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Development of an ozone scrubbing-activation process for odor control of fumes generated from recycled polypropylene fusion operationsZhong, Shi-yi 09 July 2009 (has links)
Since odor-complaint events have been increased year by year in Taiwan, odor control has become an important issue in the air pollution control field. Thus, this paper attempted to investigate if ¡§ozone scrubbing-activation carbon adsorption¡¨ is feasible for efficiently reducing the odor intensity of vented gas from recycled polypropylene (PP) fusion operations.
A pilot scrubber (0.17 m L ¡Ñ0.17 m W ¡Ñ1.2m H, packed with Intalox saddles to a total volume of around 0.018 m3) was used for the feasibility test. Odorous gases vented from the fusing operation kept at 200 ¢J in a temperature-controlled oven were used as the target waste gases. Results indicated that with operation conditions of VOCs (as methane) 10-40 ppm, an ozone concentration of 4.0 ppm in the influent gas, a liquid/gas (L/G) ratio of 0.030 L/m3 in the scrubber, and an empty bed retention time of around 9.7 s in the packed section, around 60% of the VOCs in the influent gas was removed. Most alkenes in the gas were converted into sweet-smell ketones in the ozonated gas. Vented gas from the scrubber was further treated by a granulated activated carbon (GAC) adsorption column with an EBRT of less than 1 s for the gas. An overall VOC removal of around 70% was observed for the full ozonation-GAC process. Only trace amounts of original fume-like and sweet-ketone smells were detected in the treated gases. A test indicated that the overall odor (expressed as the dilution to threshold D/T value) removal was around 70% and the D/T were 733, 309, and 232, respectively, for the influent, ozonation-scrubbing effluent, and GAC effluent. It was estimated that the cost is around NT$ 9.57 for treating 1,000 m3 of the teat gas by the system. Efforts should be made by decreasing the cost by other alternative technologies.
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