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DISTRIBUTION AND IMPACTS OF PETROLEUM HYDROCARBONS IN LOUISIANA TIDAL MARSH SEDIMENTS FOLLOWING THE DEEPWATER HORIZON OIL SPILLHatch, Rachel S 01 January 2013 (has links)
Following the 2010 Deepwater Horizon (DWH) spill, sediment cores were analyzed from marshes at various levels of oiling to determine how deeply oil penetrated sediment in these marsh environments, and if at these sites it had quantifiably affected benthic ecosystems. Minimum mixing depths were determined from penetration of the lithogenic radionuclide 234Th, which ranged from 0.25 to 4.5 cm. Sediment accumulation rates were determined using 210Pb, with verification from 137Cs in selected cores. Lead-210 profiles revealed long-term (decadal) mixing. Bay Jimmy, Louisiana was significantly affected by the DWH oil spill, as indicated by total polycyclic aromatic hydrocarbon concentrations of up to 21,913 ppb. This is far above the level at which adverse biological effects occur (4,022 ppb). Benthic foraminifera responded to the heavy oiling by decreases to standing stock and depth of habitation relative to unoiled sites, as well as exhibiting deformities. These data clearly show that oil can be quickly mixed into salt marsh sediments, with demonstrable impacts on indigenous benthos. Further, radioisotope inventories indicated that most of the sampled sites are in a net erosional state. Should marshes containing trapped DWH oil be submerged by rising sea level, there is a great potential for the remobilization of oil.
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U-Th-Ba Elemental Fractionation during Partial Melting of Crustal Xenoliths and its Implications for U-series Disequilibria in Continental Arc RocksBrens, Raul, Jr. 22 March 2011 (has links)
Understanding U-series isotopic disequilibria of partially melted crust is integral for determining the effect that crustal assimilation has on the U-series signature of magmas. In this work, U, Th and Ba (as a proxy for Ra) elemental abundances were gathered on the quenched glass in partially melted crustal xenoliths of granitic composition using microbeam techniques. The crustal xenoliths, which are found in basaltic lava, from Mirador Volcano in Chile, are old, and can be assumed to be at secular equilibrium, whereas melting occurred during eruption of Mirador in 1979. A comparison of the ratios Ba/Th and U/Th in the partial melts with those of the whole rock reveal how much fractionation has occurred during partial melting. Different ratios of U, Th and Ba compared to the whole rock substantiate fractionation via partial melting. Thus, assimilation of partial melts of crust can play a role in U-series isotopic disequilibria.
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