Making CZTSe thin film of sputtering and Selenization.Sputtering Zn¡BSn precursor layers on Soda-lime glass¡Aand using evaporating to stack Cu layer.Let it annearing under Selenium atmosphere for less then one hour. We are looking forward a profit annealing process to grow CZTSe thin film.By changing temperature of Substrate¡Bannealing time and heating rate of Substrate. Using XRD and Raman to analysis composition and crystal structure. The morphology from SEM images.Taking analysis on optical and electronic property of the thin film.