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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Effects of Fluid Mg/Ca And Dp18So on Geochemistry of Calcium Carbonates: Studies on Inorganic and Natural Samples

Novak, Aleksandra Vladimirovna 07 May 2016 (has links)
Mg/Ca and d18O derived from marine biogenic carbonates have been widely used as reliable paleoenvironmental proxy for seawater temperature, salinity and water mass circulation reconstructions. The use of Mg/Ca is based on long residence time in seawater and uniform distribution with habitat depth of planktonic foraminifera. Fluid Mg/Ca affects mineralogy of CaCO3, thus high seawater Mg/Ca favors precipitation of aragonite instead of calcite. The records of d18O in carbonates yield strong correlation with seawater temperature, salinity and d18O. Distribution of d18O in water is highly heterogeneous within longitude, latitude and depth. Therefore a combination of foraminieral d18O and Mg/Ca could resolve temperature, d118Owater, and hence salinity, which is linked to variability in fresh water balance and glacial ice volume throughout geologic history. In this work we study the effects of important seawater/fluid parameters on Mg/Ca in inorganic and d18O in natural samples and provide data for improving paleoceanographic reconstructions.

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