To support the continuously increasing number of mobile telephone users around the world, mobile communication systems have become more advanced and sophisticated in their designs. As a result of the great success with the second generation mobile radio networks, deployment of the third and development of fourth generations, the demand for higher data rates to support available services, such as internet connection, video telephony and personal navigation systems, is ever growing. To be able to meet the requirements regarding bandwidth and number of users, enhancements of existing systems and introductions of conceptually new technologies and techniques have been researched and developed. Although new proposed technologies in theory provide increased network capacity, the backbone of a successful roll-out of a mobile telephone system is inevitably the planning of the network’s cellular structure. Hence, the fundamental aspect to a reliable cellular planning is the knowledge about the physical radio channel for wide sets of different propagation scenarios. Therefore, to study radio wave propagation in typical Australian environments, the Commonwealth Scientific and Industrial Research Organisation (CSIRO) and the Australian Telecommunications Cooperative Research Centre (ATcrc) in collaboration developed a cellular code division multiple access (CDMA) pilot scanner. The pilot scanner measurement equipment enables for radio wave propagation measurements in available commercial CDMA mobile radio networks, which in Australia are usually deployed for extensive rural areas. Over time, the collected measurement data has been used to characterise many different types of mobile radio environments and some of the results are presented in this thesis. The thesis is divided into an introduction section and four parts based on peer-reviewed international research publications. The introduction section presents the reader with some relevant background on channel and propagation modelling. Also, the CDMA scanner measurement system that was developed in parallel with the research results founding this thesis is presented. The first part presents work on the evaluation and development of the different revisions of the Recommendation ITU-R P.1546 point-to-area radio wave propagation prediction model. In particular, the modified application of the terrain clearance angle (TCA) and the calculation method of the effective antenna height are scrutinized. In the second part, the correlation between the smallscale fading characteristics, described by the Ricean K-factor, and the vegetation density in the vicinity of the mobile receiving antenna is investigated. The third part presents an artificial neural network (ANN) based technique incorporated to predict path loss in rural macrocell environments. Obtained results, such as prediction accuracy and training time, are presented for different sized ANNs and different training approaches. Finally, the fourth part proposes an extension of the path loss ANN enabling the model to also predict small-scale fading characteristics.