal field P treatment dynamics; and (iii) soil subsurface plume P treatment dynamics. The active P treatment media mass and dynamics equations were developed from numerical modeling (HYDRUS-2D) and lateral flow sand filter (LFSF) OWS disposal field experiments. A 2-part piecewise linear model was found to best represent LFSF P treatment processes. Testing of the modeling framework in the mixed land-use Thomas Brook Watershed (TBW) in NS demonstrated improved simulation of baseflow total P (TP) loads in both a predominantly residential subcatchment and one dominated by agriculture over the SWAT model without POWSIM. Different residential and agricultural development and beneficial management practice (BMP) scenarios were evaluated in the TBW. Agricultural BMPs were most effective at reducing cumulative TP loads while OWS BMPs were best at mitigating in-stream eutrophication impacts. The 50 year simulation period for the various scenarios found peak OWS TP loading occurring between 25 and 50 years, suggesting that modeling for many decades is required for proper evaluation. This study highlights the importance in identifying specific water quality issues that need to be targeted prior to implementing a BMP strategy.