La première partie de ce travail présente une nouvelle méthode qui permet de détermination rapidement de la température et de la concentration en fer d'un plasma d'arc MAG utilisé dans la technologie de soudage par plasma. Le plasma est un mélange [Ar-CO2] en présence de fer, avec un rapport molaire entre Ar et CO2 constant de 82%-18%. La seconde partie s'intéresse au rayonnement d'un plasma d'argon utilisé dans la technologie soudage GTAW et pouvant conduire à des dangers photobiologique. Dans le chapitre 1, le contexte et la motivation de ce travail sont présentés. Les travaux déjà effectués et publiés dans ces deux axes scientifiques sont passés en revue. Dans le chapitre 2, les compositions à l'équilibre sont calculées par la méthode de la minimisation de l'énergie libre de Gibbs. Les densités et fonctions de partitions obtenues pour chaque espèces présente dans le plasma sont ensuite utilisées pour déterminer les pertes radiatives des plasmas [Ar-CO2]-Fe via la méthode du coefficient d'émission net (CEN). Cette estimation des pertes ne peut se faire sans le calcul préalable du coefficient d'absorption spectral que nous avons réalisé finement par la méthode " raie par raie ". Tous les mécanismes radiatifs prédominants dans le plasma ont été pris en compte: continua atomique et moléculaire, raies atomiques et moléculaires. Cette partie constitue la base de cette étude sur laquelle se fonde notre nouvelle méthode de diagnostic destinée à déterminer à la fois la température et la concentration en fer d'un plasma d'arc de soudage. Le chapitre 3 est dédié à l'étude expérimentale d'un plasma d'arc MAG constituée d'une analyse spectroscopique permettant de remonter au profil de température et tester l'hypothèse de l'Équilibre Thermodynamique Local. La température d'excitation est obtenue par la méthode de Boltzmann tandis que la mesure d'élargissement de Stark pour les raies de fer et d'argon permet de remonter à la température et la densité des électrons. / This PhD thesis introduces a method that allows the fast determination of temperature and iron concentration for MAG-P Arc. The MAG-P Arc is in fact [Ar-CO2]-Fe mixtures, with a constant molar ratio between Ar and CO2 [82%Ar-18%CO2]. In a second time, this thesis presents a study of the optical radiation associated to photobiological hazards for argon GTAW Arc. In chapter 1, the background and motivation of this work is introduced. The previous works published in this field are reviewed. In chapter 2, the equilibrium compositions are calculated firstly using the minimization of Gibbs free energy. Then the radiative properties of [Ar-CO2]-Fe plasmas are obtained in the frame of the net emission coefficient (NEC) approach, using the accurate "line by line" method. All significant radiative contribution mechanisms are taken into account in the calculation. This study will constitute a groundwork to build the diagnostic method that allows determination of temperature and iron concentration profiles in welding arc. In chapter 3, spectroscopic investigation of the LTE hypothesis across the MAG-P Arc is made. Excitation temperature is obtained with Boltzmann plot method while iron and argon lines Stark broadening measurements are used to get electron temperature and electron density. LTE hypothesis validity across the arc is discussed considering the agreement between the two temperatures, the electron density and iron content. Results show supporting evidence for the main part of the plasma, along radial and axial directions. Discrepancies occur only at the fringe of the arc, where the two temperatures differ by more than 2000 K. In chapter 4, a method allowing a fast determination of space- and time-resolved plasma temperature and iron concentration in MAG arcs during the high-current phase is introduced. This method consists in measuring the plasma spectral radiation of the arc with iron vapours using a high-speed camera filtered by narrow band filters in the spectral intervals of 570-590 nm and 606-627 nm respectively; calculating theoretically the dependence of the absolute emissivity e570-590 nm and relative emissivity e570-590 nm/e607-627 nm versus the plasma temperature and the iron concentration. This method has also been validated for a layer of plasma by adopting other existing diagnostics such as Stark broadening, which demonstrates the effectiveness of this new method. In chapter 5, a theoretical investigation of the UV (180-400 nm), UVA (315-400 nm) and blue light (300-700 nm) radiation associated with the photobiological hazards to workers for argon GTAW arcs is presented. The radiative properties of argon plasma are calculated for the three spectral regions, and a two-dimensional model of a GTAW arc is then developed to determine the local emissions in the arc, the total radiation escaping from the arc and corresponding effective irradiances. This study clearly supports the importance of undertaking an effective protection strategy for workers, particularly for skin and eyes, in the welding environment. Finally, a general conculsion is given in chapter 6.

This doctoral thesis called “Photobiological safety of luminaires and light sources” has focused on an optical radiation and its relation to human body. The thesis describes possible consequences on living tissue during excessive exposure to optical radiation. Among others the work deals with the light source, lamp and optical devices evaluation in dependence of photobiological safety. There is created a method of light source evaluation procedure for photobiological safety in accordance with ČSN EN 62471. The meaning of this procedure is based on its hazard calculation from measured values of irradiation to different photometric distances. Validity of procedure is verified by light source measuring, in which visual angle and photometric distance have been changed. There we can also find an application of this procedure in the UV source evaluation, which helps to determine a safe distance away from UV sources not to create any danger. The evaluated UV sources include a UVA luminaire with a dominant wavelength of 365 nm or an arc of an electric welder. The thesis also describes a method of evaluating light sources for blue light hazard for an aphakic and pseudophakic eye. This method can also help to determine the hazard for the eye without lens or with some implanted lens. Furthermore, there was developed the method of the blue light hazard assessment depending on the age of an exposed person. In terms of the work there was also created a computer programme evaluating photobiological safety resulting from the spectral data having been stored in the library programme or from spectroradiometric measurement data. The work also marginally deals with the topic of circadian rhythms, which are closely related to photobiological manifestation in an human body. Above all the work compares light sources for which equivalent illuminances are calculated, consequently light sources have the same effect on suppressing the melatonin hormone production.

The thesis deals with the problems of the photobiological lamp and lamps systems safety. It is divided into theoretical and practical parts. The theoretical part touches the basic knowledge concerning the eye and vision, eye and skin diseases caused by excessive exposure to non-ionizing radiation. And besides that there are described the sources of light causing the possible exposure and further more it includes the methodology of measurement and evaluation of photobiological safety. The practical part investigates a measurement of the spectrum of light sources. The measured data are evaluated according to the methods mentioned in the theoretical part.