This project expands on the 4200-year history of Laguna Los Mangos by adding diatom analysis to existing records of pollen, charcoal, elemental composition, and stable light isotope analysis. Diatoms were counted in peroxide-treated samples, and data were analyzed using cluster analysis, PCA, CCA, and Pearson correlation. Diatom variability was correlated with nitrogen and organic material. Before 3430 cal yr BP, diatoms reflect landscape instability with higher lake levels and macrophyte cover. This period was followed by a period of agriculture-induced nutrient pollution, reduced pH, and increased precipitation until about 2450 cal yr BP. Peaks in A. granulata may indicate periods of increased mixing driven by precipitation. Diatom composition reflects reduced agricultural activity and lake desiccation during the TCD and increased precipitation and agricultural collapse during the LIA. Overall, this record reflects a history of slightly alkaline, eutrophic conditions, increasing salinity, and human disturbance from maize agriculture and deforestation. / Includes bibliography. / Thesis (M.S.)--Florida Atlantic University, 2021. / FAU Electronic Theses and Dissertations Collection

No description available.

Thesis (Ph. D.)--University of Texas at Austin, 2006. / Vita. Includes bibliographical references.

Thesis (Ph. D.)--University of Oregon, 2006. / Typescript. Includes vita and abstract. Includes appendices with Foy Lake pollen and charcoal data and fire atlas metadata. Includes bibliographical references (leaves 233-244). Also available for download via the World Wide Web; free to University of Oregon users.

Open grassy environments in Africa have been key landscapes for the development and evolution of humans and our hominid ancestors for millions of years. These environments have not been static, however, as global climate changes have strongly shaped their nature and location over time. In the modern, at least 80 million people living in Sub-Saharan Africa rely on agriculture and pastoralism within the grasslands and savannas of the Sahel region alone for food security. Devastating droughts and associated famine in the region over the past several decades have highlighted this region’s potential vulnerability to future climate change. Wildfires play a unique and critical role in maintaining Africa’s grasslands and savannas, especially in the Sahel region. Emissions from these fires have additional ramifications for the Earth’s radiative balance and global cycles of carbon and nutrients. As populations in Africa rise over the coming century from ~1.3 billion to 4 billion people by 2100, increasing demand for food, rising temperatures, and highly uncertain changes in rainfall and wildfire patterns are poised to put the people and ecosystems of this region in jeopardy. In the face of potentially novel environmental conditions resulting from anthropogenic climate change, this research aims to better understand the long-term interconnections of climate, ecology, and human presence in Northwest Africa and how these linkages may vary under broad shifts in climate. Accurate projections of future climate and ecosystem change not only require the mechanistic understanding of climate forcings and climate-ecosystem interactions that can be gleaned from modern relationships, but also information about how these interactions may vary as a function of changes in the background climate state itself (on centennial to million year timescales). Highly spatially-resolved satellite measurements relevant for asking such questions only extend back a few decades and thus only provide a limited perspective on whether or not modern climate-ecosystem interactions are stationary through time. This thesis is focused on developing and applying paleoclimate reconstruction techniques to generate new records of hydroclimate, ecosystem structure, and fire activity in Northwest Africa over a broad set of time scales. These new records are used to assess the governing controls of climate variability and evaluate the evolution of climate-ecosystem interactions across a diversity of background climate states. We seek specifically to (1) improve our understanding of the natural climate forcings that dictate changes in Northwest African monsoon rainfall, (2) evaluate how changes in rainfall and other climate parameters––namely atmospheric CO₂ concentrations––together affect ecosystem distributions and compositions in Northwest Africa, (3) ground-truth the use of increasingly popular molecular proxies of fires applied to marine sediment archives, (4) assess the relative environmental and human controls on fires in Northwest African savannas over time, and (5) develop interpretive frameworks for understanding multiproxy records of environmental changes in Northwest Africa to draw conclusions about how climate-ecosystem interactions may have evolved over time. To address these goals, this dissertation is broken down into four chapters. The first two chapters focus on the orbital-scale to multimillion year forcings in the climate system that control the strength and tempo of the Northwest African monsoon and how these changes impact the distributions and compositions of ecosystems in the region over time. In both Chapters 1 and 2, we develop new reconstructions of hydroclimate using the hydrogen isotopic composition of plant-waxes and extraterrestrial 3He normalized dust fluxes from marine sediment core MD03-2705 taken off the coast of Mauritania along the Northwest African margin. We further reconstruct ecosystem change using the carbon isotopic composition of plant-waxes. Chapter 1 is centered on the late-Pleistocene while Chapter 2 takes a wider perspective and explores long-term trends in Northwest African hydroclimate and vegetation structure from the Pliocene to the late-Pleistocene. In the second half of this work, the focus is narrowed to center the role of fire in Northwest African savannas and how the nature of burning in this region has changed since the last glacial maximum. In Chapter 3, we use atmospheric back trajectory modeling and a transect of marine core sediments taken aboard the research vessels Vema and Conrad that spans the southern European to southern west African margin to test if molecular biomarkers of vegetation (plant-wax n-alkanes and pentacyclic triterpene methyl ethers) and fires (pyrosugars and polycyclic aromatic hydrocarbons) preserved in marine sediment archives capture modern distributions of ecosystems and biomass burning on the landscape. In Chapter 4, we generate new records of the fire history of Northwest Africa from the last glacial maximum to the late-Holocene from marine sediment core OCE 437-7 GC68. We compare the relative influences of changes in rainfall, ecosystem structure and human activities on fire across the most recent deglaciation and ‘Green Sahara’ period. From these new records, we are able to draw several conclusions. In Chapter 1 we find that the location, timing, and intensity of northwest African monsoon rainfall is controlled by low-latitude insolation gradients and that while increases in precipitation are associated with the expansion of grasslands into desert landscapes, changes in pCO2 predominantly drive the C3/C4 composition of savanna ecosystems. In Chapter 2 we observe that low latitude insolation gradients best explain both the tempo and amplitude of orbital scale variations in Northwest African rainfall over the last five million years, however strengthening sea surface temperature gradients in the Atlantic Ocean during the mid-Pleistocene likely led to a precipitous and sustained decline in monsoon strength ~900 thousand years ago independent of any change to orbital insolation forcing. Furthermore, changes in the relationship between rainfall and vegetation in Northwest Africa can be used to track changes in the northward extent of ecosystems, augmenting previous pollen-based reconstructions, which together show shifts in ecosystem distributions over the Plio-Pleistocene likely related to changes in ecosystem disturbances and climate-vegetation interactions. In Chapter 3 we show that by accounting for the effects of long-range transport of biomarkers, good agreement is found between ecosystem composition and biomass burning patterns on the African continent and the distribution of terrestrial plant and fire biomarkers in marine core top sediments. This provides strong justification for applying molecular indicators of fires to the paleorecord. In Chapter 4, we show that rainfall is the dominant natural control on the amount of biomass burned in Northwest African savannas, but increased human presence and land-use change during the mid- to late-Holocene likely fundamentally changed the fire regime of Northwest Africa to this day.

Large discrepancies remain regarding the timing of Cenozoic paleoclimatic and paleoenvironmental transitions in the central Asia. The first order driving force behind these changes has been intensively debated. Global climate change, the uplift of Tibetan Plateau, and the evolution of Paratethys sea have been proposed as three major candidates. To understand the evolutionary history of climate and environment of the region and controlling factors responsible for these paleoclimatic and paleoenvironmental changes, a combined study utilizing multiple proxies, including microfossils, bulk carbonate carbon and oxygen isotopes, long chain alkenones, plant n-alkane-based indices (carbon preference index, average chain length and Paq) and compound-specific carbon and hydrogen isotopes of higher plant n-alkanes, was carried out on a long, continuous and well-dated section in Dahonggou, Qaidam Basin, northern Tibetan Plateau. A parallel study was also carried out in another relatively shorter section in the Xunhua Basin, northern Tibetan Plateau. Six intervals of paleoclimatic and paleoenvironmental transitions over an interval of ~35 Myr can be recognized in the studied sections, including Late Eocene-Early Oligocene gradual drying (prior to ~30 Ma), Middle Oligocene aridification (~30-26 Ma), Late Oligocene-Early Miocene wetting (~26-21 Ma), Early Miocene drying (~21-17 Ma), Middle Miocene climatic optimum (~17-13 Ma), and deteriorated climate since the late Middle Miocene (~13 Ma onwards). The reconstructed onsite C4 plant abundance including occurrence of C4 plants and their thriving and the followed decreasing, a sensitive indicator of available moisture level in the environment, agrees well with these intervals. Microfossils and long-chain alkenones suggest that a relic sea existed in the Qaidam Basin during the Middle Miocene, thus falsifying any hypothesis of significant variations in elevations of northern Tibetan Plateau prior to the Middle Miocene. The relatively stable elevations since the Eocene and before the Middle Miocene of, respectively, the central-southern part and northern part of the Plateau reveals an insignificant role of Tibetan Plateau uplift in controlling the evolution of central Asian climate and environment during the early Cenozoic. However, the Middle Miocene marine transgression and the rapid plateau-scale uplift since the late Middle Miocene probably contributed to the Middle Miocene climatic optimum and the initiated aridification afterwards in the central Asia. A comparison of proxy records in the northern Tibetan Plateau with the global benthic oxygen isotope record suggests a tight relation between the climatic/environmental transitions in the central Asia and global climatic changes. This lends support to the hypothesis that global climate, by controlling the moisture supply to the continental interior, played the dominant role in the evolution of climate and environment of central Asia during the Cenozoic time. / published_or_final_version / Earth Sciences / Doctoral / Doctor of Philosophy

Tree-ring records from long-lived trees are instrumental for understanding climate variability during the Common Era. Some of the oldest and most valuable conifers used to reconstruct past climate exhibit strip-bark morphology, in which vertical segments of the tree have died in response to environmental stress. This form of localized stem mortality, also referred to as partial cambial dieback, is particularly common on conifers growing in xeric, cold, or exposed environments. Some studies note that strip-bark trees have increasing ring-width trends relative to trees with a fully living stem circumference, but there is substantial uncertainty as to what extent partial cambial dieback can influence tree-ring records and subsequent climate reconstructions. This dissertation explores the environmental drivers of partial cambial dieback on Siberian pine (Pinus sibirica Du Tour) from Mongolia, the effect of cambial dieback on the radial growth and physiology of affected trees, and methods for reducing strip-bark biases in tree-ring records. Chapter 1 assesses the causes and radial growth impacts of partial cambial dieback on Siberian pine trees growing on an ancient lava flow in central Mongolia. Using a combination of field observations and dendrochronological methods, this chapter demonstrates that strip-bark trees from this site exhibit dieback primarily on the southern side of stems, and that dieback was most common during a cold and dry period in the mid-19th century. Given the directionality and timing of dieback on these strip-bark trees, it is hypothesized that localized mortality events are linked to physiological injuries spurred from solar heating combined with unfavorable climatic conditions. This chapter also reveals that strip-bark trees from this site have increasing radial growth trends relative to trees with a full circular morphology (“whole-bark” trees). Strip-bark trees showed an especially rapid increase in ring widths following the cambial dieback period in the mid-19th century, providing initial evidence that dieback events can lead to increasing ring widths in strip-bark Siberian pine. Chapter 2 seeks to discern the physiological mechanisms of increasing radial growth trends in the Siberian pine strip-bark trees using stable carbon and oxygen isotopes from tree rings. One simple hypothesis is that strip-bark trees show increasing ring-width trends because radial growth is restricted to a smaller stem area after cambial dieback events. Conversely, some studies have hypothesized that increasing ring widths in strip-bark trees reflect a CO2 fertilization effect on growth that is not readily apparent in whole-bark trees. This chapter finds that strip-bark and whole-bark trees responded similarly to increasing atmospheric CO2 and climate variability in their radial growth and leaf-level gas exchange inferred from tree-ring stable isotopes. However, strip-bark and whole-bark trees showed notably different behavior following documented cambial dieback events. After dieback events, strip-bark trees exhibited an increase in ring widths and an enrichment in stable carbon and oxygen isotopes that was not apparent in whole-bark trees. These results further support the notion that partial cambial dieback leads directly to increasing ring widths in strip-bark trees, and that this response could reflect an increase in the ratio of leaf to live stem area after dieback occurs. Chapters 1 and 2 demonstrate that partial cambial dieback events and morphological changes impact the radial growth and physiology of strip-bark trees. Therefore, prior to developing climate reconstructions, it is necessary to remove variance associated with these non-climatic, morphological changes in tree-ring series. Chapter 3 outlines two chronology development methods for reducing strip-bark biases in tree-ring records. These methods, applied to Siberian pine and Great Basin bristlecone pine (Pinus longaeva Bailey), successfully reduce a strip-bark bias without removing low-to-medium frequency climate variance inferred from whole-bark trees, which were not impacted by dieback activity. While one approach directly corrects the bias in strip-bark series using a whole-bark chronology as a target, another method is based on the development of a low-percentile chronology, which can be applied to a site collection where the stem morphology of individual trees is unknown. Some limitations and caveats of these methods are discussed in context of the analyzed tree species. The findings from this dissertation have significantly contributed to our understanding of the radial growth and physiological responses of Siberian pine to partial cambial dieback and environmental changes. This dissertation also provides new methods for removing strip-bark biases in tree-ring chronologies. The conclusions presented here have important implications regarding the potential effects of partial cambial dieback on tree-ring records from other tree species and climate reconstructions derived from them. Continued and detailed study of the causes and impacts of partial cambial dieback on other tree species will be critical for understanding the interactions between ancient trees and their environment, and for improving the reliability of climate reconstructions based fully or partly on strip-bark trees.

Thesis advisor: Jeremy Shakun / As recently measured amounts of global atmospheric carbon dioxide concentrations have risen 40% from pre-Industrial levels and will likely reach double by mid-century, climate scientists have expressed concern over the future state of the climate system, and have attempted to gauge the consequences of such a large forcing. The principal parameter for climate scientists is equilibrium climate sensitivity, which is the change in temperature following a doubling of atmospheric CO2 concentrations. Current estimates of climate sensitivity span too expansive of a range to provide a clear understanding of the magnitude of temperature changes one can expect. Therefore, I conduct many individual multivariate analyses as a means of narrowing these ranges of sensitivity and to investigate geographical distributions of sensitivity, at the very least. To do so, I analyze four major climate forcings: greenhouse gas, atmospheric dust, ice volume, and insolation. Using several multiple linear regressions, I calculate the relative weighting of each forcing in driving the temperature signal in 47 local temperature proxy records. The paleoclimate proxy records chosen span glacial cycles over the past 800 kyr. These results provide insight into the geographical distributions of the relative influences of each of the forcings, while working to constrain the range of sensitivity estimates through the weighting of the greenhouse gas forcing. Separating out the individual climate inputs allows me to conclude what percentage of climate change was caused by CO2 in the past, and by implication how much warming might be expected due to GHG forcing in the future. / Thesis (BS) — Boston College, 2015. / Submitted to: Boston College. College of Arts and Sciences. / Discipline: Earth and Environmental Sciences.

Uranium and thorium isotopes are powerful and sensitive tracers of a wide range of oceanographic and environmental processes. This thesis makes use of these isotopes in deep sea sediments to reconstruct dust fluxes and deep ocean respired carbon storage over the last 350 kyr in the central equatorial Pacific. The paleoenvironmental information obtained through the application of these isotopes as proxies reveals important information about the Earth’s ocean and atmosphere, and their connectivity on millennial and glacial-interglacial timescales. In Chapter 1 of this thesis I introduce the proxies and principals employed in our paleoenvironmental reconstructions. Subsequently, the first section of this thesis explores the use of 230Thxs,0-derived 232Th fluxes as a proxy for aeolian dust deposition at three sites beneath the shifting Pacific Intertropical Convergence Zone (ITCZ). The new records presented here improve upon existing records of tropical Pacific dust fluxes by increasing the temporal resolution ~5 fold and adding almost an order of magnitude more data. Specifically, we reconstruct dust fluxes in two cores from 0-150 ka and from one core from 0-350 ka In addition to substantially improving constraints on tropical dust fluxes this work also utilizes the spatial transect of cores to infer past positions of the ITCZ on glacial-interglacial and millennial timescales. This proxy approach to reconstruct ITCZ position has only been applied and published once previously, in a relatively low-resolution study. Chapter 2, entitled “Large deglacial shifts of the Pacific Intertropical Convergence Zone,” presents evidence that the Pacific ITCZ experienced large shifts in latitudinal position, on millennial timescales during the penultimate deglaciation. The data resolve abrupt shifts in atmospheric circulation associated with deglaciation, in this case Termination II, at the boundary between the full glacial marine isotope stage (MIS) 6 and the peak interglacial MIS 5. These shifts are significant in that they appear to have occurred at the same time as changes in the North Atlantic driven by Heinrich Stadial 11 and may have played an important role in pushing the climate system over the threshold for deglaciation. Indeed, this study is the first to show evidence of a millennial-scale ITCZ response at the time of the Heinrich Event 11 catastrophic iceberg discharge event. Additionally, the data point to the existence of a previously unidentified millennial peak in northern hemisphere dust abundance during the penultimate deglaciation. In Chapter 3, “Climate-related response of dust flux to the central equatorial Pacific over the past 150 kyr,” records of dust flux are used to provide strong evidence for an association between high latitude stadial events and tropical dust fluxes during the last 150 kyr. These high-resolution observations permit the drawing of conclusions about the meridional location of the Pacific ITCZ during six Greenland stadials. As with the shift of the ITCZ during Heinrich Stadial 11, these events were associated with perturbations of the interhemispheric thermal gradient and coincident movement of the ITCZ presents an important constraint on the sensitivity of the tropical atmosphere to high latitude perturbations. The conclusions stemming from the interpretation of geochemical and paleoceanographic data presented in Chapters 2 and 3 are of broad relevance to a variety of geoscience disciplines that seek an understanding of the climate system. For example, these results confirm predictions made by modeling studies about the response of the ITCZ to high latitude climate forcing and provide an important new set of boundary conditions for modeling studies aimed at reconstructing changes in insolation forcing and tropical hydroclimate. The results show that paleo-reconstructions can constrain the magnitude of even abrupt ITCZ movement, demonstrating the potential to relate ITCZ changes to the magnitude of thermal forcing and to investigate thermal and hydrological components of other climate change events, past and future. Additionally, these results help improve understanding of the relationship between atmospheric dust abundance and climate, with implications for planetary albedo and micronutrient fertilization of the oceans. The second portion of this thesis focuses on using authigenic uranium (aU) to reconstruct deep water chemistry with implications for paleocirculation. Chapter 4, “Repeated storage of respired carbon in the equatorial Pacific Ocean over the last three glacial cycles,” presents evidence that the Pacific was a significant reservoir for respired carbon during glacial periods over at least the last 350 kyr. This reconstruction is based on the precipitation of the redox sensitive metal uranium as a proxy for deep water oxygen concentrations. Because any change in oceanic storage of respiratory carbon must be accompanied by corresponding changes in dissolved oxygen concentrations, data reflecting bottom water oxygenation are of value in addressing questions of glacial carbon sequestration. The record reveals periods of deep ocean aU deposition during each of the last three glacial maxima. Export productivity data indicate these intervals are not associated with local productivity increases, indicating episodic precipitation of aU occurs in response to basin-wide decreases in deep water oxygen concentrations. Not only does the aU record show the history of dissolved oxygen concentrations in the central equatorial Pacific, it also provides an opportunity for the reconciliation of records previously interpreted as incompatible with one another and with the storage of respired carbon. Synthesis of existing data suggests the existence of a ’floating’ pool of respired carbon between 2 and 3.5 km depth in the equatorial Pacific. This hypothesis permits the interpretation of existing proxy data reflecting abyssal LGM circulation and carbon storage without invoking a glacial watermass geometry significantly different from present. The new data and conclusions presented in Chapter 4 represent a significant advance in our understanding of where carbon was stored in the ocean during successive glacial periods. The perspective provided by the new aU time series is spatiotemporally unique and constitutes compelling evidence that hypotheses of marine carbon storage developed to explain the last glacial period are equally applicable to previous Pleistocene glacial periods. The three studies presented in this thesis provide strong support for the utility of U and Th series isotopes in paleoenvironmental reconstructions. Not only does this work demonstrate the range of paleoclimatic proxy data that can be obtained from isotopes of U and Th, it also illustrates the value of interpretations derived from their analysis. The records presented here represent a substantial contribution to our knowledge of marine hydroclimate and ocean circulation over the last 350 kyr and motivate additional high resolution paleoclimate work using isotopes of U and Th.

The fossilized remains of the calcite shells of foraminifera comprise one of the most continuous and reliable records of the geologic evolution of climate and ocean chemistry. The trace elemental composition of foraminiferal shells has been shown to systematically respond to seawater properties, providing a way to reconstruct oceanic conditions throughout the last 170 million years. In particular, the boron/calcium ratio of foraminiferal calcite (B/Ca) is an emerging proxy for the seawater carbonate system, which plays a major role in regulating atmospheric CO2 and thus Earth’s climate. In planktic foraminifera, previous culture studies have shown that shell B/Ca increases with seawater pH, which is hypothesized to result from increased incorporation of borate ion (B(OH)4 -) at high pH; increasing pH increases the [B(OH)4 -] of seawater. However, further experiments showed that B/Ca responds to both pH and seawater dissolved inorganic carbon concentration (DIC), leading to the hypothesis that B/Ca is driven by the [B(OH)4 -/DIC] ratio of seawater. Because pH (and thus B(OH)4 -) can be determined via the δ11B composition of foraminiferal calcite, B/Ca therefore may provide an opportunity to determine seawater DIC in the geologic past. The magnesium/calcium ratio (Mg/Ca) of foraminifer shells is a well-established proxy for seawater temperatures, where foraminiferal Mg/Ca increases at greater temperatures. However, foraminifera shell chemistry such as B/Ca and Mg/Ca ratios also depend on the major ion chemistry of seawater. For example, the seawater Mg/Ca ratio (Mg/Casw), which has increased significantly over the last 60 million years, is known to affect the sensitivity of the Mg/Ca proxy to temperature. In addition, the seawater boron concentration ([B]sw) has also increased across the Cenozoic. The dependence of B/Ca proxy relationships on Mg/Casw and [B]sw composition remains unknown. During the Paleogene era (65-34 Ma), Earth’s climate was characterized by a number of rapid warming events termed ”hyperthermals”. Evidence from the sedimentary record suggests that hyperthermals were catalyzed by rapid carbon release and caused widespread ocean acidification and deep-sea deoxygenation. These hyperthermal events present the best geologic analog conditions to anthropogenic climate change, and their study can therefore help to illuminate how the Earth system responds to rapid carbon release and warming. Planktic foraminiferal B/Ca records from the largest hyperthermal event, the Paleocene-Eocene Thermal Maximum (PETM), show a large decrease, which agrees with the theory that ocean acidification should cause B/Ca to decline. However, the decrease is larger than can be reconciled from existing proxy calibrations conducted in modern seawater, begging the question of whether the low Mg/Casw of the Paleogene Ocean affected the sensitivity of B/Ca to the seawater carbonate system. Because there are also a number of outstanding uncertainties regarding the controls on B/Ca- including seawater [Ca] and shell growth rate, light intensity, and phosphate concentration- it is also possible that these factors contributed to the PETM B/Ca excursion. The influence of these additional parameters on B/Ca, as well as the influence of Mg/Casw, needs to be tested in controlled culture experiments. To address these outstanding questions in proxy development, I conducted a series of culture experiments in three living planktic foraminifer species- Orbulina universa, Trilobatus sacculifer, and Globigerinoides ruber (pink). In order to refine our understanding of proxy controls on foraminiferal B/Ca, I investigated how foraminiferal B/Ca is affected by variable light intensity, growth rate (indirectly via seawater [Ca] manipulation), and seawater [B]. Subsequently I tested the influence of low seawater Mg/Ca, analogous to that of the Paleocene ocean, on B/Ca-carbonate chemistry relationships. In Chapters 2 and 3, I detail how my results support the notion that planktic foraminiferal B/Ca in these three symbiont-bearing species is driven by the B(OH)4 -/DIC ratio of seawater and is not compromised by growth rate effects. Furthermore, the sensitivity of B/Ca to B(OH)4 -/DIC is increased under low Mg/Casw in both O. universa and T. sacculifer. In Chapters 2 and 3, I hypothesize that this increased sensitivity is due to decreased cellular pH regulation under low Mg/Casw, leading to a greater sensitivity of the foraminiferal microenvironment’s carbon system to external forcing. I define new culture calibrations that can be applied to records from Paleocene seawater in Chapter 3, and use these calibrations to reconstruct surface ocean DIC and the overall size of the carbon system perturbation across the PETM in Chapter 4. Finally, in Chapter 5, I show how foraminiferal Mg/Ca responds to seawater Mg/Ca and the carbon system from these same experiments, with implications for accounting for carbon system influences on Mg/Ca from early Cenozoic proxy records.