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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.

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Chiral recognition in metal–organic frameworks studied by solid-state NMR spectroscopy using chiral solvating agents

Hoffmann, Herbert C., Paasch, Silvia, Müller, Philipp, Senkovska, Irena, Padmanaban, Mohan, Glorius, Frank, Kaskel, Stefan, Brunner, Eike 09 April 2014 (has links) (PDF)
Recently, we have described the synthesis of chiral metal–organic frameworks iPr-ChirUMCM-1 and Bn-ChirUMCM-1 and their use in enantioselective separation. Here, we demonstrate for the first time the use of a chiral solvating agent (1-phenyl-2,2,2-trifluoroethanol, TFPE) for chiral recognition in iPr-ChirUMCM-1 and Bn-ChirUMCM-1 by means of solid-state13C NMR spectroscopy. / Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich.
Metall-organische Gerüste
MOF
MRT
Magnetresonanztomographie
Polymere
Raumtemperatur
Spin Crossover
poröse Festkörper
Adsorption
NMR-Spektroskopie
Metal-organic framework
resonance spectroscopy
magnetic resonance imaging
coordination polymer
room temperature
spin crossover
porous solids
configuration
adsorption
simulations
assignment
reagents
ddc:540
rvk: VA 1120

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