This study investigates the runoff process and groundwater behavior in a subarctic watershed called Wolf Creek Research Basin, in Whitehorse, Yukon Territory, Canada. This basin is underlain by discontinuous permafrost that is typical of high latitude watersheds. Goundwater supports the stream flow year round and dominated the hydrology in most of the study period as baseflow. The baseflow was concentrated in dissolved ions. However, the baseflow was diluted during the melt season in May and June of 2012. Multiple chemical and isotopic tracers were used to develop a robust three-component (groundwater, soilwater and precipitation) mixing model for runoff generation. The concentrations of weathering ions decreased with the increased discharge during the melt. Soilwater was responsible for about 60% of the streamwater on the hydrograph in the melt season. The infiltration of the meltwater from the snowpack and the thawed water from the seasonal frost to the baseflow existed. The tritium concentrations indicated that there was fast moving hydrogeological system within the basin. The baseflow was also characterized as relatively enriched in both 13C and 14C, and concentrated in DIC. DIC was the major loss of carbon in Wolf Creek Research Basin.Le pergélisol est grandement sous-jacent dans les bassins-versants à haute latitude. Cette étude examine le processus de ruissellement et le comportement des eaux souterraines dans un bassin-versant subarctique de Wolf Creek, à Whitehorse, territoire du Yukon au Canada. Les eaux souterraines soutenaient l’écoulement fluvial et dominaient l’hydrographe comme débit de base durant la majorité de la période d’étude. Le débit de base était concentré d’ions dissipés. Par contre, le débit de base était dilué durant la saison des fontes au mois de mai et juin 2012. Plusieurs traceurs chimiques et isotopiques étaient utilisé afin de développer un modèle de trois composants (eau souterraine, eau interstitielle de sol et précipitation) de ruissellement. Les concentrations de la déségrégation des ions diminuaient avec l’augmentation du débit durant la fonte. Les eaux interstitielles des sols étaient responsables de 60% de l’eau de ruisseau sur l’hydrographe durant la saison de fontes. L’infiltration de l’eau de fonte du manteau neigeux et l’eau du gel du débit de base existaient. Les concentrations de tritium indiquent qu’il y avait un système hydrogéologique qui se déplaçait à grande vitesse dans les limites du bassin. Le débit de base était aussi caractérisé comme étant enrichi en 13C et 14C, avec des concentrations en carbone inorganique dissous.

This study investigates the runoff process and groundwater behavior in a subarctic watershed called Wolf Creek Research Basin, in Whitehorse, Yukon Territory, Canada. This basin is underlain by discontinuous permafrost that is typical of high latitude watersheds. Goundwater supports the stream flow year round and dominated the hydrology in most of the study period as baseflow. The baseflow was concentrated in dissolved ions. However, the baseflow was diluted during the melt season in May and June of 2012. Multiple chemical and isotopic tracers were used to develop a robust three-component (groundwater, soilwater and precipitation) mixing model for runoff generation. The concentrations of weathering ions decreased with the increased discharge during the melt. Soilwater was responsible for about 60% of the streamwater on the hydrograph in the melt season. The infiltration of the meltwater from the snowpack and the thawed water from the seasonal frost to the baseflow existed. The tritium concentrations indicated that there was fast moving hydrogeological system within the basin. The baseflow was also characterized as relatively enriched in both 13C and 14C, and concentrated in DIC. DIC was the major loss of carbon in Wolf Creek Research Basin.Le pergélisol est grandement sous-jacent dans les bassins-versants à haute latitude. Cette étude examine le processus de ruissellement et le comportement des eaux souterraines dans un bassin-versant subarctique de Wolf Creek, à Whitehorse, territoire du Yukon au Canada. Les eaux souterraines soutenaient l’écoulement fluvial et dominaient l’hydrographe comme débit de base durant la majorité de la période d’étude. Le débit de base était concentré d’ions dissipés. Par contre, le débit de base était dilué durant la saison des fontes au mois de mai et juin 2012. Plusieurs traceurs chimiques et isotopiques étaient utilisé afin de développer un modèle de trois composants (eau souterraine, eau interstitielle de sol et précipitation) de ruissellement. Les concentrations de la déségrégation des ions diminuaient avec l’augmentation du débit durant la fonte. Les eaux interstitielles des sols étaient responsables de 60% de l’eau de ruisseau sur l’hydrographe durant la saison de fontes. L’infiltration de l’eau de fonte du manteau neigeux et l’eau du gel du débit de base existaient. Les concentrations de tritium indiquent qu’il y avait un système hydrogéologique qui se déplaçait à grande vitesse dans les limites du bassin. Le débit de base était aussi caractérisé comme étant enrichi en 13C et 14C, avec des concentrations en carbone inorganique dissous.

The diploma thesis focuses on the analysis of rainfall-runoff processes and erosion characteristics of selected catchment in different landscape management. This analysis was solved at the Lukavecký brook catchment, which is located in the Pelhřimov district in Vysočina region. The theoretical part of the thesis describes the rainfall-runoff process and then focuses more on individual processes. It also characterizes water erosion, its consequences, forms and erosion control. At the end of the theoretical part are described methods of calculation of water runoff and water erosion. The practical part describes the catchment of the Lukavecký brook, its characteristics of natural conditions and the threat of water erosion. Then there is a procedure for processing of bases and data in the program ArcGIS. Subsequently, it includes an assessment of the different measures and changes in the type of land to drain water from the catchment and erosion threat.

An extensive investigation with parallel field andlaboratory exposures has been conducted to elucidateatmospheric corrosion and metal runoff processes on copper andzinc used for roofing applications. Detailed studies have beenperformed to disclose the effect of various parameters on therunoff rate including: surface inclination and orientation,natural patination (age), patina composition, rain duration andvolume, rain pH, and length of dry periods inbetween rainevents. Annual and average corrosion rates and runoff rateshave been determined consecutively during urban field exposuresin Stockholm on naturally patinated copper and zinc of varyingage and patina composition. The corrosion rate was found todecrease with time, amounting to 6.7 g Cu/(m2.y) and 5.0 gZn/(m2.y) after 48 weeks of exposure, whereas the runoff ratewas relatively constant with time on a yearly basis, being 1.3g/(m2.y) and 3.1 g/(m2.y) for copper and zinc, respectively.The annual runoff rate was found to be significantly lower thanthe corresponding corrosion rate for both copper and zinc.Somewhat higher runoff rates of copper were determined fromnaturally green-patinated copper (&gt;40 years old, 2.0g/(m2.y)) compared to brown-patinated copper (1 year old). Themain reasons are specific environmental conditions combinedwith characteristics of the patina layer, which increase themagnitude of dissolved species flushed from the surface duringthe first flush volume of a rain event. No intrinsic effect ofpanel age on the runoff rate was seen for naturally patinatedzinc. However, differences in prevailing environmentalconditions during the initial exposure period and, hence,differences in formation rate and surface coverage of thecorrosion patina, resulted in variations in runoff rate. Thisinitial difference remained also during prolonged exposureperiods and was referred to as a memory effect. Model roof investigations and laboratory studies showedsurface orientation and inclination to have a detrimentaleffect on the runoff rate with high runoff rates from surfacesof low inclination from horizon and surfaces exposed towardsthe wind direction. Based on fieldexposures and literature data, a correlationwas established between the runoff rate and the prevailingSO2-concentration. The runoff rate increases with increasingSO2 level for exposure sites of similar annual precipitationquantities (500-1000 mm/y). A rain device, using artificialrain, was shown to successfully simulate outdoor rain events ofvarying intensity and pH and result in realistic runoff ratesof both copper and zinc. The device was used to monitor changesin metal concentration and quantity of runoff water duringindividual rain events. High metal concentrations are found inthe initial rain volume flushing the surface (first flush),which decreased to rather constant metal concentrations duringthe subsequent rain volume (steady-state). The magnitude offirst flush depends primarily on environmental conditions priorto a rain event and the characteristics of the corrosionpatina. The metal concentration in runoff water increases withrain acidity, decreases with rain intensity and increases withlength of the dry period preceding a rain event. A comparison between instantaneous corrosion rates,monitored by electrochemical impedance spectroscopy using a2-electrode set-up, and runoff rates during a continuous rainevent was performed for naturally patinated copper panels.Corrosion rates were found to be approximately 10 (brownishpatina) and 25 times (greenish patina) lower than correspondinginstantaneous runoff rates. A schematic description of the first flush and steady-stateregion of the runoff process was established. The magnitude ofthe concentration during first flush is primarily affected byprevailing environmental conditions prior to a rain event,while rain pH and intensity primarily affect the concentrationduring steady-state. <b>Key words:</b>atmospheric corrosion, corrosion rate, runoffrate, copper, zinc, field study, laboratory study, roof, firstflush, rain quantity, rain intensity, rain pH, dry and wetdeposition, corrosion and runoff process.

<p>An extensive investigation with parallel field andlaboratory exposures has been conducted to elucidateatmospheric corrosion and metal runoff processes on copper andzinc used for roofing applications. Detailed studies have beenperformed to disclose the effect of various parameters on therunoff rate including: surface inclination and orientation,natural patination (age), patina composition, rain duration andvolume, rain pH, and length of dry periods inbetween rainevents. Annual and average corrosion rates and runoff rateshave been determined consecutively during urban field exposuresin Stockholm on naturally patinated copper and zinc of varyingage and patina composition. The corrosion rate was found todecrease with time, amounting to 6.7 g Cu/(m2.y) and 5.0 gZn/(m2.y) after 48 weeks of exposure, whereas the runoff ratewas relatively constant with time on a yearly basis, being 1.3g/(m2.y) and 3.1 g/(m2.y) for copper and zinc, respectively.The annual runoff rate was found to be significantly lower thanthe corresponding corrosion rate for both copper and zinc.Somewhat higher runoff rates of copper were determined fromnaturally green-patinated copper (>40 years old, 2.0g/(m2.y)) compared to brown-patinated copper (1 year old). Themain reasons are specific environmental conditions combinedwith characteristics of the patina layer, which increase themagnitude of dissolved species flushed from the surface duringthe first flush volume of a rain event. No intrinsic effect ofpanel age on the runoff rate was seen for naturally patinatedzinc. However, differences in prevailing environmentalconditions during the initial exposure period and, hence,differences in formation rate and surface coverage of thecorrosion patina, resulted in variations in runoff rate. Thisinitial difference remained also during prolonged exposureperiods and was referred to as a memory effect.</p><p>Model roof investigations and laboratory studies showedsurface orientation and inclination to have a detrimentaleffect on the runoff rate with high runoff rates from surfacesof low inclination from horizon and surfaces exposed towardsthe wind direction.</p><p>Based on fieldexposures and literature data, a correlationwas established between the runoff rate and the prevailingSO2-concentration. The runoff rate increases with increasingSO2 level for exposure sites of similar annual precipitationquantities (500-1000 mm/y). A rain device, using artificialrain, was shown to successfully simulate outdoor rain events ofvarying intensity and pH and result in realistic runoff ratesof both copper and zinc. The device was used to monitor changesin metal concentration and quantity of runoff water duringindividual rain events. High metal concentrations are found inthe initial rain volume flushing the surface (first flush),which decreased to rather constant metal concentrations duringthe subsequent rain volume (steady-state). The magnitude offirst flush depends primarily on environmental conditions priorto a rain event and the characteristics of the corrosionpatina. The metal concentration in runoff water increases withrain acidity, decreases with rain intensity and increases withlength of the dry period preceding a rain event.</p><p>A comparison between instantaneous corrosion rates,monitored by electrochemical impedance spectroscopy using a2-electrode set-up, and runoff rates during a continuous rainevent was performed for naturally patinated copper panels.Corrosion rates were found to be approximately 10 (brownishpatina) and 25 times (greenish patina) lower than correspondinginstantaneous runoff rates.</p><p>A schematic description of the first flush and steady-stateregion of the runoff process was established. The magnitude ofthe concentration during first flush is primarily affected byprevailing environmental conditions prior to a rain event,while rain pH and intensity primarily affect the concentrationduring steady-state.</p><p><b>Key words:</b>atmospheric corrosion, corrosion rate, runoffrate, copper, zinc, field study, laboratory study, roof, firstflush, rain quantity, rain intensity, rain pH, dry and wetdeposition, corrosion and runoff process.</p>

Erosion is an issue, which causes huge damages not only on agricultural land. This diploma thesis describes practical evaluation of erosion control measures (usage of leaving crop residue, circuit strips, contour tillage), which are include in Good Agriculture and Environmental Condition standart, which was issued by European union. Efficiency of usage of narrow-row and wide-row crops is also modeled. Each measures were evaluated in two different modeling programmes HydroCad for calibration and ERCN for results comparison. Seven different scripts are used in the thesis. Subcatchment area P6 in catchment area of Kopaninský creek is used as model area. Literature review describes the precipitation and runoff process, issue of erosion, and agriculture land protection against water erosion. Is also describes GAEC standards (today DZES).

The doctoral thesis deals with the evaluation of influences of causal factors that significantly affect runoff processes in landscape. The research is mainly focused on the examination of land and soil cover impacts and partially pays attention to the effects of surface drainage and snow cover. The main effort was to find out the extent of influences of each individual factor on runoff from a different type of landscape. In order to find the correct answer, a methodical approach was applied to small experimental paired catchments where the research has been continuously undergoing since the year of 2006 (the presented results have been collected for 11 years of observations). The small experimental paired catchments are located at the foothills of the Šumava Mountains and they represent small area neighbouring catchments of similar physical-geographic and hydrographic conditions. The catchments were selected as the comparative ones where the main differences are the landscape and soil cover. Moreover, the character of surface drainage is regarded to be an important variable. In the catchment area of the Zbytinský Brook, there predominates the grassland which is largely drained by the subsurface drainage system. In the catchment area of the Tetřívčí Brook the dominant cover is formed by the forest...