An electrochemical sensor array can provide information about the spatial and temporal distribution of chemicals in liquid turbulent plumes. Planar laser induced fluorescence (PLIF) and amperometric sensor arrays were used to record signals from modulated chemical plumes released into a recirculating aquatic flume. Coherence analysis was applied to extract the frequency components contained in the sensor response. Effects due to release distance, modulation frequency, and array orientation were investigated. This study has demonstrated that frequency encoded information can be extracted from a turbulent chemical plume using an array of amperometric sensors with optimized three-dimensional geometry and tuning.

Thesis (Ph. D.)--University of Texas at Austin, 2009. / Title from PDF title page (University of Texas Digital Repository, viewed on Sept. 9, 2009). Vita. Includes bibliographical references.

The rectangular pulsed plasma thruster (PPT) is an electromagnetic thruster that ablates Teflon propellant to produce thrust in a discharge that lasts 5-20 microseconds. In order to integrate PPTs onto spacecraft, it is necessary to investigate possible thruster plume-spacecraft interactions. The PPT plume consists of neutral and charged particles from the ablation of the Teflon fuel bar as well as electrode materials. In this thesis a novel application of quadruple Langmuir probes is implemented in the PPT plume to obtain electron temperature, electron density, and ion speed ratio measurements (ion speed divided by most probable thermal speed). The pulsed plasma thruster used is a NASA Glenn laboratory model based on the LES 8/9 series of PPTs, and is similar in design to the Earth Observing-1 satellite PPT. At the 20 J discharge energy level, the thruster ablates 26.6 mg of Teflon, creating an impulse bit of 256 mN-s with a specific impulse of 986 s. The quadruple probes were operated in the so-called current mode, eliminating the need to make voltage measurements. The current collection to the parallel to the flow electrodes is based on Laframboise's theory for probe to Debye length ratios between 5 and 100, and on the thin-sheath theory for ratios above 100. The ion current to the perpendicular probe is based on a model by Kanal and is a function of the ion speed ratio, the applied non-dimensional potential and the collection area. A formal error analysis is performed using the complete set of nonlinear current collection equations. The quadruple Langmuir probes were mounted on a computer controlled motion system that allowed movement in the radial direction, and the thruster was mounted on a motion system that allowed angular variation. Measurements were taken at 10, 15 and 20 cm form the Teflon fuel bar face, at angles up to 40 degrees off of the centerline axis at discharge energy levels of 5, 20, and 40 J. All data points are based on an average of four PPT pulses. Data analysis shows the temporal and spatial variation in the plume. Electron temperatures show two peaks during the length of the pulse, a trend most evident during the 20 J and 40 J discharge energies at 10 cm from the surface of the Teflon fuel bar. The electron temperatures after the initial high temperature peak are below 2 eV. Electron densities are highest near the thruster exit plane. At 10 cm from the Teflon surface, maximum electron densities are 1.04e20 ± 2.8e19 m-3, 9.8e20 ± 2.3e20 m-3, and 1.38e21 ± 4.05e20 m-3 for the 5 J, 20 J and 40 J discharge energy, respectively. The electrons densities decrease to 2.8x1019 ± 8.9e18 m-3, 1.2e20 ± 4.2e19 m-3, and 4.5e20 ± 1.2e20 m-3 at 20 cm for the 5 J, 20 J, and 40 J cases, respectively. Electron temperature and density decrease with increasing angle away from the centerline, and with increasing downstream distance. The plume is more symmetric in the parallel plane than in the perpendicular plane. Ion speed ratios are lowest near the thruster exit, increase with increasing downstream distance, but do not show any consistent angular variation. Peak speed ratios at a radial distance of 10 cm are 5.9±3.6, 5.3±0.39, and 4.8±0.41 for the 5 J, 20 J and 40 J discharge energies, respectively. The ratios increase to 6.05±5.9, 7.5±1.6, and 6.09±0.72 at a radial distance of 20 cm. Estimates of ion velocities show peak values between 36 km/s to 40 km/s, 26 km/s to 30 km/s, and 26 km/s to 36 km/s for the % J, 20 J, and 40 J discharge energies, respectively.

Thesis (S.M.)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2003. / In title on t.p., "[Beta]" appears as the Greek letter. / Includes bibliographical references (p. 81-84). / by Shinichiro Kida. / S.M.

Turbulent mixing enhancement has received a great deal of attention in the fluid mechanics community in the last few decades. Generally speaking, mixing enhancement involves the increased dispersion of the fluid that makes up a flow. The current work focuses on mixing enhancement of an axisymmetric jet via high amplitude fluidic pulses applied at the nozzle exit with high aspect ratio actuator nozzles. The work consists of small scale clean jet experiments, small scale micro-turbine engine experiments, and full scale laboratory simulated core exhaust experiments using actuators designed to fit within the engine nacelle of a full scale aircraft. The small scale clean jet experiments show that mixing enhancement compared to the unforced case is likely due to a combination of mechanisms. The first mechanism is the growth of shear layer instabilities, similar to that which occurs with an acoustically excited jet except that, in this case, the forcing is highly nonlinear. The result of the instability is a frequency bucket with an optimal forcing frequency. The second mechanism is the generation of counter rotating vortex pairs similar to those generated by mechanical tabs. The penetration depth determines the extent to which this mechanism acts. The importance of this mechanism is therefore a function of the pulsing amplitude. The key mixing parameters were found to be the actuator to jet momentum ratio (amplitude) and the pulsing frequency, where the optimal frequency depends on the amplitude. The importance of phase, offset, duty cycle, and geometric configuration were also explored. The experiments on the jet engine and full scale simulated core nozzle demonstrated that pulse fluidic mixing enhancement was effective on realistic flows. The same parameters that were important for the cleaner small scale experiments were found to be important for the more realistic cases as well. This suggests that the same mixing mechanisms are at work. Additional work was done to optimize, in real time, mixing on the small jet engine using an evolution strategy.

Thesis (Ph. D.)--Joint Program in Oceanography (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 1988. / Includes bibliographical references (p. 145-152). / by Sarah Alden Little. / Ph.D.

The analysis and modeling of the coastal farfield behavior of inlet discharge plumes is the key to understanding the fate of pollutants discharged into the ocean. These plumes disperse in chaotic and unpredictable patterns. Theoretical models are based on the average conditions and calibrated to the results of tracer studies. Data and models for freshwater discharges in coastal ocean systems are limited because of the lack of adequate tracers. On February, 2007, a tracer study was conducted on the Boynton Inlet, Florida, using sulfur hexafluoride (SF6) tracer. The objective of this study is to provide methods of analysis for the sample data collected during the experiment. The detected tracer concentrated in a bolus that migrated north of the inlet at velocities lower than predicted by the current data. The plume was successfully modeled with a Gaussian plume model, with 90% of the SF6 predictions having less than 4.6 pptr error. / by Joaquin Pire-Schmidt. / Thesis (M.S.C.S.)--Florida Atlantic University, 2009. / Includes bibliography. / Electronic reproduction. Boca Raton, Fla., 2009. Mode of access: World Wide Web.

This study involves the modeling of small cold-gas (N2) thrusters nozzle and plume flows, their interactions with spacecraft surfaces and the induced pressure environment. These small cold-gas thrusters were used for pitch, yaw and roll control and were mounted on the bottom of the conical Environmental Monitor Payload (EMP) suborbital spacecraft. The pitch and yaw thrusters had 0.906 mm throat diameter and 4.826 mm exit diameter, while the roll thrusters had 1.6 mm throat diameter and 5.882 mm exit diameter. During thruster firing, at altitudes between 670 km and 1200 km, pressure measurements exhibited non-periodic pulses (Gatsonis et al., 1999). The pressure sensor was located inside the EMP and was connected to it's sidewall with a 0.1-m long, 0.022-m diameter tube and the pressure pulses appeared instantaneously with the firings for thrusters without a direct line-of-sight with the sensor entrance. Preliminary analysis showed that the plume of these small EMP thrusters undergoes transition from continuous to rarefied. Therefore, nozzle and plume simulations are performed using a combination of Navier-Stokes and Direct Simulation Monte Carlo codes. This study presents first a validation of the Navier-Stokes code Rampant used for the continuous EMP nozzle and plume simulations. The first Rampant validation example involves a two-dimensional axisymetric freejet expansion and is used to demonstrate the use of Bird's breakdown parameter. Results are compared favorably with those of Bird (1980) obtained through the method of characteristics. The second validation example involves three-dimensional plume simulations of a NASA thruster. This nitrogen nozzle has a throat diameter of 3.18 mm, an exit diameter of 31.8 mm, half-angle of 20 degrees, stagnation temperature of 699 K, stagnation pressure of 6,400 Pa. Simulation results are compared favorably with previous Navier-Stokes and Direct Simulation Monte Carlo numerical work. The third validation example involves three-dimensional simulations of Rothe's (1970) nozzle that has a throat diameter of 2.5 mm, an exit diameter of 20.3 mm, half-angle of 20 degrees, operating at stagnation temperature of 300 K and pressure of 1975 Pa. Numerical results also compared favorably to experimental data. The combined Navier-Stokes/DSMC approach and the EMP simulation results are presented and discussed. The continuous part of the EMP nozzle and plume flow is modeled using the three-dimensional Navier-Stokes Rampant code. The Navier-Stokes domain includes the geometry of the nozzle and the EMP base until transition of the continuous flow established by Bird's breakdown parameter. The rarefied part of the plume flow is modeled using the Direct Simulation Monte Carlo code DAC. Flowfield data obtained inside the breakdown surface from the Navier-Stokes simulation are used as inputs to the DSMC simulations. The DSMC domain includes the input surface and the EMP spacecraft geometry. The combined Navier-Stokes/DSMC simulations show the complex structure of the plume flow as it expands over the EMP surfaces. Plume reflection and backflow are demonstrated. The study also summarizes findings presented by Gatsonis et al. (2000), where the DSMC predictions at the entrance of the pressure sensor are used as inputs to a semi-analytical model to predict the pressure inside the sensor. It is shown that the pressure predictions for the pitch/yaw thrusters are close to the measurements. The plume of a pitch or yaw thruster reaches the pressure sensor after expanding on the EMP base. The pressure predicted for the roll thruster is larger that the measured. This is attributed to the uncertainty in the roll thruster location on the EMP base resulting, in the simulation, in a component of direct flow to the sensor.

[Truncated abstract] To date, many subsurface contaminant modelling studies have focused on increasing model complexity and measurement requirements to improve model accuracy and widen model application. However, due to the highly complex and heterogeneous nature of flow in the subsurface, the greater benefit in model development may lie in decreasing complexity by identifying key processes and parameters, simplifying the relationships that exist between them, and incorporating these relationships into simple models that recognise or quantify the inherent complexity and uncertainty. To address this need, this study aims to identify and isolate the key processes and parameters that control dense nonaqueous phase liquid (DNAPL) and aqueous phase migration through single, onedimensional fractures. This is a theoretical representation which allows the study of processes through conceptual and mathematical models. Fracture systems typically consist of multiple two-dimensional fractures in a three-dimensional network; however, these systems are computationally and conceptually demanding to investigate and were outside of the scope of this study. This work initially focuses on DNAPL migration in single, one-dimensional fractures. The similitude techniques of dimensional and inspectional analysis are performed to simplify the system and to develop breakthrough time scale factors. This approach relies heavily on the limitations of the equation used for the analysis and on the difficulty in representing variable aperture scenarios. The complexity of the conceptual model is then increased by embedding the fracture in a two-dimensional, porous matrix. ... These tools can be readily applied by the field investigator or computer modeller to make order-of-magnitude estimates of breakthrough times, reduce or target measurement requirements, and lessen the need to employ numerical multiphase flow models. To determine the implications of the results found in the one-dimensional studies to applications at the field scale, the complexity of the conceptual model was increased to a single, two-dimensional, planar fracture embedded in a three-dimensional porous matrix. The focus of this study was not DNAPL breakthrough times but the relative importance and interaction of different mass transport processes and parameters on plume migration and evolution. Observations clearly show that estimates of the size, location and concentration of the plume is highly dependent on the geologic media, the temporal and spatial location and resolution of measurements, and on the history, mass and location of the DNAPL source. In addition, the processes controlling mass transport (especially matrix diffusion and back diffusion) act in combination at the field scale in ways not always expected from an analysis of processes acting individually at smaller spatial and temporal scales. Serious concerns over the application of the common '1% Rule of Thumb' to predict DNAPL presence and the use of remediation efforts that rely largely on natural attenuation are raised. These findings have major implications for the field worker and computer modeller, and any characterisation, monitoring or remediation program development needs to be sensitive to these findings.

M.Phil. (Energy Studies) / Southern Africa is a major source of regional aerosols and trace gases from biomass burning, and this creates a need for experimental validation and systematics of the magnitude and frequency of aerosol transport episodes affecting the atmosphere of the region. This study links surface measurements of biomass burning atmospheric aerosols and trace gases with air mass trajectory analysis to determine transport pathways for periods of high and low concentrations. The hypothesis of this study is that from chemical signatures of trace gases and aerosols, as well as trajectory analyses, it is possible to identify sources of these emissions from industrial, traffic, marine and biomass burning activities. Consequently, frequencies, durations, intensities and seasonal variations of trace gases can be established. The study aims to interpret the long-term atmospheric monitoring record from a remote monitoring station at Botsalano (North West Province, South Africa) to determine the origin, frequencies, durations, intensities and seasonal occurrences of aerosol/haze episodes influencing the atmosphere of southern Africa. A suite of trace gas analysers and a Differential Mobility Particle Sizer (DMPS®) were used to measure ground level trace gas and aerosol quantities. MATLAB® scripts were used in performing quality assurance and processing to provide a working set of data from which different fire periods could be selected. Fire signatures, based on excess CO above average tropospheric levels and episodes of enhanced particulate matter concentrations in the 10 to 200 nm range, were identified using MATLAB® scripts and Excel®. Altogether 36 plumes were accepted as biomass burning plumes. Twenty-nine fire plumes had weak signals with excess CO ratios ranging between 0.07 and 0.32; seven plumes had strong signals ranging between 0.41 and 0.64. The occurrence of identified biomass burning plumes was high in the dry season from May to October (83%) and low (17%) during the wet season from November to April. Four pathways were identified for the long-range transportation of biomass burning aerosols to the site: easterly, south-westerly, re-circulation and northerly modes, with occurrence frequencies of 39%, 31%, 22% and 8%, respectively. Anti-cyclonic circulation was observed over southern Africa and was evident in the re-circulation and Indian Ocean slow modes. CO and Aitken-mode aerosol number intensities were generally larger for fire emissions arriving in the easterly and south-westerly air masses when compared with those arriving in re-circulation and northerly air masses. Easterly and south-westerly flows were dominated by Aitken-mode aerosol, whereas accumulation mode particles dominated in the re-circulation and northerly modes. Consequently, easterly and south-westerly flows transported emissions from young/fresh fire plumes, with source regions probably close to Botsalano. Re-circulation and northerly flows were responsible for transport of rather aged plumes from more distant regional fires. Based on forward trajectories, this study revealed that the 2006/2007 measurement period exhibited transport features of a La Niña ENSO during which transport of biomass v burning aerosols towards the south in the Indian Ocean slow and Indian Ocean fast modes was most frequent. This study is significant in that it complements earlier studies of regional aerosol transport over the sub-continent and adds to the understanding of the regional scale generation and transport of trace substances through the atmosphere. Furthermore, the study combines a technique for identifying enhanced CO concentrations as a unique identifier of large scale biomass combustion events with the use of the Aitken-mode particle number densities and size distributions. This technique reveals aspects of aerosol growth dynamics through the changing size distributions, thereby adding fresh insights normally not available through conventional particle volume/mass concentrations measurements.