Freestanding self-written polymer waveguides were fabricated between two single mode fibres by using free radical photopolymerization technique. Photo curing enables modification of the initial liquid monomer at the illuminated part of the photopolymerizable system to form a permanent solid polymer waveguide between the cores of the fibres. Three compound acrylate based monomer (PETA) and Norland optical adhesives (NOA) were used to fabricate polymer bridges. The two systems are cured by visible and UV respectively. The optical, mechanical and nonlinearity properties of freestanding self-written polymer waveguides were investigated. Polymer waveguides up to 600 μm long between two fibres were fabricated by unidirectional illumination. The optical power required for photopolymerization is sufficiently low that it is possible to use incoherent light source instead of laser, which also allows investigation of the optical transmission over a wide range of wavelengths from visible to NIR. Optical characterization showed that PETA waveguides have better optical transmission and insertion loss of about 1.2 dB was measured for the bridges up to 600 μm long at 1550nm. Some limitations prevented us to extend waveguide’s length beyond 600 μm, the bridges also showed poor adhesion quality particularly at the polymer/fibre interfaces which needed an action. In order to improve mechanical properties of polymer waveguides also to overcome bonding failure between fibre and polymer, the fibres were treated with adhesion promoter. The treatment together with bidirectional curing from both fibres improved mechanical and optical properties of the polymer waveguides. The insertion loss was reduced to 0.6 dB associated with bi-directionally cured 600 μm long waveguide. Nonlinear response of polymer waveguides was measured by coupling a high power ultra short pulse laser. Using bidirectional curing and inserting fibre ends into capillaries millimeter long waveguides with minimum loss of 1.1dB were fabricated. A long interaction length of polymer waveguide allows spectral broadening and self-phase modulation features to occur in response to the high power laser propagation through the polymer bridge. The spectral broadening in polymer waveguide was much broader than that of 1.5m plain fibre. The comparison of the results associated with maximum phase shift occurs in polymer with plain fibre revealed that the nonlinear coefficient of polymer material is about 1000 times larger than that of silica fibre.

In this dissertation, the development of an experimental prototype for on-board optical-to-electrical signal broadcasting at 10 Gb/s per channel over an interconnect distance of 10 cm was presented. The optical distribution network was implemented using a polymer-based 1-by-4 multimode interference (MMI) splitter with linearly tapered output facet. A 1-by-8 MMI splitter with input/output waveguides of 10 microns in width was first fabricated using standard photolithography and characterized at 40 Gb/s in NRZ format and PRBS = 2^7-1. The pulse response of MMI devices was further quantified from the time-dependent, pulse-modulated field propagation perspective incorporated with various dispersion mechanisms. The results predict their operating limitations and investigate why and how such devices become non-functional in the ultrashort-pulse limit that is far beyond the most present-day optical systems. The guided-mode attenuation associated with polymer waveguides fabricated on FR-4 printed-circuit boards was also investigated for the first time. The rigorous transmission-line network approach was applied and the FR-4 substrate was treated as a long-period substrate grating with rectangular corrugations. The peaks of attenuation were shown to occur near the Bragg conditions that were recognized as the leaky-wave stop bands. As the buffer layer thickness increases, the attenuation becomes negligibly small that is attributed to the weak grating-induced perturbation to the mode behavior. The prototype was then developed on the basis of both experimental verifications to the devices and theoretical investigations. An improved 1-by-4 MMI splitter at 1550 nm with linearly tapered output facet was heterogeneously integrated with four p-i-n photodetectors (PDs) on a silicon (Si) bench. The Si bench itself was then hybrid integrated onto an FR-4 printed-circuit board with four receiver channels composed of transimpedance amplifiers, limiting amplifiers, and surface-mounted components. The innovative integration approach demonstrated the simultaneous alignment between multiple waveguides and multiple PDs during the MMI fabrication process that is a complete radical departure from the conventional assembly method inherent from the telecommunication industry. The entire system was fully functional at 10 Gb/s per channel.

Polymeric waveguide-on-flex has the potential to replace complex and costly light-turning devices in optoelectronic applications. As light signals are propagated and confined through the definition of core-cladding interface, the light guiding structure is required to adhere well and ensure long term interfacial stability. This thesis addresses the gap that has emerged in the fundamental material issues such as the polymeric optical waveguide materials deposited on the flexible substrates. In addition, this thesis investigates the feasibility of a new approach using electrostatic-induced lithography in micro-patterning of polymer, in optical waveguide fabrication. Plasma treatment is applied to enhance interfacial adhesion between flex substrates and optical cladding layers. The modified flex surfaces of polyimide KaptonHNTM and liquid crystal polymer VecstarTM materials are characterised. In addition, sonochemical surface treatment is evaluated on these flexible substrates. ToF-SIMS depth profiling has confirmed the interface reaction mechanisms where it has shown that plasma treatment increases the interfacial interpenetration. The larger interfacial width increases the possible entanglement mechanism between the polymer chains. These results, together with the double cantilever beam testing, indicate the strengthening of the polymeric interface upon plasma treatment, which is essential for long term optical and mechanical stability of waveguide-on-flex applications. A new method of micro-pattering of polymer material has been adopted for fabricating multimode waveguide-on-flex. The method, using an electrostatic-induced lithography, is developed to produce 50 μm x 50 μm arrays of polysiloxane LightlinkTM waveguide on flex. This thesis looks at various process recipes of the technique and reports the pattern formation of polymeric optical core. By adjusting the spin-coated liquid core thickness, pre-bake condition, UV exposure and applied voltage, the aspect ratio and profile of the optical core microstructure can be varied. As the electrostatic pressure overcoming the surface tension of spin-coated waveguide material induces the optical core formation, the core structure is smooth, making it ideal for low scattering loss waveguide. The propagation loss of fabricated waveguide is measured at 1.97 dB/cm at 850 nm wavelength. The result shows that the use of electrostatic-induced lithography in optical polymer is a promising approach for low cost and low temperature (<150 °C) processing at back end optical-electrical integrated circuitry assembly.

Polymer waveguides present a potentially low cost alternative to electronics in communication systems. Polymers offer relatively straightforward and economical fabrication when compared to conventional materials. In this study, a fabrication process for Bragg gratings in polymer waveguides was developed. Waveguides were designed using finite-element analysis, patterned via e-beam lithography, and a detailed fabrication method was developed. Surface-Plasmon Resonance (SPR) is a widely accepted method for biological and chemical sensing. Measurement of bulk refractive index changes and specific surface binding is a crucial part in any biosensing. Design and fabrication of a novel self-referencing SPR sensor is described and its functionality is tested.

<p>The resonance of surface plasmons on metal nanoparticles can be excited at visible wavelengths. The extraordinary enhancement of a variety of optical phenomena in the vicinity of metal nanoparticles has been attributed to the strong fields generated under resonance conditions. As a result, extensive research has been carried out to incorporate the extraordinary optical properties of metal nanoparticles into optical devices and applications, ranging from spectroscopy (e.g, surface enhanced Raman, IR and Fluorescence), optical sensing and imaging, to photovoltaic cells, photonic crystals and optical switches. Particular effort has been directed towards producing stable dispersion of metal nanoparticles within soft dielectric matrices and their subsequent construction into different device geometries.</p> <p>This thesis describes a method to photolytically generate Ag nanoparticles within organosiloxane sols, which can subsequently be photopolymerized in the presence of photoinitiators and therefore, be patterned through a variety of photo-inscription processes. The mechanism of Ag nanoparticle growth and evolution is described in detail followed by the fabrication of periodic metallodielectric gratings through photomask and laser interference lithography. Studies also showed that three different forms of nonlinear light propagation, optical self-trapping, modulation instability and spatial self-phase modulation could be elicited in the Ag nanoparticle-doped systems. Detailed experimental examination of these phenomena elucidated significant differences in their dynamics in the metallodielectric systems compared to non-doped samples. These included variations in the dynamics of self-trapped beams such as the excitation of optical modes, critical thresholds for modulation instability and self-phase modulation. The potential of these nonlinear processes for the self-inscription of 3-D metallodielectric structures including cylindrical multimode waveguides and waveguide lattices has also been studied.</p> / Doctor of Philosophy (PhD)

Due to their inherent BW capacity, optical interconnect (OI) offers a means of replacement to BW limited copper as bottlenecks begin to appear within the various interconnect levels of electronics systems. Low-cost optically enabled printed circuit boards are a key milestone on many electronics roadmaps, e.g. iNEMI. Current OI solutions found in industry are based upon optical fibres and are capable of providing a suitable platform for inter-board applications especially on the backplane. However, to allow component assembly onto high BW interconnects, an integral requirement for intra-board applications, optically enabled printed circuit boards containing waveguides are essential. Major barriers to the deployment of optical printed circuit boards include the compatibility of the technique, the cost of acquiring OI and the optical power budget. The purpose of this PhD research programme is to explore suitable techniques to address these barriers, primarily by means of laser material processing using UV and IR source lasers namely 248 nm KrF Excimer, 355 nm UV Nd:YAG and 10.6 μm IR CO2. The use of these three main lasers, the trio of which dominates most PCB production assembly, provides underpinning drive for the deployment of this technology into the industry at a very low cost without the need for any additional system or system modification. It further provides trade-offs among the suitable candidates in terms of processing speed, cost and quality of waveguides that could be achieved. This thesis presents the context of the research and the underlying governing science, i.e. theoretical analysis, involving laser-matter interactions. Experimental investigation of thermal (or pyrolitic) and bond-breaking (or photolytic) nature of laser ablation was studied in relation to each of the chosen lasers with regression analysis used to explain the experimental results. Optimal parameters necessary for achieving minimum Heat Affected Zone (HAZ) and surface/wall roughness were explored, both of which are key to achieving low loss waveguides. While photochemical dominance - a function of wavelength and pulse duration - is desired in laser ablation of photopolymers, the author has been able to find out that photothermallyprocessed materials, for example at 10.6 μm, can also provide desirable waveguides. Although there are literature information detailing the effect of certain parameters such as fluence, pulse repetition rate, pulse duration and wavelength among others, in relation to the etch rate of different materials, the machining of new materials requires new data to be obtained. In fact various models are available to try to explain the laser-matter interaction in a mathematical way, but these cannot be taken universally as they are deficient to general applications. For this reason, experimental optimisation appears to be the logical way forward at this stage of the research and thus requiring material-system characterisation to be conducted for each case thereby forming an integral achievement of this research. In this work, laser ablation of a single-layer optical polymer (Truemode™) multimode waveguides were successfully demonstrated using the aforementioned chosen lasers, thus providing opportunities for rapid deployment of OI to the PCB manufacturing industry. Truemode™ was chosen as it provides a very low absorption loss value < 0.04 dB/cm at 850 nm datacom wavelength used for VSR interconnections - a key to optical power budget - and its compatibility with current PCB fabrication processes. A wet-Truemode™ formulation was used which required that optical polymer layer on an FR4 substrate be formed using spin coating and then UV-cured in a nitrogen oxygen-free chamber. Layer thickness, chiefly influenced by spinning speed and duration, was studied in order to meet the optical layer thickness requirement for multimode (typically > 9 μm) waveguides. Two alternative polymers, namely polysiloxane-based photopolymer (OE4140 and OE 4141) from Dow Corning and PMMA, were sparingly utilized at some point in the research, mainly during laser machining using UV Nd:YAG and CO2 lasers. While Excimer laser was widely considered for polymer waveguide due to its high quality potential, the successful fabrication at 10.6 μm IR and 355 nm UV wavelengths and at relatively low propagation loss at datacom wavelength of 850 nm (estimated to be < 1.5 dB/cm) were unprecedented. The author considered further reduction in the optical loss by looking at the effect of fluence, power, pulse repetition rate, speed and optical density on the achievable propagation but found no direct relationship between these parameters; it is therefore concluded that process optimisation is the best practice. In addition, a novel in-plane 45-degree coupling mirror fabrication using Excimer laser ablation was demonstrated for the first time, which was considered to be vital for communication between chips (or other suitable components) at board-level.