No description available.

No description available.

No description available.

No description available.

Ground magnetic data are consistent with the interpretation that Lower Jurassic volcanic rocks of the Twin Buttes mine area (Ox Frame Volcanics) are confined to a distinct block by the northwest trending Sawmill Canyon Fault Zone which was initially active during the Lower Jurassic. Possible reactivation of the Sawmill Canyon Fault zone in the Middle Jurassic as a left-lateral wrench fault is recorded by the deposition of syntectonic red-beds (Rodolfo Formation). Lower Cretaceous rocks (Whitcomb Quartzite, Glance Conglomerate, and Angelica Akrose) were deposited in alluvial environments resulting from additional reactivation of the Sawmill Canyon Fault Zone. Upper Cretaceous (Laramide) deformation involved the formation of northwest trending folds and northwest and northeast trending reverse, tear, and later block faults during the uplift of Precambrian basement. Ore deposits of the Pima mining district are localized along a northeast trending fault zone with evidence for initial activity in the Middle Jurassic and later reactivation during the Laramide.

Metamorphic rocks constitute a vast volumetric proportion of the Earth’s continental lithosphere and are invaluable recorders of the mechanisms and rates of deformation and metamorphism that occur at the micro-, meso- and macro-scale. As such, they have the potential to provide detailed insight into important tectonic processes such as the subductive transport of material into, and back from, mantle depths and also folding, faulting and thickening of crust that occurs during collisional orogeny. The Himalayan-Karakoram-Tibetan orogen is the youngest and most prominent example of a continent-continent collisional mountain belt on Earth today and is a product of the on-going convergence of the Indian and Asian plates that initiated in the Early Eocene. Thus, it provides an exceptional natural laboratory for the investigation of such processes. Recent advances in the computational ability to replicate natural mineral assemblages through a variety of metamorphic modelling techniques have led to improvements in the amount (and quality) of petrographic data that may be obtained from a typical metamorphic rock. In this study, phase equilibria modelling (pseudosection construction) using THERMOCALC, amongst other techniques, has been integrated with in-situ U–Pb and Th–Pb geochronology of accessory monazite in order to constrain the tectonothermal evolution of four regions intimately associated with the Himalayan-Karakoram-Tibetan orogen. These regions comprise the Karakoram metamorphic complex (north Pakistan), the Tso Morari massif (north-west India), the eastern Himalayan syntaxis (south-east Tibet) and the Day Nui Con Voi metamorphic core complex of the Red River shear zone (North Vietnam). Each case study documents previously unreported metamorphic, magmatic or deformational events that are associated with the India-Asia collision. These data have allowed original interpretations to be made regarding the tectonic evolution of each individual region as well as the large-scale evolution of the Himalayan-Karakoram-Tibetan orogenic system as a whole.

published_or_final_version / Earth Sciences / Master / Master of Philosophy

Brandt, Martin B.C. 2011. Imaging the African Superplume – Upper mantle, Tomography and Moment tensor. Ph.D. thesis, Faculty of Science, University of the Witwatersrand, Johannesburg, South Africa. The African Superplume, African Superswell and East African Rift System are amongst the most prominent geophysical features on Earth, but the structure, evolution and interaction between these features is controversial. In my thesis I conducted a range of investigations in an effort to better understand these issues. The thesis presents the investigations into the structure and expressions of these features. These include: (I) A study of the upper mantle shear velocity structure beneath southern Africa to investigate the source of the buoyancy that has powered the Superswell; (II) Statistical hypothesis testing of middle-mantle shear velocity tomographic models to evaluate evidence for links between the Superplume and low velocity features in/near the transition zone; and (III) Computation of three new regional moment tensors for South Africa to assess crustal stress in the Kalahari craton, and its link with mantle structure and dynamics. Waveform data were obtained for the study on the upper mantle shear velocity structure and the moment tensor inversions from the Southern African Seismic Experiment Kaapvaal craton array. For the statistical hypothesis testing on global tomography images, new travel-time data from both global and AfricaArray stations were added to Grand’s global shear velocity data set. The principal findings of this study are summarized below. I. The upper mantle shear velocity structure beneath the Kalahari craton is similar to that of other shields, except for slightly slower velocities from 110–220 km depth. The difference may be due to higher temperatures or a decrease in magnesium number (Mg#). If the slower velocities in the deep lithosphere are due solely to a temperature anomaly, then slightly less than half of the unusually high elevation of the Kalahari craton can be explained by shallow buoyancy from a depleted hot lithosphere. Decreasing the Mg# of the lower lithosphere would increase density and counteract higher temperatures. If an excess temperature of 90 K over a 110 km depth range and a corresponding decrease in Mg# of -2 between the Kalahari and the other cratons are assumed, this would match the seismic velocity difference but would result in essentially no buoyancy difference. We conclude that the high elevation of the Kalahari craton can only be partially supported by shallow mantle buoyancy and must have a deeper source. We determined a thickness of 250±30 km for the mantle transition zone below eastern southern Africa, which is similar to the global average, but the corresponding velocity gradient is less steep than in standard global models (PREM and IASP91). Velocity jumps of 0.16±0.1 km/s (eastern) and 0.21±0.1 km/s (central) across the 410 km discontinuity were found. Our results indicate a thermal or chemical anomaly in the mantle transition zone, but this cannot be quantified due to uncertainty. II. Statistical hypothesis testing on our global tomography images indicated that the African Superplume rises from the core-mantle boundary to at least 1150 km depth, and the upper mantle slow-velocity anomaly extends from the base of the lithosphere to below the mantle transition zone. The model that links the African Superplume with the slow-velocity anomaly in the upper mantle under eastern Africa has an equal probability to an alternative hypothesis with a thin slow-velocity “obstruction zone” at 850 to 1000 km depth. III. Finally, we calculated three regional moment tensors for South Africa and made progress towards resolving the discrepancy between the local and moment magnitudes we observe for the region. Moment tensors/focal mechanisms in southern Africa change from normal faulting (extension) in the northeast near the East African Rift to strike-slip faulting in the southwest. This confirms previous studies stating that not only eastern Africa, but also southern Africa is being actively uplifted by lithospheric modification at its base and/or the African Superplume.

A dissertation submitted to the Faculty of Science, University of the Witwatersrand, in fulfilment of the requirements for the degree of Doctor of Philosophy, Johannesburg 2014 / Namibia is renowned for its abundant mineral resources, a large proportion of which are hosted in the metasedimentary lithologies of the Damara Belt, the northeast-trending inland branch of the Neoproterozoic Pan-African Damara Orogen. Deposit types include late- to post-tectonic (~ 523 – 506 Ma) LCT (Li-Be, Sn-, and miarolitic gem-tourmalinebearing) pegmatites, and uraniferous pegmatitic sheeted leucogranites (SLGs), which have an NYF affinity. Fluid inclusion studies reveal that although mineralization differs between the different types of pegmatites located at different geographic locations, and by extension, different stratigraphic levels, the fluid inclusion assemblages present in these pegmatites are similar; thus different types of pegmatites are indistinguishable from each other based on their fluid inclusion assemblages. Thorough fluid inclusion petrography indicated that although fluid inclusions are abundant in the pegmatites, no primary fluid inclusions could be identified, and rather those studied are pseudosecondary and secondary. Fluid inclusions are aqueo-carbonic (± NaCl), carbonic, and aqueous. It is proposed that all of the pegmatites studied share a similar late-stage evolution, with fluids becoming less carbonic and less saline with the progression of crystallisation. Oxygen isotope ratios allow the discrimination of different pegmatites into two groups, Group A (Sn-, Li-Sn-, and gem-tourmaline-bearing LCT pegmatites), and Group B (Li-Bebearing LCT, and U-bearing NYF pegmatites). Group A pegmatites have O-isotope ratios ranging from 11 to 13 ‰ suggesting that they have an I-type affinity. These values are, however, elevated above those of typical I-type granites (7 - 9 ‰), indicating either a postemplacement low-temperature exchange with meteoric fluid, high-temperature hydrothermal exchange with δ18O country rocks during emplacement, or the derivation of these pegmatites from a non-pelitic/S-type metaigneous source. Group B pegmatites have higher δ18O ratios (δ18O = 15 - 16 ‰), indicative of their S-type affinity, and their derivation from metapelitic source rocks. δD values of all the pegmatites range from -40 ‰ to -90 ‰ indicating that the pegmatitic fluids are primary magmatic with a metamorphic fluid component. Trends in the trace element concentrations of both Group A and Group B pegmatites are very similar to each other, making the two groups indistinguishable from each other on this basis. The Damaran pegmatites also share similar geochemical trends with their country rocks. There is, however, no direct field evidence to suggest that the pegmatites were derived from the in situ anatexis of the country rocks. It is more likely that anatexis occurred some distance away from where the pegmatites were ultimately emplaced, and that the melts migrated and were finally emplaced in pre-existing structures, possibly formed during Damaran deformation. O-isotope and Ti-in-quartz geothermometry indicate that Damaran pegmatites can be subdivided into two groups based on their crystallisation temperatures. LCT pegmatites crystallised at temperatures ranging from ~ 450 - 550 ºC, while the NYF pegmatites crystallised at higher temperatures, ranging from 630 - 670 ºC. It is important to note that the subdivision of pegmatites in Groups A and B based on their O-isotope systematics does not correspond with their subdivision into the LCT and NYF pegmatite families according to their crystallisation temperatures. In addition to clarifying aspects of the emplacement and evolution of the Damaran pegmatites, this study points out that there are several discrepancies in the current classification schemes of pegmatites. It shows that in addition to the problems encountered when trying to distinguish between LCT and NYF pegmatites based on their mineralogy, they also cannot truly be distinguished from each other using their geochemical and isotopic characteristics, or their tectonic settings. It is tentatively proposed that crystallisation temperature be considered as an alternative or additional characteristic in the classification of pegmatites, and that it be considered on a regional scale rather than only in the evaluation of the highly evolved end-members of a pegmatite swarm.

MSc., Faculty of Science, University of the Witwatersrand, 2011 / Granitoid intrusions are numerous in southwestern Rajasthan and are useful because they can provide geochronological constraints on tectonic activity and geodynamic conditions operating as the time of intrusion, as well as information about deeper crustal sources. The particularly voluminous Neoproterozoic felsic magmatism in the Sirohi region of Rajasthan is of particular interest as it may have implications for supercontinental (Rodinia and Gondwana) geometry. The Mt. Abu granitoid pluton is located between two major felsic suites, the older (~870-800 Ma) Erinpura granite and the younger (~751-771 Ma) Malani Igneous Suite (MIS). The Erinpura granite is syn- to lateorogenic and formed during the Delhi orogeny, while the MIS is classified as alkaline, anorogenic and either rift- or plume-related. This tectonic setting is contentious, as recent authors have proposed formation within an Andean-type arc setting. The Mt. Abu granitoid pluton has been mapped as partly Erinpura (deformed textural variant) and partly younger MIS (undeformed massive pink granite). As the tectonic settings of the two terranes are not compatible, confusion arises as to the classification of the Mt. Abu granitoid pluton. Poorly-constrained Rb-Sr age dating place the age of formation anywhere between 735 ± 15 and 800 ± 50 Ma. The older age is taken as evidence that the Mt. Abu intrusion was either a late phase of the Erinpura granite. However, U-Pb zircon geochronology clearly indicates that the Mt. Abu felsic pluton is not related to- or contiguous with- the Erinpura granite suite. The major results from this study indicate that the all textural variants within the Mt. Abu pluton were formed coevally at ~765 Ma. Samples of massive pink granite, mafic-foliated granite and augen gneiss from the pluton were dated using U-Pb zircon ID-TIMS at 766.0 ± 4.3 Ma, 763.2 ± 2.7 Ma and 767.7 ± 2.3 Ma, respectively. The simple Mt. Abu pluton is considered as an enriched intermediate I- to A-type intrusion. They are not anorogenic A-types, as, although these felsic rocks have high overall alkali and incompatible element enrichment, no phase in the Mt. Abu pluton contains alkali rich amphibole or pyroxene, nor do REE diagrams for the most enriched samples show the gull-wing shape typical of highly evolved alkaline phases. The alkali-enriched magma may be explained by partial melting of a crustal source such as the high-K metaigneous (andesite) one suggested by Roberts & Clemens (1993), not derivation from a mantle-derived mafic magma. The fairly restricted composition of Mt. Abu granitoids suggests that partial melting and a degree of assimilation/mixing may have been the major factors affecting the evolution of this granitoid pluton; fractional crystallization was not the major control on evolution of these granitoids. Revdar Rd. granitoids that are similar in outcrop appearance and petrography to Mt. Abu granitoids also conform to Mt. Abu granitoids geochemically and are classified as part of the Mt. Abu felsic pluton. Mt. Abu samples from this study have a maximum age range of 760.5-770 Ma, placing the Mt. Abu pluton within the time limits of the Malani Igneous Suite (MIS) as well as ~750 Ma granitoids from the Seychelles. Ages of the Sindreth-Punagarh Groups are also similar. These mafic-ultramafic volcanics are thought to be remnants of an ophiolitic mélange within a back-arc basin setting at ~750-770 Ma. The three Indian terranes are spatially and temporally contiguous. The same contiguity in space and time has been demonstrated by robust paleomagnetic data for the Seychelles and MIS. These similarities imply formation within a common geological event, the proposed Andean-type arc (Ashwal et al., 2002) on the western outboard of Rodinia. The implications are that peninsular India did not become a coherent entity until after this Neoproterozoic magmatism; Rodinia was not a static supercontinent that was completely amalgamated by 750 Ma, as subduction was occurring here simultaneous with rifting elsewhere. Pageiv The Mt. Abu pluton has undergone deformation, with much of the pluton having foliated or augen gneiss textures. The timing of some of the deformation, particularly the augen gneiss and shear zone deformation, is thought to have occurred during intrusion. The Mt. Abu and Erinpura granitoids have experienced a common regional metamorphic event, as hornblende (Mt. Abu) and biotite (Erinpura) give 40Ar/39Ar ages of 508.7 ± 4.4 Ma and 515.7 ± 4.5 Ma, respectively. This event may have reactivated older deformatory trends as well. The temperature of resetting of argon in hornblende coincides with temperatures experienced during upper-greenschist to lower-amphibolite facies metamorphism. These late Pan-African ages are the first such ages reported for the Sirohi region and southern part of the Aravalli mountain range. They offer evidence for the extension of Pan-African amalgamation tectonics (evidence from southern India) into NW India. The age of formation of the Erinpura augen gneiss magma is 880.5 ± 2.1 Ma, thus placing the Erinpura granitoids within the age limits of the Delhi orogeny (~900-800 Ma; Bhushan, 1995). Most deformation observed here would have been caused by compression during intrusion. The Erinpura granitoids are S-type granitoids due to their predominantly peraluminous nature, restricted SiO2-content, normative corundum and the presence of Al-rich muscovite and sillimanite in the mode. Weathered argillaceous metasedimentary material may also have been incorporated in this magma, while the presence of inherited cores suggests relatively lower temperatures of formation for these granitoids as compared to the Mt. Abu granitoids. The age of inheritance (1971 ± 23 Ma) in the Erinpura augen gneiss is taken as the age of the source component, which coincides with Aravalli SG formation. The Sumerpur granitoids differ from the Erinpura granitoids in terms of macroscopic and microscopic texture (undeformed, rarely megaporphyritic) but conform geochemically to the Erinpura granitoid characteristics and may thus be related to the Erinpura granitoid suite.The Revdar Rd. granitoids that are similar in macroscopic appearance to Erinpura granitoids also conform geochemically, and may similarly belong to the Erinpura granite suite. A Revdar Rd. mylonite gneiss with the Erinpura granitoids’ geochemical signature was dated at ~841 Ma, which does not conform to the age of the type-locality Erinpura augen gneiss dated here, but later intrusion within the same event cannot be ruled out because of the uncertainty in the age data (~21 Ma). The presence of garnet in one Revdar Rd. (Erinpura-type) sample implies generation of these granitoids at depth and/or entrainment from the source, similar to the S-type Erinpura granitoids. The Ranakpur granitoids differ significantly from both the Erinpura and Mt. Abu intrusives due to their low SiO2-content and steep REE profiles (garnet present in the source magma); they are thought to have been generated under higher pressures from a more primitive source. The deeper pressure of generation is confirmed by the absence of a negative Eu-anomaly. The Ranakpur quartz syenite dated at 848.1 ± 7.1 Ma is younger by ~30 m.y. than the Erinpura augen gneiss. It is within the same time range as numerous other granitoids from this region as well as the Revdar Rd. granitoid dated in this study. The prevalence of 830- 840 Ma ages may indicate that a major tectonic event occurred at this time. The Ranakpur quartz syenite may have been generated near a subduction or collision zone, where thickened crust allows for magma generation at depth. The deeply developed Nb-anomaly in the spider diagram also implies a larger subduction component to the magma. The Swarupganj Rd. monzogranite is interpreted to have formed by high degrees of partial melting from a depleted crustal source and is dissimilar to other granitoids from this study. More sampling, geochemical and geochronological work needs to be done in order to characterize this intrusion. Pagev The Kishengarh nepheline syenite gneiss is situated in the North Delhi Fold Belt and is the oldest sample dated within this study. The deformation in this sample is due to arc- or continental- collision during a Grenvillian-type orogeny related to the amalgamation of the Rodinia supercontinent (and peninsular India), dated by the highly reset zircons at ~990 Ma. This is considered a DARC (deformed alkaline rock and carbonatite) and represents a suture zone (Leelanandam et al., 2006). The primary age of formation of this DARC is older than 1365 ± 99 Ma, which is the age of xenocrystic titanites from the sample. The granitoid rocks from this study area (Sirohi region) range widely in outcrop appearance, petrography and geochemistry. Granitoids from the Sirohi region dated in this study show a range of meaningful ages that represent geological events occurring at ~880 Ma, ~844 Ma, ~817 Ma, ~789 Ma, ~765 Ma and ~511 Ma. Granitoid magmatism (age of formation) in this region is predominantly Neoproterozoic, and the number of events associated with each granitoid intrusion as well as diverse tectonic settings implies a complexity in the South Delhi Fold Belt that is not matched by the conventional and simplified view of a progression from collision and orogeny during Grenvillian times (Rodinia formation), through late orogenic events, to anorogenic, within-plate (rift-related) alkaline magmatism during Rodinia dispersal. Instead, it is envisaged that convergence and subduction during the formation of Rodinia occurred at ~1 Ga (Kishengarh nepheline syenite deformation), with a transition to continental-continental collision at ~880-840 Ma (Erinpura and Ranakpur granitoids). This was then followed by far-field Mt. Abu and MIS magmatism, related to a renewed period of subduction at ~770 Ma. The last deformatory event to affect this region was that associated with the formation of Gondwana in the late Pan-African (~510 Ma).