published_or_final_version / Earth Sciences / Master / Master of Philosophy

D.Phil. / The Mesoarchean Pongola Supergroup, cropping out in the southeastern region of the Kaapvaal craton, is one of the oldest known supracrustal successions in the world. It represents an erosional remnant of a once extensive cratonic cover sequence. The succession is subdivided into the lower Nsuze Group, a volcano sedimentary succession, and the Mozaan Group composed mainly of siliciclastics and minor volcanics. The Mozaan Group is host to the world’s oldest known glacial deposit. The Pongola Supergroup is well preserved both geochemically and structurally. Outcrops extend from the northern part of KwaZulu-Natal and Mpumalanga Province in South Africa into Swaziland. This study presents results of an integrated stratigraphic, sedimentological, geochemical, geochronological, and paleomagnetic investigation of the Pongola Supergroup in Swaziland and drill cores from the Nongoma Graben in KwaZulu-Natal. The Nsuze Group displays marked cyclicity between volcanic and siliciclastic rocks that were probably deposited in an intracratonic ‘sag and dome’ basin. The volcanicsedimentary cycles are thought to represent periodic heat loss from a hot regional mantle beneath the Kaapvaal craton. In the sag basins the rate of subsidence was gradual and sedimentation marked by near shore deposition. Volcanism in the Agatha Formation was episodic and displays a cyclicity of 2-14Myr in duration. Magmatic eruption was marked by the development of a low crustal level magma chamber. Crustal contamination trough assimilation and fractional crystallization at these low crustal level magma storages is recorded by compositional bimodal volcanism of basaltic andesite-rhyodacite and andesite-rhyolite association. After cessation of the volcanism of the Nsuze Group, subsequent development of the Pongola basin was marked by thermal subsidence and marine transgression in an epicratonic basin, at the time of deposition of the Mozaan Group. The Mozaan Group overlies the Nsuze Group with an erosive unconformity developed over an in situ weathering profile, i.e. a paleosol. The Mozaan Group consists of alternating quartzite, shale, conglomerate, iron-formation. Three units of contemporaneous flood basalt, namely the Tobolsk, Gabela and Ntanyana formations are interbedded with the siliciclastic deposits in the upper part of the succession. Unimodal paleocurrent directions based on fluvial quartzites indicate initial provenances to the south and north. This indicates that the basin morphology was in a form of a trough. Eventually paleocurrent distribution patterns turn southeast, and marine flooding extended further towards the west, to form the Greater Witwatersrand Basin, which was then modified by development of a foreland basin towards the west and northwest. This suggests that the present outcrops of the Mozaan Group represent mere remnants of an extensive basin. Siliciclastic deposits of the Mozaan succession harbours a wealth of information on the crust-forming events that affected the Kaapvaal craton. Detrital zircons from quartzites and diamictite samples yield ages that record magmatic events that extend from the early (ca. 3.6Ga) to middle (2.89Ga) Archean. Late magmatic events were coeval with the development of the Mozaan basin. The Mozaan succession also is host to the oldest known glacial deposits, namely the Klipwal and the Mpatheni Member diamictites. The absence of deformation, erosional contacts and the presence of incorporated underlying material suggest that grounded glaciers were not the mode of deposition of these diamictites, but that the glacial deposits can be explained as gravity flows from collapse of oversteepened slopes of low relief glaciomarine setting that degenerated in more distal part of the basin into clast poor turbidity flows. Analysis of shale and matrix composition in diamictites show that mechanical erosion processes dominated the source area. CIA values range between 70 and 81, suggesting negligible chemical weathering in the sediment source area. CIA values increase only in the upper part of the stratigraphy, i.e. Ntanyana Formation. Incompatible to compatible trace element ratios are low and suggest that mafic and ultramafic rock dominated the source area. This, perhaps, demonstrates that the greenstone belts were a major source of detritus to the Mozaan basin. Well-constrained paleomagnetic data sets acquired from the Klipwal Member diamictite and Tobolsk lava give a very good estimate of the paleogeographic setting of the Kaapvaal craton during the deposition of the Mozaan Group. The Klipwal diamictite was apparently deposited at high-paleolatitude setting of 48°. The craton then moved slightly to the north to latitude ~43° at the time of eruption of the Tobolsk lavas. From the results it appears that available geochemical classification schemes based on the composition of Phanerozoic volcanic rocks are not suitable to classify the lavas of the Agatha Formation unequivocally. To arrive at any tectonic model for these igneous rocks it is necessary to consider stratigraphic relationships, physical volcanology and geochemical characteristics of the rock succession. On the other hand, the wellconstrained paleomagnetic data indicate that the global climate system in the Mesoarchean was similar to modern day earth where glacial deposits are constrained largely to Polar Regions.

Thesis (M.Sc.)--Memorial University of Newfoundland, 2005. / Restricted until May 2006. Bibliography: leaves 75-77. Also available online.

published_or_final_version / Earth Sciences / Master / Master of Philosophy

In this study, palaeomagnetic methods have been combined with field and volcanological techniques to identify, classify and correlate the pyroclastic deposits found on Ascension Island, South Atlantic, allowing them to be placed into a temporal and geographic framework. Pyroclastic material is abundant on the island and, in general, wellpreserved, making Ascension an ideal site to study the nature and distribution of the pyroclastic products of this type of composite volcano or stratovolcano. A better understanding of the nature and distribution of the products of past pyroclastic eruptions on Ascension should enhance our ability to assess volcanic hazard around stratovolcanoes world-wide. Field mapping and stratigraphic logging have revealed the presence of several major pyroclastic sequences on Ascension. These comprise extensive felsic (pumice) and mafic (scoria) lapilli deposits, two major and several minor exposures of welded material and numerous breccia deposits that exhibit great variation in juvenile/lithic content, matrix type and content and internal structure. Preliminary interpretations of the deposits were made in the field, based on features such as welding, grain shape and internal structures. However many of the deposits - particularly the breccia deposits - display ambiguous field characteristics that could be attributed to pyroclastic or epiclastic processes and their origins could not therefore be determined from field characteristics alone. [See pdf for continuation of abstract].

Thesis (M. Phil.)--University of Hong Kong, 2009. / Includes bibliographical references (leaves 106-131) Also available in print.

Thesis (M. Phil.)--University of Hong Kong, 2000. / Includes bibliographical references (leaves 177-190).

Thesis (Ph. D.)--Lehigh University, 1997. / Includes vita. Bibliography: leaves 163-175.

Thesis (M.S.)--University of Wisconsin--Madison, 1969. / eContent provider-neutral record in process. Description based on print version record. Includes bibliographical references.

The Kaapvaal craton of southern Africa and the Pilbara craton of Western Australia, two of the best-preserved Archean cratons in the world, are covered by remarkably similar early Precambrian cover sequences. This has led to the proposal of the so-called Vaalbara hypothesis, which promotes the existence of the two cratons as a single crustal entity, and possibly, Earth’s oldest assembled continent in Neoarchean-early Paleoproterozoic times. Previous studies have failed to prove the existence of Vaalbara conclusively, principally due to a lack of reliable ages or because of uncertainty and gaps in the paleomagnetic record from the Kaapvaal craton. During the present study paleomagnetic samples were collected from selected Neoarchean- Paleoproterozoic cover sequences of the Kaapvaal craton for the establishment of well-defined paleomagnetic poles. In addition, the Hartswater Group of the Ventersdorp Supergroup was sampled for zircon SHRIMP analyses in order to constrain the ages of poles defined from that succession. The paleopoles established here, together with existing paleopoles from the Kaapvaal craton, are used to evaluate the apparent polar wander path of the craton during the Neoarchean-Paleoproterozoic and are compared with poles of similar age from the Pilbara craton as a test of the Vaalbara hypothesis. Regarding the age of the Hartswater Group, zircon SHRIMP ages of 2735 ± 3 Ma and 2724 ± 6 Ma cast doubt on younger ages from the Klipriviersberg Formation, which comprise the base of the Ventersdorp Supergroup. Traditional (younger) age constraints from the Ventersdorp Supergroup do not support the original Vaalbara correlation. A new correlation is suggested here, taking the new ages into account, showing that the Ventersdorp Supergroup overlaps in time with the Fortescue Group of the Pilbara craton. Most importantly, the new ages also provide constraints on the magnetization within the Platberg Group and the Allanridge Formation. Six new paleopoles, of various quality, are added to the existing database from that craton. These poles from the ~2.73 Ga Platberg Group and ~2.7Ga Allanridge Formation of the Ventersdorp Supergroup, the ~2.5Ga lower Transvaal Supergroup, the lower two unconformitybounded sequences of the Waterberg Group (2.05 Ga and ~1.99 Ga) and the upper Soutpansberg Group (~1.76 Ga) have, together with existing poles from the Kaapvaal craton, led to the definition of an APWP for that craton for a period ~2.78 to ~1.76 Ga. Particularly the poles from the Waterberg and Soutpansberg Groups provided the information to identify complexities (looping) in the APWP that have gone unrecognized in the past. The paleomagnetic data gathered and the newly defined APWP could be used in conjunction with geological evidence from the Kaapvaal and Pilbara cratons to evaluate, and validate, the Vaalbara hypothesis. A good match between the APWP’s of the two cratons for the period ~2.78 to ~2.70 Ga and the geological features (lithology and structure) of the two cratons provide the best evidence that Vaalbara existed as a cratonic unit in the late Archean. Paleomagnetic data constrain the position of the Pilbara craton in immediate proximity to the northwest of the Kaapvaal craton (in a Kaapvaal reference frame). The position of the Zimbabwe craton relative to the Pilbara and Kaapvaal cratons is still unresolved, but indications are that it was most likely in a proximal position to the Kaapvaal craton at 2.7 Ga in a configuration not much different from its present day configuration. This would imply that Vaalbara was most probably the Earth’s oldest assembled continent as proposed by earlier workers. The new paleomagnetic data further suggest that Vaalbara did not exist anymore at ~2.0Ga. When evaluated in conjunction with geological evidence a strong argument can be made for the existence of the Vaalbaran continent up until ~2.22 Ga and that the Pilbara and Kaapvaal cratons became separate entities from about ~2.05 Ga. / Prof. NJ Beukes Prof. DAD Evans