Inaug.-Diss.--Kaiser Wilhelms Universität. / Includes bibliographical references.

Thesis (M.A.)--West Virginia University, 2008. / Title from document title page. Document formatted into pages; contains iii, 48 p. Includes abstract. Includes bibliographical references (p. 46-48).

Thesis (Ph. D.)--University of Washington, 2004. / Vita. Includes bibliographical references (p. 115-124).

This dissertation has investigated the adsorption, thermal behavior, and radiation (both photon and electron) processing of prebiotically-relevant ices and surfaces. A custom ultra-high vacuum (UHV) chamber has been built that is coupled with a Fourier Transform-Infrared (FT IR) spectrometer and a Temperature Programmed Desorption (TPD) system that utilizes Quadrupole Mass Spectrometry (QMS) to study selected organic:surface systems. Formamide (HCONH₂) has been studied in two related but distinct studies relevant to primitive Earth and interstellar chemistry. First, in collaboration with a theory group, formamide’s interaction with kaolinite (Al6Si6O36H30), a clay mineral relevant to early Earth chemistry, has been studied experimentally and theoretically. Experimental infrared results are compared with calculated infrared frequencies obtained by our collaborators. TPD analysis is compared with the calculated values of adsorption energy, and the optimal kaolinite termination site for adsorption is reported. Second, the first thermal and radiation damage study of pure formamide and HCONH₂:H₂O mixed ices on an interstellar icy grain analog (SiO₂) is reported. A discussion of the pure formamide ice phases identified with FT-IR upon warm-up, as well as the TPD binding energies of HCONH₂ on SiO₂, is presented. The observed Lyman-alpha photochemical products and proposed formation mechanisms from pure formamide ice is reported and discussed. In addition, results of Lyman alpha processing of mixed HCONH₂:H₂O ices are provided. Low-energy electron irradiation of pure HCONH₂ and HCONH₂:H₂O mixed ices has also been reported for the first time. A third investigation has studied acetylene (C₂D₂) and acetonitrile (CH₃CN) interactions and radiation stability in mixed low-temperature ices to simulate possible prebiotic reactions that may occur on Saturn’s moon, Titan. This investigation contributes to understanding the possible consumption, trapping, and degradation of these species on the surface of Titan.

Continental and submarine hydrothermal systems are commonly found around the world. Similar systems that sustain water or other fluids are also likely to exist in planetary bodies throughout the solar system. Also, terrestrial submarine systems have been suggested as the locations of the first life on Earth and may, therefore, provide indications of where to find life on other planetary bodies. The study of these systems is vital to the understanding of planetary heat transfer, chemical cycling, and biological processes; hence hydrothermal processes play a fundamental role in planetary evolution. In this thesis, three particular types of hydrothermal systems are investigated through the development of mathematical models: (1) terrestrial low-temperature diffuse flows at mid-oceanic ridges (MORs), (2) submarine near-axis convection on Earth, and (3) convection driven by magmatic intrusives on Mars. Model set-ups for all systems include a two-dimensional space with a vertical, hot wall, maintained at constant temperature, located adjacent to a water-saturated porous medium at a lower temperature. By assuming that convection occurs vigorously and within a thin layer next to the hot wall, boundary layer theory is applicable. The models provide steady-state, single-phase estimates of the total heat and mass transfer rates in each scenario over permeability ranges of 10^-14 m² to 10^-10 m² for the submarine systems and 10^-14 m² to 10^-8 m² for the Martian systems. Heat output results derived from the boundary layer model suggest that diffuse flow on MORs contributes 50% or less of heat output to the ridge system, which falls at the low end of observations. For the near-axis model, results found that heat transfer in the hydrothermal boundary layer was greater than the input from steady state generation of the oceanic crust by seafloor spreading. This suggests that the size of the mushy zone evolves with time. Heat output and fluid flux calculations for Martian systems show that fluid outflow adjacent to a single intrusion is too small to generate observed Martian surface features in a reasonable length of time.